An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

A comparative mineralogical study of gas-related sediments of the Gulf of Cádiz

The Gulf of Cádiz area has been extensively surveyed in recent years and several gas-related fluid escape seafloor structures have been identified. In this study, gravity cores, collected during the ANASTASYA/00 and ANASTASYA/01 cruises, on mud volcanoes, hemipelagic sediments and dredged material from diapiric structures, have been studied. A comparative mineralogical analysis by XRD and SEM of samples from different areas has been performed in order to determine whether there is a characteristic mineralogy related to these fluid escape structures, and also to determine the origin of the mud matrix and constrain the depth of the parent units. The mineralogical analysis reflects the different origins of the different units described in the cores: hemipelagic material of the slope, clays that underlie the mud volcanoes and are discharged at the sea bottom surface, and authigenic and diagenetic minerals possibly involved in the anaerobic oxidation of methane in the mud volcano sediments.     

Onshore Neogene stratigraphy in the North of the Alboran Sea (Betic Internal Zones): Paleogeographic implications

The Neogene is the period in which the Betic Cordillera, the Rif, and the Alboran Sea acquired their present configuration. The Neogene sediments of the Betic Internal Zones (located directly to the North of the Alboran Sea) show the effects of important periods of deformation. Deposition was clearly controlled by tectonics. Therefore the generation, evolution, and total or partial destruction of basins and the formation of new, often superimposed, basins are common phenomena, according to the locations of the basins in the Betic Cordillera and to the different geodynamic situations.     

Phosphate adsorption and desorption in a tropical estuary (Maracaibo system)

The Maracaibo Estuary is of particular interest because of its location in the tropics, its large size (over 12,000 km²), the economic importance of its underlying hydrocarbon deposits and its increasing rate of pollution. Sediments from this estuary were studied in order to characterise their capacity to adsorb and desorb phosphorus. Considerable variability in capacity for phosphate sorption was found among the seventeen samples studied. This variability can be attributed first to the differences among the samples in total P content and, secondly, to their differences in free iron content. Also, it appears that P retention contributes to the control of P concentration in the water and therefore the sediments serve as a buffer in controlling P eutrophication in the estuary.     

Palynological characterization of gassy sediments in the inner part of Ría de Vigo (NW Spain). New chronological and environmental data

Palynological characterization of the pollen assemblages from core ZV-01 offers a reliable age record of shallow ‘gas seal’ and ‘gas reservoir’ sediments from the Ría de Vigo (NW Spain). Gassy sediments show a direct correspondence with the palynological assemblage zones (LPAZ) 2, 3 and 4, which range in age from 950 to 1510 a.d. for the interval 81–176 cm where gas is found. The facies acting as a seal would correspond to the sedimentation in the ria starting from 1510 a.d. These assemblages also provide significant data which make it possible to reconstruct the palaeoenvironmental changes recorded in the sedimentary infill of the Ría de Vigo. The gassy horizon corresponds to the phase when riparian and mesophilous forest were better represented. This coincides with a relative high abundance of Lingulodinium machaerophorum, which indicates that the waters of the ria had been less renewed by oceanic waters and had a plentiful supply of continental nutrients. At that time, anoxic conditions resulted from restricted vertical circulation of seawater and/or high biological productivity. The dinocyst assemblages overlying and underlying the gassy horizon in core ZV-01 are clearly different from those concomitant with the accumulation of the gassy sediments. This suggests that oceanographic conditions in the Ría de Vigo may have changed several times during the time interval covered by our record. The weaker relationship between L. machaerophorum/Spiniferites spp., and simultaneous significant increases in Impagidinium spp. and Bitectatodinium tepikiense may indicate a greater intrusion of colder, more oceanic waters into the Ría de Vigo, which may have provoked intensification in upwelling during two periods, ca. 700–850 a.d. and ca. 1500–1750 a.d.     

The Huelva (Spain) Tsunami-Ready Station and Its Interaction with Storm Emma (March 2018)

Abstract

The sea level station operating since 1996 at Mazagón (Huelva, Spain) has been progressively upgraded to fit tsunami warning requirements, due to its location in one of the main regions at risk. Its radar water level sensor was complemented in 2017, with the addition of a pressure sensor. The performance of both sea level sensors and their response to sea level oscillations, at different frequencies, is assessed. Particular emphasis is put on the effect of extreme events, such as Storm Emma, when alternative methods to obtain 1-min data are tested, in contrast to the one based on arithmetic means. The overall differences are small, for the whole period of study (centered-root-mean-square-error below 1?cm, for 5-min, and hourly data; similar tidal parameters and sea level oscillations with periods between 30?s and 5?min). However, during Storm Emma, the pressure sensor presents sensibly lower readings than the radar, with the centered-root-mean-square-error rising to 80?mm on the March 2^nd 2018. A new method to compute 1-min data, based on medians, reduced this value to 10?mm for the same day.     

Influence of upwelling and river runoff interaction on phytoplankton assemblages in a Middle Galician Ria and Comparison with northern and southern rias (NW Iberian Peninsula)

The first oceanographic research (hydrography, nutrient salts, chlorophyll, primary production and phytoplankton assemblages) in a Middle Galician Ria was carried out in Corme-Laxe during 2001, just a year before the Prestige oil spill, being the only reference to evaluate eventual changes in the phytoplankton community. Due to the small size of this ria (6.5 km²), oceanographic processes were driven by the continental water supplied by Anllons River during the wet season (20–30 m³ s⁻¹ in winter), and the strong oceanic influence from the nearby shelf during the dry season. The annual cycle showed a spring bloom with high levels of chlorophyll (up to 14 μg Chl-a L⁻¹) and primary production (3 g C m⁻² d⁻¹) and a summer upwelling bloom (up to 8 μg Chl-a L⁻¹ and 10 g C m⁻² d⁻¹) where the proximity of the Galician upwelling core (<13.5 °C at sea surface) favors the input of upwelled seawater (up to 9 μM of nitrate and silicate) to the bottom ria layer, even during summer stratification events (primary production around 2 g C m⁻² d⁻¹). Thus, phytoplankton assemblages form a “continuum” from spring to autumn with a predominance of diatoms and overlapping species between consecutive periods; only in autumn dinoflagellates and flagellates characterized the phytoplankton community. In the Middle Rias as Corme-Laxe, the nutrient values, Chl-a, primary production and phytoplankton abundance for productive periods were higher than those reported for the Northern (Ria of A Coruña) and Southern Rias (Ria of Arousa) for year 2001; this suggests the importance of the hydrographic events occurring in the zone of maximum upwelling intensity of the Western Iberian Shelf, where a lack of annual cycles studies exists.     

Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.