Dissimilarity among Ocean Reanalyses in Equatorial Pacific Upper-Ocean Heat Content and Its Relationship with ENSO

This study focuses on the temporal variation of dissimilarity in heat content(HC)anomalies in the upper 300 m of ocean(HC300A)in the equatorial Pacific(±10°N)and its response to the El Ni?o-Southern Oscillation(ENSO).The HC300A anomalies are derived from four ocean reanalyses that are commonly used in ENSO studies and are compared using a simple differencing method.The dissimilarity in HC300A is found to vary closely with the magnitude of ENSO(regardless of phase),meaning that it tends to be greater during strong ENSO events.However,the dissimilarity among ocean reanalyses persists after the event decays.This effect is more pronounced after strong events.The persistence of the dissimilarity after ENSO events is a result of a late maturation of the ENSO signal,its persistence,and the interruption of the signal decay due to follow-up ENSO events.The combined effect of these three factors slows down the decay of HC300A in the region and hence results in the slow decay of dissimilarity.It is also found that areas with a significant spread in vertical temperature profiles collocate with the ENSO signal during warm ENSO phases.Thus,differences in subsurface process reconstruction are a significant factor in the dissimilarity among ocean reanalyses during warm ENSO events.     

Curvature analysis as a tool for subsidence-related risk zones identification in the city of Tuzla (BiH)

Shallow Miocene salt deposits located below the city of Tuzla (BiH) have been exploited during the last 60 years by means of wells extracting salt-saturated groundwater brines. The massive extraction activities have led to severe subsidence accommodated by collapse and strain localization. Surface topography and geomorphology have been influenced and modified by several faults and fractures.A series of sequential topographical survey data collected during the last 50 years have been used to obtain the total subsidence envelope surface. In order to analyze the salt dissolution-related morphological development of the Tuzla topography and to identify the location of faults and fractures in the deformed area, we applied curvature analysis to the subsidence surface by means of two different analytical methods: the directional, two-dimensional curvature and the analytic Gaussian curvature. The comparison of the curvature maps with those of surface fractures visible in the area shows a good spatial agreement between the directional curvature and fracture intensity, whereas the subsurface normal faults are more evident in the Gaussian curvature maps.     

Detecting short-term evolution of Etnean scoria cones: a LIDAR-based approach

The 2001 and 2002–2003 flank eruptions on Mount Etna (Italy) were characterized by intense explosive activity which led to the formation of two large monogenetic scoria cones (one from each eruption) on the upper southern flank of the volcano. Continuous monitoring of Etna, especially during flank eruptions, has provided detailed information on the growth of these cones. They differ in genesis, shape, and size. A set of high resolution (1 m) digital elevation models (DEMs) derived from light detection and ranging (LIDAR) data collected during four different surveys (2004, 2005, 2006, and 2007) has been used to map morphology and to extract the morphometric parameters of the scoria cones. By comparing LIDAR-derived DEMs with a pre-eruption (1998) 10 m DEM, the volume of the two scoria cones was calculated for the first time. Comparison of the LIDAR-derived DEMs revealed in unprecedented detail morphological changes during scoria cone degradation. In particular, the morphologically more exposed and structurally weaker 2002–2003 cone was eroded rapidly during the first few years after its emplacement mainly due to gravitational instability of slopes and wind erosion.     

Microseismicity induced during fluid-injection: A case study from the geothermal site at Groß Schönebeck,North German Basin

The technical feasibility of geothermal power production in a low enthalpy environment will be investigated in the geothermal site at Groß Schönebeck, North German Basin, where a borehole doublet was completed in 2007. In order to complete the Enhanced Geothermal System, three massive hydraulic stimulations were performed. A seismic network was deployed including a single 3-component downhole seismic sensor at only 500 m distance to the injection point. Injection rates reached up to 9 m³/min and the maximum injection well-head pressure was as high as ～60 MPa. A total of 80 very small (?1.8 < M _W < ?1.0) induced seismic events were detected. The hypocenters were determined for 29 events. The events show a strong spatial and temporal clustering and a maximum seismicity rate of 22 events per day. Spectral parameters were estimated from the downhole seismometer and related to those from other types of induced seismicity. The majority of events occurred towards the end of stimulation phases indicating a similar behavior as observed at similar treatments in crystalline environments but in our case at a smaller level of seismic activity and at lower magnitudes.     

Photosynthesis and Growth of Temperate and Sub-Tropical Estuarine Phytoplankton in a Scenario of Nutrient Enrichment under Solar Ultraviolet Radiation Exposure

We compared the responses of two estuarine phytoplankton communities, one from a temperate (Chubut River estuary (CH), Argentina) and one from a sub-tropical site (Babitonga Bay (BB), Brazil), in a scenario of nutrient enrichment under solar ultraviolet radiation (UVR) exposure. Seawater samples were exposed in microcosms to two nutrients, ambient vs. enriched, and two radiation conditions, with and without UVR, and exposed to solar radiation for 4 days. We evaluated the short- (PSII photochemistry, during 90 min light and 90 min dark cycles, before and after the , whereas in BB, nutrient effects prevailed. Such differences were related to the previous light history of the cells and to the ambient nutrient status. After acclimation, an overall improvement of the photosynthetic performance was observed at both sites, either by reducing the relative inhibition or by increasing the recovery of the effective photochemical quantum yield. Interactive effects of UVR and nutrients on growth at CH were antagonistic, while at BB, no differences were observed between the interactive and the sum of effects. Part of the differences in the mid-term observed responses can be attributed to taxonomic changes, with the CH community dominated by diatoms throughout the experiment, but with a shift from a diatom to a flagellate-dominated community in BB. Temperature differences between both sites might have favored higher growth rates and flagellates dominance in BB under the nutrient enriched conditions.     

A hydrogeological conceptual model of the Suio hydrothermal area (central Italy)

A hydrogeological conceptual model has been developed that describes the hydrothermal system of Suio Terme (central Italy). The studied area is located along the peri-Tyrrhenian zone of the central Apennines, between the Mesozoic and Cenozoic carbonate platform sequences of the Aurunci Mountains and the volcanic sequences of the Roccamonfina. A multi-disciplinary approach was followed, using new hydrogeological surveys, the interpretation of stratigraphic logs of boreholes and water wells, and geophysical data—seismic sections, shear-wave velocity (Vs) crustal model and gravimetric model. The collected information allowed for construction of a conceptual hydrogeological model and characterization of the hydrothermal system. The Suio hydrothermal system is strongly influenced by the Eastern Aurunci hydrostructure. Along the southeastern side, the top of the hydrostructure sinks to ?1,000 m relative to sea level via a series of normal faults which give origin to the Garigliano graben. Geological and hydrogeological data strongly suggest the propagation and mixing of hot fluids, with cold waters coming from the shallow karst circuit. The aquitard distribution, the normal tectonic displacements and the fracturing of the karst hydrostructure strongly influence the hydrothermal basin. Carbon dioxide and other gasses play a key role in the whole circuit, facilitating the development of the hydrothermal system. The current level of knowledge suggests that the origin of the Suio hydrothermalism is the result of interaction between the carbonate reservoir of the Eastern Aurunci Mountains and the hot and deep crust of this peri-Tyrrhenian sector, where the Roccamonfina volcano represents the shallowest expression.     

Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.