Late- and post-Variscan cooling and exhumation history of the northern Rhenish massif and the southern Ruhr Basin: new constraints from fission-track analysis

Apatite fission-track analyses were carried out on outcrop and core samples from the Rhenish massif and the Carboniferous Ruhr Basin/Germany in order to study the late- and post-Variscan thermal and exhumation history. Apatite fission-track ages range from 291±15 Ma (lower Permian) to 136±7 Ma (lower Cretaceous) and mean track lengths vary between 11.6 m and 13.9 m, mostly displaying unimodal distributions with narrow standard deviations. All apatite fission-track ages are younger than the corresponding sample stratigraphic age, indicating substantial post-depositional annealing of the apatite fission-tracks. This agrees with results from maturity modelling, which indicates 3500–7000 m eroded Devonian and Carboniferous sedimentary cover. Numerical modelling of apatite fission-track data predicts onset of exhumation and cooling not earlier than 320 Ma in the Rhenish massif and 300 Ma in the Ruhr Basin, generally followed by late Carboniferous–Triassic cooling to below 50–60°C. Rapid late Variscan cooling was followed by moderate Mesozoic cooling rates of 0.1–0.2°C/Ma, converting into denudation rates of <1 mm/a (assuming a stable geothermal gradient of 30°C/km). Modelling results also give evidence for some late Triassic and early Jurassic heating and/or burial, which is supported by sedimentary rocks of the same age preserved at the rim of the lower Rhine Basin and in the subsurface of the Central and Northern Ruhr Basin. Cenozoic exhumation and cooling of the Rhenish massif is interpreted as an isostatic response to former erosion and major base-level fall caused by the subsidence in the lower Rhine Basin.     

Ergebnisse neuer Untersuchungen über Fazies und Bildung von Trias und Jura in Südwest-Deutschland

Ohne Zusammenfassung     

Phthalate esters in the Kiel Bight

Phthalate plasticizers have been accumulated from filtered seawater by liquid—solid adsorption, and in suspended organic matter collected on glass-fibre filters. They were characterized by gas chromatographic retention indices and by their mass spectra. Single-ion detection, focused on m/e 149, was used as a selective and sensitive method to quantify different phthalate esters in Baltic seawater in the 1:10¹⁰–1:10¹¹ concentration range.     

Sedimentary evidence for late Messinian uplift of the SE margin of the Central Anatolian Plateau: Adana Basin,southern Turkey

The Adana Basin of southern Turkey, located at the SE margin of the Central Anatolian Plateau in the vicinity of the Arabia‐Eurasia collision zone, is ideally suited to record Neogene and Quaternary topographic and tectonic changes in the easternmost Mediterranean realm. On the basis of our correlation of 34 seismic reflection profiles with corresponding exposed units along the margins of the Adana Basin, we identify and characterize the seismic facies that corresponds to the upper part of the Messinian Handere Formation (ca. 5.45 to 5.33 Ma), which consists mainly of fluvial conglomerates and marls. The seismic reflection profiles indicate that ca. 1100 km³ of the Handere Formation upper sub‐unit is distributed over ca. 3000 km², reflecting local sedimentation rates of up to 12.5 mm year^?1. This indicates a major increase in both sediment supply and subsidence rates at ca. 5.45 Ma. Our provenance analysis of the Handere Formation upper sub‐unit based on clast counting and palaeocurrent measurements reveals that most of the sediment is derived from the Taurus Mountains at the SE margin of the Central Anatolian Plateau and regions farther north. A comparison of these results with the composition of recent fluvial conglomerates and the present‐day drainage basins indicates major changes between late Messinian and present‐day source areas. We suggest that these changes in drainage patterns and lithological characteristics result from uplift and ensuing erosion of the SE margin of the plateau. We interpret the tectonic evolution of the southern flank of the Anatolian Plateau and the coeval subsidence and sedimentation in the Adana Basin to be related to deep lithospheric processes, particularly lithospheric delamination and slab break‐off.     

Ein Vertikal-Einstab-Pendel zur Messung der Erdgezeitenbedingten Lotschwankungen

Резюме Возможно наблюдать приливнЫе изменения положения стержня с карданной подвеской с помощью соответственно направленнЫх измерительнЫх датчиков. По этому принципу временные изменения направления отвеса измерялисЯ в шахте в г. Фрейберг. Сообщаются и обсуждаются результаты этих исследований.

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Anschrift: Gustav-Zeuner-Strasse, Freiberg/Sa, DDR.     

High-pressure synthesis,long-term stability of single crystals of diboron trioxide,B<Subscript>2</Subscript>O<Subscript>3</Subscript>, and an empirical electronic polarizability of <Superscript>[3]</Superscript>B<Superscript>3+</Superscript>

Single crystals of B₂O₃ are needed for the precise determination of the refractive indices used to calculate the electronic polarizability α of 3-coordinated boron. The α(B) values in turn are used to predict mean refractive indices of borate minerals. Since the contribution of boron to the total polarizability of a mineral is very low, the synthetic compound B₂O₃ represents an ideal model system because of its high molar content of boron. Millimeter-sized crystals were synthesized at 1 GPa in a piston-cylinder apparatus. The samples were heated above the liquidus (800 °C), subsequently cooled at 15 °C/h to 500 °C and finally quenched. The refractive indices were determined by the immersion method using a microrefractometer spindle stage. The refractive indices n _o = 1.653 (3) and n _e = 1.632 (3) correspond to a total polarizability for B₂O₃ of α = 4.877 Å³. These values were used to determine the electronic polarizability of boron of α(B) = 0.16 Å³. Although the surface of the B₂O₃ crystals was coated with a hydrous film immediately after being exposed to air, its bulk crystallinity is retained for a period of at least 2 months.     

Uncertainty management and the dynamic adjustment of deep decarbonization pathways

Contrary to ‘static’ pathways that are defined once for all, this article deals with the need for policy makers to adopt a dynamic adaptive policy pathway for managing decarbonization over the period of implementation. When choosing a pathway as the most desirable option, it is important to keep in mind that each decarbonization option relies on the implementation of specific policies and instruments. Given structural, effectiveness, and timing uncertainties specific to each policy option, they may fail in delivering the expected outcomes in time. The possibility of diverging from an initial decarbonization trajectory to another one without incurring excessive costs should therefore be a strategic element in the design of an appropriate decarbonization strategy. The article relies on initial experiences in France and Germany on decarbonization planning and implementation to define elements for managing dynamic adjustment issues. Such an adaptive pathway strategy should combine long-lived incentives, like a pre-announced escalating carbon price, to form consistent expectations, as well as adaptive policies to improve overall robustness and resilience. We sketch key elements of a monitoring process based on an ex ante definition of leading indicators that should be assessed regularly and combined with signposts and trigger values at the subsector level.

Policy relevance

These research questions are of special interest and urgency following the Paris Agreement in 2015. It calls on all countries to monitor the implementation of their national contributions and review their ambition regularly. The regular revision of decarbonization pathways constitute a great research opportunity to gather experiences on decarbonization pathway implementation and on dynamic management issues to progress towards an operational dynamic adaptive policy pathway mechanism.