The catalog of the meteorite collection of the Italian Museum of Planetary Sciences in Prato (Italy)

For the first time, this paper presents to the planetary scientists' community the catalog of the meteorite collection preserved at the Italian Museum of Planetary Sciences (Museo Italiano di Scienze Planetarie, henceforth MISP) in Prato (Italy). Founded in 2005, MISP is a type specimen official repository approved by the Nomenclature Committee of the Meteoritical Society. It represents one of the few museums worldwide entirely devoted to planetary sciences. The catalog of its meteorite collection encompasses 430 meteorites for a total of 1536 specimens, including 291 thin sections, 184 thick sections, and 278 specimens that MISP has classified. Furthermore, MISP is currently classifying 57 other meteorites. Some samples were found during meteorite recovery expeditions in hot deserts, promoted by MISP in collaboration with diverse Italian universities and national research institutions. MISP also keeps an impact rocks collection comprising 257 samples. In a country like Italy, where most of the collected meteorites are housed in museums whose catalogs are not available online, the publication of the MISP meteorite collection catalog, together with the catalog of the impact rocks collection, represents not only a significant scientific primary source but also a remarkable tool for disseminating meteoritics to nonresearch audiences in educational activities and citizen science projects.     

Using DORIS measurements for modeling the vertical total electron content of the Earth’s ionosphere

The Doppler orbitography and radiopositioning integrated by satellite (DORIS) system was originally developed for precise orbit determination of low Earth orbiting (LEO) satellites. Beyond that, it is highly qualified for modeling the distribution of electrons within the Earth’s ionosphere. It measures with two frequencies in L-band with a relative frequency ratio close to 5. Since the terrestrial ground beacons are distributed quite homogeneously and several LEOs are equipped with modern receivers, a good applicability for global vertical total electron content (VTEC) modeling can be expected. This paper investigates the capability of DORIS dual-frequency phase observations for deriving VTEC and the contribution of these data to global VTEC modeling. The DORIS preprocessing is performed similar to commonly used global navigation satellite systems (GNSS) preprocessing. However, the absolute DORIS VTEC level is taken from global ionospheric maps (GIM) provided by the International GNSS Service (IGS) as the DORIS data contain no absolute information. DORIS-derived VTEC values show good consistency with IGS GIMs with a RMS between 2 and 3 total electron content units (TECU) depending on solar activity which can be reduced to less than 2 TECU when using only observations with elevation angles higher than \(50^\circ \) . The combination of DORIS VTEC with data from other space-geodetic measurement techniques improves the accuracy of global VTEC models significantly. If DORIS VTEC data is used to update IGS GIMs, an improvement of up to 12  % can be achieved. The accuracy directly beneath the DORIS satellites’ ground-tracks ranges between 1.5 and 3.5 TECU assuming a precision of 2.5 TECU for altimeter-derived VTEC values which have been used for validation purposes.     

Mechanisms of failure on terraced slopes: the Valtellina case (northern Italy)

Slopes that are terraced by means of dry-stone retaining walls are very common in the alpine environment. In Valtellina, a typical Italian alpine valley, these slopes are widespread and quite often involved in superficial mass movements that can result in severe damage and casualties. For an in-depth understanding of the processes that can trigger these events, numerical modeling of groundwater movement and a related stability analysis were performed on a detailed scale, based on an intensive monitoring of rainfall events and groundwater movement. Field observations suggest that the formation of a perched groundwater table at the contact between the bedrock and the backfill soil of walls as well as the concomitant saturation of this backfill soil are the determining factors of potential slope failure. The numerical models support these observations. In addition, the models are able to explain the mechanisms of formation of perched water tables, highlighting the factors that can influence groundwater levels and slope instabilities.     

Human alteration of groundwater–surface water interactions (Sagittario River,Central Italy): implication for flow regime,contaminant fate and invertebrate response

Many rivers worldwide are undergoing severe man-induced alterations which are reflected also in changes of the degree of connectivity between surface waters and groundwater. Pollution, irrigation withdrawal, alteration of freshwater flows, road construction, surface water diversion, soil erosion in agriculture, deforestation and dam building have led to some irreversible species losses and severe changes in community composition of freshwater ecosystems. Taking into account the impact of damming and flow diversion on natural river discharge, the present study is aimed at (i) evaluating the effects of anthropogenic changes on groundwater/surface water interactions; (ii) analyzing the fate of nitrogenous pollutants at the floodplain scale; and (iii) describing the overall response of invertebrate assemblages to such changes. Hydrogeological, geochemical and isotopic data revealed short- and long-term changes in hydrology, allowing the assessment of the hydrogeological setting and the evaluation of potential contamination by nitrogen compounds. Water isotopes allowed distinguishing a shallow aquifer locally fed by zenithal recharge and river losses, and a deeper aquifer/aquitard system fed by surrounding carbonate aquifers. This system was found to retain ammonium and, through the shallow aquifer, release it in surface running waters via the hyporheic zone of the riverbed. All these factors influence river ecosystem health. As many environmental drivers entered in action offering a multiple-component artificial environment, a clear relationship between river flow alteration and benthic and hyporheic invertebrate diversity was not found, being species response driven by the combination of three main stressors: ammonium pollution, man-induced changes in river morphology and altered discharge regime.     

Monitoring large oil slick dynamics with moderate resolution multispectral satellite data

Accidental release of crude oil into the sea due to human activity causes water pollution and heavy damages to natural ecosystems killing birds, fish, mammals and other organisms. A number of monitoring systems are used for tracking the spills and their effects on the marine environment, as well as for collecting data for feeding models. Among them, Earth observation technologies play a crucial role and moderate spatial resolution satellite systems are able to collect images with a very short revisit time or even daily. This paper describes the use of Moderate-Resolution Imaging Spectroradiometer data for monitoring large oil slicks with the fluorescence/emissivity index and object-based image analysis. Two case studies are presented: the Deepwater Horizon (2010) and the Campos Basin (2011) oil spill accidents. Results show that it is possible to track the dynamics of the slick both for massive and long-lasting accidents and for smaller and very quick accidents. The main advantages of the method proposed are a straightforward implementation, a fast and semi-automated data processing and the capability of integration of daytime and nighttime acquisitions, as well as its adaptability to different sensors.     

LightSquared effects on estimated C/N 0, pseudoranges and positions

We present experimental results showing the impact of the proposed LightSquared (LS) Long-term Evolution (LTE) signals on both GPS and Galileo civil modulations in the L1/E1 band. The experiments were conducted in radiated mode in a large anechoic chamber. Three Galileo enabled receivers were chosen for the tests, and a state of the art GNSS signal generator was used to simulate both GPS and Galileo signals. The LTE signals were generated by an Agilent Programmable Signal Generator with a license to generate the signals according to the 3GPP LTE FDD standard. The interference impact was measured in terms of a Carrier-to-Noise power spectral density ratio (C/N ₀) degradation, in accordance with the methodology which the LS/GPS Technical Working Group (TWG) established by mandate of the FCC. A model for determining the impact of the LS signal on the considered GNSS signals is provided and is validated against experimental data. It is shown that the Galileo E1 Open Service (OS) signal is marginally more susceptible to this form of interference than the GPS L1 C/A signal due to its greater proximity to the lower edge of the L1 band. The impact of LS interference was further analyzed in terms of pseudorange and position errors. Despite its relevance for most GNSS users, this aspect was not considered by the TWG. Measurement and position domain analysis along with the study of the LS impact on the Galileo OS signals are the major contributions. The analysis confirms the results obtained by the TWG and shows that the receiver front-end plays a major role in protecting GNSS signals against RF interference. While it appears that, for now, the LS network will not be deployed, the approach taken and the results obtained herein can be readily adapted for any future terrestrial mobile network that may take the place of LS.     

High-pressure behaviour along the jadeite NaAlSi2O6–aegirine NaFeSi2O6 solid solution up to 10 GPa

The volume variation as a function of pressure along the jadeite–aegirine solid solution was determined at room temperature up to pressures between 6.5 and 9.7 GPa by single-crystal X-ray diffraction. The unit-cell volumes collected at room pressure for the different compositions indicate a slight deviation from linearity along the join. The pressure–volume data have been fitted using a third-order Birch-Murnaghan equation of state (BM3-EoS). The bulk modulus, K _T0, varies from 134.0(7) GPa for pure jadeite to 116.1(5) GPa for pure aegirine. Its evolution with composition along the join is not linear and can be described by the following second order polynomial:

Seep mounds on the Southern Vøring Plateau (offshore Norway)

Multidisciplinary study of seep-related structures on Southern Vøring Plateau has been performed during several UNESCO/IOC TTR cruises on R/V Professor Logachev. High-resolution sidescan sonar and subbottom profiler data suggest that most of the studied fluid discharge structures have a positive relief at their central part surrounded by depression. Our data shows that the present day fluid activity is concentrated on the top of these “seep mounds”. Number of high hydrocarbon (HC) gas saturated sediment cores and 5 cores with gas hydrate presence have been recovered from these structures. δ¹³C of methane (between −68 and −94.6‰ VPDB) and dry composition of the gas points to its biogenic origin. The sulfate depletion generally occurs within the upper 30–200 cm bsf and usually coincides with an increase of methane concentration. Pore water δ¹⁸O ranges from 0.29 to 1.14‰ showing an overall gradual increase from bottom water values (δ¹⁸O ∼ 0.35‰). Although no obvious evidence of fluid seepage was observed during the TV surveys, coring data revealed a broad distribution of living Pogonophora and bacterial colonies on sea bottom inside seep structures. These evidences point to ongoing fluid activity (continuous seepage of methane) through these structures. From other side, considerable number and variety of chemosynthetic macro fauna with complete absence of living species suggest that present day level of fluid activity is significantly lower than it was in past. Dead and subfossil fauna recovered from various seep sites consist of solemyid (Acharax sp.), thyasirid and vesicomyid (cf. Calyptogena sp.) bivalves belonging to chemosymbiotic families. Significant variations in δ¹³C (−31.6‰ to −59.2‰) and δ¹⁸O (0.42‰ and 6.4‰) of methane-derived carbonates collected from these structures most probably related to changes in gas composition and bottom water temperature between periods of their precipitation. This led us to ideas that: (1) seep activity on the Southern Vøring Plateau was started with large input of the deep thermogenic gas and gradually decries in time with increasing of biogenic constituent; (2) authigenic carbonate precipitation started at the near normal deep sea environments with bottom water temperature around +5 °C and continues with gradual cooling up to negative temperatures recording at present time.     

Erosion-driven uplift of the modern Central Alps

We present a compilation of data of modern tectono-geomorphic processes in the Central European Alps which suggest that observed rock uplift is a response to climate-driven denudation. This interpretation is predominantly based on the recent quantification of basin-averaged Late Holocene denudation rates that are so similar to the pattern and rates of rock uplift rates as determined by geodetic leveling. Furthermore, a GPS data-based synthesis of Adriatic microplate kinematics suggests that the Central Alps are currently not in a state of active convergence. Finally, we illustrate that the Central Alps have acted as a closed system for Holocene redistribution of sediment in which the peri-Alpine lakes have operated as a sink for the erosional products of the inner Central Alps.While various hypotheses have been put forward to explain Central Alpine rock uplift (e.g. lithospheric forcing by convergence, mantle processes, or ice melting) we show with an elastic model of lithospheric deformation, that the correlation between erosion and rock uplift rates reflects a positive feedback between denudation and the associated isostatic response to unloading. Thus, erosion does not passively respond to advection of crustal material as might be the case in actively converging orogens. Rather, we suggest that the geomorphic response of the Alpine topography to glacial and fluvial erosion and the resulting disequilibrium for modern channelized and associated hillslope processes explains much of the pattern of modern denudation and hence rock uplift. Therefore, in a non-convergent orogen such as the Central European Alps, the observed vertical rock uplift is primarily a consequence of passive unloading due to erosion.