Early detection of volcanic hazard by lidar measurement of carbon dioxide

Volcanic gases give information on magmatic processes. In particular, anomalous releases of carbon dioxide precede volcanic eruptions. Up to now, this gas has been measured in volcanic plumes with conventional measurements that imply the severe risks of local sampling and can last many hours. For these reasons and for the great advantages of laser sensing, the thorough development of volcanic lidars has been undertaken at ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development). In fact, lidar profiling allows one to scan remotely volcanic plumes in a fast and continuous way, and with high spatial and temporal resolution. A differential absorption lidar instrument will be presented in this paper: BILLI (BrIdge voLcanic LIdar). It is based on injection-seeded Nd:YAG laser, double-grating dye laser, difference frequency mixing and optical parametric amplifier. BILLI is funded by the ERC (European Research Council) project BRIDGE (BRIDging the gap between Gas Emissions and geophysical observations at active volcanos). It scanned the gas emitted by Pozzuoli Solfatara (Naples, Italy) and Stromboli Volcano (Sicily, Italy) during field campaigns carried out from October 13 to 17, 2014, and from June 24 to 29, 2015, respectively. Carbon dioxide concentration maps were retrieved remotely in few minutes in the crater areas. To our knowledge, it is the first time that carbon dioxide in a volcanic plume is retrieved by lidar. This result represents the first direct measurement of this kind ever performed on active volcanos and shows the high potential of laser remote sensing in early detection of volcanic hazard.     

A lost Tethyan evaporitic basin: Evidence from a Cretaceous hemipelagic meta‐selenite – red chert association in the Eastern Mediterranean realm

Ancient evaporite deposits are geological archives of depositional environments characterized by a long‐term negative precipitation balance and bear evidence for global ocean element mass balance calculations. Here, Cretaceous selenite pseudomorphs from western Anatolia (‘Rosetta Marble’) — characterized by their exceptional morphological preservation — and their ‘marine’ geochemical signatures are described and interpreted in a process‐oriented context. These rocks recorded Late Cretaceous high‐pressure/low‐temperature, subduction‐related metamorphism with peak conditions of 1·0 to 1·2 GPa and 300 to 400°C. Metre‐scale, rock‐forming radiating rods, now present as fibrous calcite marble, clearly point to selenitic gypsum as the precursor mineral. Stratigraphic successions are recorded along a reconstructed proximal to distal transect. The cyclical alternation of selenite beds and radiolarian ribbon‐bedded cherts in the distal portions are interpreted as a two type of seawater system. During arid intervals, shallow marine brines cascaded downward into basinal settings and induced precipitation. During more humid times, upwelling‐induced radiolarian blooms caused the deposition of radiolarite facies. Interestingly, there is no comparable depositional setting known from the Cenozoic world. Meta‐selenite geochemical data (δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr) plot within the range of reconstructed middle Cretaceous seawater signatures. Possible sources for the ¹³C‐enriched (mean 2·2‰) values include methanogenesis, gas hydrates and cold seep fluid exhalation. Spatially resolved component‐specific analysis of a rock slab displays isotopic variances between meta‐selenite crystals (mean δ¹³C 2·2‰) and host matrix (mean δ¹³C 1·3‰). The Cretaceous evaporite‐pseudomorphs of Anatolia represent a basin wide event coeval with the Aptian evaporites of the Proto‐Atlantic and the pseudomorphs share many attributes, including lateral distribution of 600 km and stratigraphic thickness of 1·5 to 2·0 km, with the evaporites formed during the younger Messinian salinity crisis. The Rosetta Marble of Anatolia may represent the best‐preserved selenite pseudomorphs worldwide and have a clear potential to act as a template for the study of meta‐selenite in deep time.     

Multi‐scale analysis of a migrating submarine channel system in a tectonically‐confined basin: The Miocene Gorgoglione Flysch Formation,southern Italy

The Miocene Gorgoglione Flysch Formation records the stratigraphic product of protracted sediment transfer and deposition through a long‐lived submarine channel system developed in a narrow and elongate thrust‐top basin of the Southern Apennines (Italy). Channel‐fill deposits are exposed in an outcrop belt approximately 500 m thick and 15 km long, oriented oblique to the palaeoflow, which was roughly south‐eastward. These exceptional exposures of channel‐fill strata allow the stacking architectures and the evolution of the channel system to be analyzed at multiple scales, enabling the effects of syn‐sedimentary thrust tectonics and basin confinement on the depositional system development to be deciphered. Two end‐member types of elementary channel architecture have been identified: high‐aspect‐ratio, weakly‐confined channels, and low‐aspect‐ratio, incisional channels. Their systematic stacking results in a complex pattern of seismic‐scale depositional architectures that determines the stratigraphic framework of the deep‐water system. From the base of the succession, two prominent channel complex sets have been recognized, namely CS1 and CS2, consisting of amalgamated incisional channel elements and weakly‐confined channel elements. These channelized units are overlain by isolated incisional channels, erosional into mud‐prone slope deposits. The juxtaposition of different channel architectures is interpreted to have been governed by regional thrust‐tectonics, in combination with a high subsidence rate that promoted significant aggradation. In this scenario, the alternating ‘in sequence’ and ‘out of sequence’ tectonic pulses of the basin‐bounding thrusts controlled the activation of coarse‐clastic inputs in the basin and the resulting stacking architectures of channelized units. The tectonically‐driven confinement of the depositional system limited the lateral offset in channel stacking, preventing large‐scale avulsions. This study represents an excellent opportunity to analyze the stratigraphic evolution of a submarine channel system in tectonically‐active settings from an outcrop perspective. It should find wide applicability in analogous depositional systems, whose stratigraphic architecture has been influenced by tectonically‐controlled lateral confinement and associated lateral tilting.     

On the nature,formation and diversity of particulate coherent structures in microgravity conditions and their relevance to materials science and problems of astrophysical interest

Different phenomena related to the spontaneous accumulation of solid particles dispersed in a fluid medium in microgravity conditions are discussed, with an emphasis on recent discoveries and potential links with the general field of astrophysical fluid-dynamics on the one hand, and with terrestrial applications in the field of materials science on the other hand. With special attention to the typical physical forces at play in such an environment, namely, surface-tension gradients, oscillatory residual gravity components, inertial disturbances and forces of an electrostatic nature, specific experimental and numerical examples are presented to provide inputs for an increased understanding of the underlying cause-and-effect relationships. Studying these systems can be seen as a matter of understanding how macroscopic scenarios arise from the cooperative behaviour of sub-parts or competing mechanisms (nonlinearities and interdependencies on various spatial and temporal scales). Through a critical assessment of the properties displayed by the resulting structures (which appear in the form of one-dimensional circuits formed by aligned particles, planar accumulation surfaces, three-dimensional compact structures resembling “quadrics”, micro-crystallites or fractal aggregates), we discuss a possible classification of the related particle attractors in the space of parameters according to the prevailing effect.     

Giant sector-collapse structures (scalloped margins) of the Yangtze Platform and Great Bank of Guizhou,China: Implications for genesis of collapsed carbonate platform margin systems

Sector-collapse structures ranging up to 27 km wide with up to 7.7 km bankward erosion (scalloped margins) and linear escarpments occur along the east-north-east-trending, south-facing margins of the Yangtze Platform and Great Bank of Guizhou. Exposure of one of the structures on the rotated limb of a syncline displays the geometry in profile view. Declivities range from 65° to 90° in the upper wall and decrease asymptotically to the toe. Catastrophic collapses of the margins in both platforms occurred during the late Ladinian as constrained by the ages of strata truncated along the margins and the siliciclastic turbidites that onlap collapse structures. Middle Triassic Anisian and Ladinian platform-edge reef facies and platform-interior facies were truncated along both the Yangtze and Great Bank of Guizhou margins. Lower Triassic facies were also truncated along the Great Bank of Guizhou margin. Gravity transport during the main episodes of collapse occurred as mud-rich debris-flows and as mud-free hyper-concentrated flows. Clasts, several to tens of metres and, exceptionally, hundreds of metres across, were transported to the basin. Following collapse, talus, carbonate turbidites and periplatform-mud accumulated at the toe of slope. Shedding of skeletal grains and carbonate mud indicates active carbonate factories at the margin. Preserved sections of the margins demonstrate that the platforms evolved high-relief, accretionary escarpments prior to collapse. High-relief, without buttressing by basin-filling sediments, predisposed the margins to collapse by development of tensile strain and fracturing within the margin due to the lack of confining stress. The linear geometry of margins and active tectonics in the region supports tectonic activity triggering the collapse. Collapse is thus interpreted to have been triggered by fault movement and seismic shock. Comparison with other systems indicates that evolution from high-relief accretion to tectonic collapse of largely lithified margins resulted in large sector-collapse structures and deposition of a coarse, generally mud-poor breccia apron.     

Controls on carbonate platform architecture and reef recovery across the Palaeozoic to Mesozoic transition: A high-resolution analysis of the Great Bank of Guizhou

Carbonate platforms spanning intervals of global change provide an opportunity to identify causal links between the evolution of marine environment and depositional architecture. This study investigates the controls on platform geometry across the Palaeozoic to Mesozoic transition and yields new stratigraphic and palaeoenvironmental constraints on the Great Bank of Guizhou, a latest Permian to earliest Late Triassic isolated carbonate platform in the Nanpanjiang Basin of south China. Reconstruction of platform architecture was achieved by integrating field mapping, petrography, biostratigraphy, satellite imagery analysis and δ¹³C chemostratigraphy. In contrast to previous interpretations, this study indicates that: (i) the Great Bank of Guizhou transitioned during Early Triassic time from a low-relief bank to a platform with high relief above the basin floor (up to 600 m) and steep slope angles (preserved up to 50°); and (ii) the oldest-known platform-margin reef of the Mesozoic Era grew along steep, prograding clinoforms in an outer-margin to lower-slope environment. Increasing platform relief during Early Triassic time was caused by limited sediment delivery to the basin margin and a high rate of accommodation creation driven by Indosinian convergence. The steep upper Olenekian (upper Lower Triassic) slope is dominated by well-cemented grainstone, suggesting that high carbonate saturation states led to syndepositional or rapid post-depositional sediment stabilization. Latest Spathian reef initiation coincided with global cooling following Early Triassic global warmth. The first Triassic framework-building metazoans on the Great Bank of Guizhou were small calcareous sponges restricted to deeper water settings, but early Mesozoic reef builders were volumetrically dominated by Tubiphytes, a fossil genus of uncertain taxonomic affinity. In aggregate, the stratigraphic architecture of the Great Bank of Guizhou records sedimentary response to long-term environmental and biological recovery from the end-Permian mass extinction, highlighting the close connections among marine chemistry, marine ecosystems and carbonate depositional systems.     

Responses of humpback whales to a changing climate in the Southern Hemisphere: Priorities for research efforts

Globally, baleen whales were severely depleted by historic whaling. Recovering populations have been observed to alter their behaviour. These changes have been attributed to climate change in some cases and raise concerns over the successful recovery of baleen whale populations. Current data-driven statistical habitat and behavioural models have proven useful for addressing questions of whale distribution changes within their limitations. Given observed changes in oceanic conditions, a new approach to managing baleen whale population recovery is necessary. Model predictions of future whale movements and distributions under climate change scenarios are vital to enable adequate conservation management. This paper presents a new perspective on understanding the impacts of climate change on humpback whales, arguing the need for a system-based multidisciplinary research approach. Our approach includes coupled, mechanistic models based upon robust ecological principles, and integrates key physical, biogeochemical, biological and ecological modules to address long-term changes associated with climate change. To illustrate the need for this system-based multidisciplinary approach, we focus on Southern Hemisphere humpback whales, the recovery of which may be impacted by rapid changes in habitat conditions brought about by anthropogenic climate change.     

Quaternary normal faulting in southeastern Sicily (Italy):a seismic source for the 1693 large earthquake

We present geological and morphological data, combined with an analysis of seismic reflection lines across the Ionian offshore zone and information on historical earthquakes, in order to yield new constraints on active faulting in southeastern Sicily. This region, one of the most seismically active of the Mediterranean, is affected by WNW–ESE regional extension producing normal faulting of the southern edge of the Siculo–Calabrian rift zone. Our data describe two systems of Quaternary normal faults, characterized by different ages and related to distinct tectonic processes. The older NW–SE-trending normal fault segments developed up to ≈400  kyr ago and, striking perpendicular to the main front of the Maghrebian thrust belt, bound the small basins occurring along the eastern coast of the Hyblean Plateau. The younger fault system is represented by prominent NNW–SSE-trending normal fault segments and extends along the Ionian offshore zone following the NE–SW-trending Avola and Rosolini–Ispica normal faults. These faults are characterized by vertical slip rates of 0.7–3.3  mm  yr ⁻¹ and might be associated with the large seismic events of January 1693. We suggest that the main shock of the January 1693 earthquakes ( M ~ 7) could be related to a 45  km long normal fault with a right-lateral component of motion. A long-term net slip rate of about 3.7  mm  yr ⁻¹ is calculated, and a recurrence interval of about 550 ± 50  yr is proposed for large events similar to that of January 1693.     

The upper Miocene diatomaceous sediments of the northernmost Mediterranean region: A lamina-scale investigation of an overlooked palaeoceanographic archive

During the late Miocene the Mediterranean experienced a dramatic intensification of opaline accumulation, recorded by the deposition of diatomaceous sediments. The fine lamination of these deposits potentially records annual to sub-annual palaeoceanographic processes that occurred during a critical phase of the geodynamic evolution of the Mediterranean basin, which eventually led to the Messinian salinity crisis. The diatomaceous facies has been interpreted by previous researchers as the product of intensified upwelling currents and of bottom anoxia formation in the Mediterranean basin. However, until now, no efforts have been made to unravel the sedimentological and micropalaeontological content of these deposits at the lamina-scale. This paper presents the first case study of a systematic scanning electron microscope-based morphological investigation of the diatomaceous sediments deposited during the late Miocene at the northernmost offshoot of the Mediterranean basin (Piedmont Basin, north-west Italy). Using a non-invasive analytical approach, six faciological components (laminae, laminated packets, non-laminated intervals, burrows, opal-rich aggregates and mixed pelletal structures) and their relationships are described and interpreted herein. Following the lamina-scale study of these sediments, an annual sedimentary cycle could be identified and an accumulation rate (ca 50 cm kyr⁻¹) inferred that is atypical for a setting actively influenced by upwelling. The role played by the entanglement of diatom valves in creating a physical barrier to the bioturbation is here emphasized as the main process responsible for the preservation of the laminated fabric of diatomaceous sediments, challenging the supposed role of deep anoxia. These results suggest that the late Miocene diatomaceous deposition in the Piedmont Basin cannot be univocally considered as a by-product of upwelling intensification and seafloor oxygen depletion.