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61.
62.
Over several years many partition coefficients have been measured between framework silicates, sheet silicates and hydrothermal solutions. Only trace alkaline cations are considered in the present work. It is well known that the difference between ionic radii of the trace cation and the major cation is replaces is not satisfactory for a good correlation with the partition coefficients PX. A structural parameter δc is therefore defined, taking into consideration the adaptation of the trace cation to the cavity in which it occurs. This cavity may be the entire site of the major element, or a part of this site in the case of small cations, or a structural cavity located out of the alkali-ion site. The adaptation parameter δc is the difference between the ionic radius of the trace cation and the radius of that cavity. This paper shows that the partition coefficient PX of the trace alkali-ion from the hydrothermal solution is an exponential function of the adaptation parameter δc, whatever the silicate may be. 相似文献
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Bačík Peter Dikej Jakub Fridrichová Jana Miglierini Marcel Števko Martin 《Mineralogy and Petrology》2017,111(4):609-624
Mineralogy and Petrology - Tourmaline-supergroup minerals are common gangue minerals in Sb-hydrothermal veins on Betliar – Straková, Čučma – Gabriela and... 相似文献
66.
Serge Fourcade Laurent Trotignon Philippe Boulvais Isabelle Techer Marcel Elie Didier Vandamme Elias Salameh Hani Khoury 《Applied Geochemistry》2007
The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ13C-values down to −31.4‰/PDB show the contribution of CO2 derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO2 in the near field. 相似文献
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The continuous spectrum of linear ideal MHD is determined analytically in 2D magnetostatic models for coronal loops and arcades by means of a perturbation expansion. Poloidal mode coupling, induced by non-circularity of the cross-sections of the magnetic surfaces and/or variation of the plasma density along the magnetic field lines, is shown to occur in first order. The coupling is most pronounced on and near rational surfaces for particular poloidal and toroidal mode numbers and produces gaps in the continuous spectrum of ideal MHD. 相似文献
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Namık Aysal Marcel Guillong Tamara Bayanova Mayuko Fukuyama Nicole Leonard İsak Yılmaz Elif Varol Fatma Şişman Tükel Yusuf Kaan Kadıoğlu Nurullah Hanilçi Fulya Uzun Ersin Kaygısız 《Geostandards and Geoanalytical Research》2023,47(2):297-310
Gem quality andradite-rich garnet (IUC-1), obtained from the Miocene trachyte dome near Ankara city (Turkey), has been identified as a potential natural secondary reference material for U-Pb dating. In this study, U-Pb dating was performed in five different laboratories using isotope dilution TIMS and laser ablation ICP-MS to determine the homogeneity of euhedral garnet crystals. The U-Pb ID-TIMS data for IUC-1 yielded 207Pb/235U and 206Pb/238U ages of 20.9 ± 0.4 and 20.6 ± 0.8 Ma respectively, and these values are consistent with U-Pb LA-ICP-MS analyses, in which different garnet crystals yielded ages of 20.8 ± 0.1, 20.7 ± 0.1, 20.7 ± 0.2 and 20.2 ± 0.1 Ma. An andradite (IUC-2) from the Serçeören wollastonite skarn (Turkey) can be used as a secondary reference material provided detailed imaging of the crystals is undertaken. ID-TIMS data yielded 207Pb/235U and 206Pb/238U ages of 20.4 ± 0.4 and 20.9 ± 1.0 Ma respectively, and yielded U-Pb ages on different grains of 20.5 ± 0.1, 20.7 ± 1.0, 20.8 ± 1.7 and 20.9 ± 1.6 Ma. The assigned weighted mean age of IUC-1 (20.4 ± 0.5 Ma, 2s) is proposed as a 2023 reference value. IUC-1 garnet is expected to contribute significantly to rapidly developing garnet geochronology in the near future. 相似文献
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The question of total resonant absorption of acoustic oscillations in sunspots is studied for cylindrical 1-D flux tubes that are stratified only in the radial direction and surrounded by a uniform, non-magnetic plasma. The numerical investigation of Goossens and Poedts (1992) in linear resistive MHD is taken further by increasing the strength of the azimuthal magnetic field in the equilibrium flux tubes. For relatively strong azimuthal magnetic fields, total absorption is found over a relatively wide range of spot radii. 相似文献