Historical trends of mercury and spheroidal carbonaceous particle deposition in sub-alpine lakes in the Great Basin,United States

The geochemistry of lake sediments was used to identify anthropogenic factors influencing aquatic ecosystems of sub-alpine lakes in the western United States during the past century. Sediment cores were recovered from six high-elevation lakes in the central Great Basin of the United States. The proxies utilized to examine the degree of recent anthropogenic environmental change include spheroidal carbonaceous particle (SCP), mercury (Hg), and sediment organic content estimated using loss-on-ignition. Chronologies for the sediment cores, developed using ²¹⁰Pb, indicate the cores span the twentieth century. Mercury flux varied between lakes but all exhibited increasing fluxes during the mid-twentieth century. The mean ratio of modern (post-A.D. 1985) to preindustrial (pre-A.D. 1880) Hg flux was 5.2, which is comparable to the results from previous studies conducted in western North America. Peak SCP flux for all lakes occurred between approximately A.D. 1940 and A.D. 1970, after which time the SCP flux was greatly reduced. The reduction in SCP input is likely due to better controls on combustion sources. Measured Hg concentrations and calculated sedimentation rates suggest atmospheric Hg flux increased in the early 1900s, from A.D. 1920 to A.D. 1990, and at present. Atmospheric deposition is the primary source of the anthropogenic inputs of Hg and SCPs to these high elevation lakes. The input of SCPs, which is largely driven by regional sources, has declined with the implementation of national pollution control regulations. Mercury deposition in the Great Basin has most likely been influenced more by regional inputs.     

Identifying volcanic regimes using Hidden Markov Models

We examine the application of Hidden Markov Models (HMMs) to volcanic occurrences. The parameters in HMMs can be estimated from data by means of the Expectation–Maximization (EM) algorithm. Various formulations permit modelling the activity level of a volcano through onset counts, the intensity of a Markov Modulated Poisson Process (MMPP), or through the intervals between onsets. More elaborate models allow investigation of the relationship between durations and reposes. After fitting the model, the Viterbi algorithm can be used to identify the underlying (hidden) activity level of the volcano most consistent with the observations. The HMM readily provides forecasts of the next event, and is easily simulated. Data of flank eruptions 1600–2006 from Mount Etna are used to illustrate the methodology. We find that the volcano has longish periods of Poissonian behaviour, interspersed with less random periods, and that changes in regime may be more frequent than have previously been identified statistically. The flank eruptions of Mount Etna appear to have a complex time-predictable character, which is compatible with transitions between an open and closed conduit system. The relationship between reposes and durations appears to characterize the cyclic nature of the volcanoes activity.     

Flooding of the continental shelves as a contributor to deglacial CH4 rise

The transition from the last glacial and beginning of Bølling–Allerød and Pre‐Boreal periods in particular is marked by rapid increases in atmospheric methane (CH₄) concentrations. The CH₄ concentrations reached during these intervals, ～650–750 ppb, is twice that at the last glacial maximum and is not exceeded until the onset of industrialization at the end of the Holocene. Periods of rapid sea‐level rise as the Last Glacial Maximum ice sheets retreated and associated with ‘melt‐water pulses’ appear to coincide with the onset of elevated concentrations of CH₄, suggestive of a potential causative link. Here we identify and outline a mechanism involving the flooding of the continental shelves that were exposed and vegetated during the glacial sea‐level low stand and that can help account for some of these observations. Specifically, we hypothesize that waterlogging (and later, flooding) of large tracts of forest and savanna in the Tropics and Subtropics during the deglacial transition and early Holocene would have resulted in rapid anaerobic decomposition of standing biomass and emission of methane to the atmosphere. This novel mechanism, akin to the consequences of filling new hydroelectric reservoirs, provides a mechanistic explanation for the apparent synchronicity between rate of sea‐level rise and occurrence of elevated concentrations of ice core CH₄. However, shelf flooding and the creation of transient wetlands are unlikely to explain more than ～60 ppb of the increase in atmospheric CH₄ during the deglacial transition, requiring additional mechanisms to explain the bulk of the glacial to interglacial increase. Similarly, this mechanism has the potential also to play some role in the rapid changes in atmospheric methane associated with the Dansgaard–Oeschger cycles. Copyright © 2012 John Wiley & Sons, Ltd.     

Finding Common Ground: A Critique of Subsumption Theory and Its Application to Small-Scale Forest Carbon Offsetting in Uganda

Carbon markets as a policy tool to mitigate emissions of greenhouse gases continue to be controversial, especially in developing countries. It is thus refreshing that Carton and Andersson (2017 Carton, W., and E. Andersson. 2017. Where forest carbon meets its maker: Forestry-based offsetting as the subsumption of nature. Society &; Natural Resources 30 (7):829–43.[Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]) undertook a field investigation of a transnational forest carbon offset project in Uganda. However, I am concerned that assumptions of structural Marxism that underwrite subsumption theory may have led the authors to see the project as inherently conflict ridden and exploitative and to neglect actual benefits. Their presentation of the project’s local impact jarred with my own empirical research into this project, undertaken in 2009, as well as more recent news accounts. While my field effort preceded the authors’ by 6 years, I attribute our different interpretations largely to theoretical and methodological differences. Evidence I present below suggests considerable alignment between the interests of transnational carbon markets and Ugandan smallholder farmers. Additional fieldwork might be able to resolve these differences in interpretation.     

A field test of tubino's (1991) model of alternate bar formation

This study investigates the fluvial dynamics of straight natural stream channels. In particular, this experimental field study quantitatively assesses a physically based non-linear mathematical theory of alternate bar formation under unsteady natural flow conditions within a straight alluvial stream. The study site is an artificially straightened section of the Embarras River located approximately 16 km south of Champaign, Illinois. Data were collected on channel form, gradient, alternate bar dimensions, bed sediment size and flow stage over a 2 year study period. Both linear and non-linear steady flow hydrodynamic theories suggest that alternate bars are critical to the process of meander development. But these theories do not predict bar development for unsteady flow conditions, which typically occur in natural alluvial channels. Tubino (1991) suggests that bar evolution for a flood hydrograph can be divided into three parts: (1) a period of limited bar growth during the rising stage of the flood; (2) a stage of modest bar decay near the peak of the flood; and (3) a stage of non-linear bar growth during the prolonged falling stage of the flood. Bars developed during the falling limb of a hydrograph, and exhibited sequential development rather than the uniform growth along the reach predicted by Tubino's model. As flow stage decreased, short, low, fine-grained bars were superimposed on long, high and coarser-grained bars that developed under preceding high flow stages. These results suggest that the process of bar formation in artificially straightened natural streams with heterogeneous bed material may occur under different flow conditions and in a different manner than predicted by theoretical models. Further work should focus on attempting to isolate the physical mechanisms responsible for alternate bar formation in straight natural streams with heterogeneous bed material and flashy hydrologic flow regimes.     

Denitrification capacity in a subterranean estuary below a Rhode Island fringing salt marsh

Coastal waters are severely threatened by nitrogen (N) loading from direct groundwater discharge. The subterranean estuary, the mixing zone of fresh groundwater and sea water in a coastal aquifer, has a high potential to remove substantial N. A network of piezometers was used to characterize the denitrification capacity and groundwater flow paths in the subterranean estuary below a Rhode Island fringing salt marsh.¹⁵N-enriched nitrate was injected into the subterranean estuary (in situ push-pull method) to evaluate the denitrification capacity of the saturated zone at multiple depths (125–300 cm) below different zones (upland-marsh transition zone, high marsh, and low marsh). From the upland to low marsh, the water table became shallower, groundwater dissolved oxygen decreased, and groundwater pH, soil organic carbon, and total root biomass increased. As groundwater approached the high and low marsh, the hydraulic gradient increased and deep groundwater upwelled. In the warm season (groundwater temperature >12 °C), elevated groundwater denitrification capacity within each zone was observed. The warm season low marsh groundwater denitrification capacity was significantly higher than all other zones and depths. In the cool season (groundwater temperature <10.5 °C), elevated groundwater denitrification capacity was only found in the low marsh. Additions of dissolved organic carbon did not alter groundwater denitrification capacity suggesting that an alternative electron donor, possibly transported by tidal inundation from the root zone, may be limiting. Combining flow paths with denitrification capacity and saturated porewater residence time, we estimated that as much as 29–60 mg N could be removed from 11 of water flowing through the subterranean estuary below the low marsh, arguing for the significance of subterranean estuaries in annual watershed scale N budgets.     

The Harry Creek Deformed Zone,a retrograde schist zone of the Arunta Block,central Australia

The Harry Creek Deformed Zone, a retrograde schist zone of epidote amphibolite facies grade, which separates the granulite facies Utralanama Block from the amphibolite facies Ankala Block in the southeastern Strangways Range, N.T., is typical of the retrograde schist zones transecting the Arunta Block. Associated with the deformed zone is a small deformed granitic pluton and its various offshoots—the Gumtree Granite Suite—which provides structural and geochrono‐logical evidence that the Harry Creek Deformed Zone has had a polyphase deforma‐tional history. Early movements within the deformed zone pre‐dated intrusion of the Gumtree Granite Suite and resulted in the movement of the Utralanama and Ankala Blocks into their present juxtaposition. Reactivation of much of the zone during the Alice Springs Orogeny brought about the schistose character of the zone and the deformation of the granitic rocks. Further minor reactivation of the zone, subsequent to the main phase of the Alice Springs Orogeny, resulted in limited development of pseudotachylytes.

The age of the granite (990 ± 13 m.y.) gives a minimum age for initiation of the zone, and evidence for the nature of the structures associated with the early movements is presented. It is suggested that the Harry Creek Deformed Zone represents a post‐orogenic wrench fault which has been reactivated. Early movements, which were of a brittle transcurrent nature, brought about major uplift (up to 10 km) to the north, and lateral movements may have been of the order of 60 km in a sinistral sense. Comparison with the Redbank Zone indicates many similarities, suggestive of a similar history.     

Mesozoic thermal evolution of the southern African mantle lithosphere

The thermal structure of Archean and Proterozoic lithospheric terranes in southern Africa during the Mesozoic was evaluated by thermobarometry of mantle peridotite xenoliths erupted in alkaline magmas between 180 and 60 Ma. For cratonic xenoliths, the presence of a 150–200 °C isobaric temperature range at 5–6 GPa confirms original interpretations of a conductive geotherm, which is perturbed at depth, and therefore does not record steady state lithospheric mantle structure.

Xenoliths from both Archean and Proterozoic terranes record conductive limb temperatures characteristic of a “cratonic” geotherm (40 mW m⁻²), indicating cooling of Proterozoic mantle following the last major tectonothermal event in the region at 1 Ga and the probability of thick off-craton lithosphere capable of hosting diamond. This inference is supported by U–Pb thermochronology of lower crustal xenoliths [Schmitz and Bowring, 2003. Contrib. Mineral. Petrol. 144, 592–618].

The entire region then suffered a protracted regional heating event in the Mesozoic, affecting both mantle and lower crust. In the mantle, the event is recorded at 150 Ma to the southeast of the craton, propagating to the west by 108–74 Ma, the craton interior by 85–90 Ma and the far southwest and northwest by 65–70 Ma. The heating penetrated to shallower levels in the off-craton areas than on the craton, and is more apparent on the southern margin of the craton than in its western interior. The focus and spatial progression mimic inferred patterns of plume activity and supercontinent breakup 30–100 Ma earlier and are probably connected.

Contrasting thermal profiles from Archean and Proterozoic mantle result from penetration to shallower levels of the Proterozoic lithosphere by heat transporting magmas. Extent of penetration is related not to original lithospheric thickness, but to its more fertile character and the presence of structurally weak zones of old tectonism. The present day distribution of surface heat flow in southern Africa is related to this dynamic event and is not a direct reflection of the pre-existing lithospheric architecture.