Multistage melt/fluid-peridotite interactions in the refertilized lithospheric mantle beneath the North China Craton: constraints from the Li–Sr–Nd isotopic disequilibrium between minerals of peridotite xenoliths

Elemental and Li–Sr–Nd isotopic data of minerals in spinel peridotites hosted by Cenozoic basalts allow us to refine the existing models for Li isotopic fractionation in mantle peridotites and constrain the melt/fluid-peridotite interaction in the lithospheric mantle beneath the North China Craton. Highly elevated Li concentrations in cpx (up to 24 ppm) relative to coexisting opx and olivine (<4 ppm) indicate that the peridotites experienced metasomatism by mafic silicate melts and/or fluids. The mineral δ⁷Li vary greatly, with olivine (+0.7 to +5.4‰) being isotopically heavier than coexisting opx (−4.4 to −25.9‰) and cpx (−3.3 to −21.4‰) in most samples. The δ⁷Li in pyroxenes are considerably lower than the normal mantle values and show negative correlation with their Li abundances, likely due to recent Li ingress attended by diffusive fractionation of Li isotopes. Two exceptional samples have olivine δ⁷Li of −3.0 and −7.9‰, indicating the existence of low δ⁷Li domains in the mantle, which could be transient and generated by meter-scale diffusion of Li during melt/fluid-peridotite interaction. The ¹⁴³Nd/¹⁴⁴Nd (0.5123–0.5139) and ⁸⁷Sr/⁸⁶Sr (0.7018–0.7062) in the pyroxenes also show a large variation, in which the cpx are apparently lower in ⁸⁷Sr/⁸⁶Sr and slightly higher in ¹⁴³Nd/¹⁴⁴Nd than coexisting opx, implying an intermineral Sr–Nd isotopic disequilibrium. This is observed more apparently in peridotites having low ⁸⁷Sr/⁸⁶Sr and high ¹⁴³Nd/¹⁴⁴Nd ratios than in those with high ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd, suggesting that a relatively recent interaction existed between an ancient metasomatized lithospheric mantle and asthenospheric melt, which transformed the refractory peridotites with highly radiogenic Sr and unradiogenic Nd isotopic compositions to the fertile lherzolites with unradiogenic Sr and radiogenic Nd isotopic compositions. Therefore, we argue that the lithospheric mantle represented by the peridotites has been heterogeneously refertilized by multistage melt/fluid-peridotite interactions.     

Supernova Nucleosynthesis, Chemical Evolution, and Cosmic Supernova Rate

In the chemical evolution of the Galaxy, Type II supernovae (SNe II)have contributed to the early metal enrichment and later Type Iasupernovae (SNe Ia) have contributed to the delayed enrichment of Fe.In principle, hypothetical pre-galactic population III objects couldcause the earliest heavy element enrichment. Here we present our twonew findings. 1) The peculiar abundance pattern among iron peakelements (Cr, Mn, Co, and Fe) in the very metal poor can be reproducedwith SN II nucleosynthesis yields without invoking the contributionfrom Pop III objects. 2) The observed chemical evolution in the solarneighborhood is well reproduced with the metallicity dependentoccurrence of SNe Ia, where SNe Ia do not occur if the iron abundanceof the progenitors is as low as [Fe/H] ≲ -1. We make theprediction that the cosmic SN Ia rate drops at z ∼ 1-2 because ofthe low-iron abundance, which can be observed with the Next GenerationSpace Telescope. This revised version was published online in July 2006 with corrections to the Cover Date.     

The effect of back pressure on the contact evolution of a close binary system

The contact condition which includes the effect of pressure in common envelope is derived and employed in the evolutionary calculation of a close binary system in contact phase. The result indicates that the effect is negligibly small and the equality of surface potentials of both components is a sufficiently good approximation for the contact condition.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

Effect of divalent cations on the kinetics of Fe(III) complexation by organic ligands in natural waters

We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca²⁺ and Mg²⁺) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 10⁴ to 3.2 × 10⁶ M⁻¹ s⁻¹. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater.     

Seasonal Variability in Circulation Pattern and Residence Time of Suo-Nada

The development and evolution of the persistent counterclockwise circulation in Suo-Nada have been studied in detail using a three-dimensional numerical model. The realistic circulation has been reproduced from the monthly climatological fields of salinity, temperature along the open boundary, wind, heat flux and buoyancy input from twenty-two major rivers surrounding the basin. The seasonal variation of fresh-water discharge from the rivers proved to be the most important forcing mechanism driving the circulation. The expansion and contraction of coastal low salinity water well corresponded with the development of counterclockwise circulation from spring to summer and dissipation from autumn to winter. The circulation was found to be vertically homogenous and quasi-barotropic. However, confined along the coastal zone is an estuarine flow (i.e., oppositely directed currents in the upper and lower layers) whose horizontal dimension conforms to the period of maximum buoyancy flux from the rivers. This indicates that the flow pattern in Suo-Nada can be separated into two distinct regions where the relative dominance of estuarine circulation plays a significant role. Furthermore, the monthly water exchange capacity for autonomous purification of the basin has been evaluated from the average residence time of conservative material based on the calculated current field. It is demonstrated that the kinetic energy of the basin is directly responsible in promoting water exchange in Suo-Nada. This revised version was published online in August 2006 with corrections to the Cover Date.     

Circulation and Material Transport in Suo-Nada during Spring and Summer

An attempt was made to reproduce the circulation pattern in Suo-Nada, Japan during spring and summer season in order to elucidate the water exchange mechanism in the basin. Two hydrographic surveys at the end of each season were conducted covering the entire Suo-Nada area. A three-dimensional hydrodynamic Princeton Ocean Model (POM) was used to compute the current resulting from the observed density and wind field. During spring, a very pronounced counter clockwise gyre is situated near the opening of the basin. This is replaced by a clockwise circulation which seemed to occupy the whole domain during summer. Within each season, however, the vertical distribution of current does not show any remarkable differences, indicating the dominance of horizontal current and a very weak estuarine flow. These observational and numerical results were used to estimate the remnant function and the corresponding average residence time of permanently dissolved matter (PDM) and transformable matter (TM). The results revealed a small difference in the average residence times of materials within each season but a large seasonal variability between spring and summer. Furthermore, calculations based on climatological density fields have indicated a similar trend of variation between the seasonal values of average residence times. This revised version was published online in July 2006 with corrections to the Cover Date.     

Growth inhibition of a red tide flagellate,Chattonella antiqua by copper

Journal of Oceanography - Copper toxicity inChattonella antiqua (Raphidophyceae) was examined using an artificial seawater medium. The growth rate (Μ) was found to be a unique function of...     

CaseA evolution of massive close binary systems

The caseA evolution of close binary systems with total mass of 20.4M is investigated by following the evolution of both components simultaneously. The evolution is followed up to the stage at which a system overflows the outer critical surface or evolves into the phase of modeBr mass-transfer. It is found that the evolution of the systems can be classified into six types. The ranges of initial parameters which lead systems to each type of evolution are shown on the initial-parameter plane. The evolutionary features of each evolution type are described in detail.