Source of trace element variability in Great Barrier Reef corals affected by the Burdekin flood plumes

Massive corals in the Great Barrier Reef, analyzed at high-resolution for Sr/Ca (thermal ionization mass spectrometry) and trace elements such as Ba and Mn (laser ablation inductively coupled plasma mass spectrometry), can provide continuous proxy records of dissolved seawater concentrations, as well as sea surface temperature (SST). A 10-yr record (1989 to 1998) from Pandora Reef, an inshore reef regularly impacted by the freshwater plumes of the Burdekin River, is compared with an overlapping record from a midshelf reef, away from runoff influences. Surface seawater samples, taken away from river plumes, show little variability for Sr/Ca (8484 ± 10 μmol/mol) and Ba (33.7 ± 0.7 nmol/kg). Discrete Ba/Ca peaks in the inshore coral coincide with flood events. The magnitude of this Ba/Ca enrichment is most likely controlled by the amount of suspended sediments delivered to the estuary, which remains difficult to monitor. The maximum flow rate at peak river discharge is used here as a proxy for the sediment load and is shown to be strongly correlated with coral Ba/Ca (r = 0.97). After the wet summer of 1991, the coral Ba/Ca flood peak is followed by a plateau that lingers for several months after dissipation of plume waters, signifying an additional flux of Ba that may originate from submarine groundwater seeps and/or mangrove reservoirs. Both Mn and Y are enriched by a factor of ∼5 in inshore relative to midshelf corals. Mn/Ca ratios show a seasonal cycle that follows SST (r = 0.7), not river discharge, with an additional high variability in summer suggesting a link with biological activity. P and Cd show no significant seasonal variation and are at a low level at both inshore and midreef locations. However, leaching experiments suggest that part of the coral P is not lattice bound.     

Hydrodynamical non-radiative accretion flows in two dimensions

Two-dimensional (axially symmetric) numerical hydrodynamical calculations of accretion flows that cannot cool through emission of radiation are presented. The calculations begin from an equilibrium configuration consisting of a thick torus with constant specific angular momentum. Accretion is induced by the addition of a small anomalous azimuthal shear stress which is characterized by a function ν . We study the flows generated as the amplitude and form of ν are varied. A spherical polar grid which spans more than two orders of magnitude in radius is used to resolve the flow over a wide range of spatial scales. We find that convection in the inner regions produces significant outward mass motions that carry away both the energy liberated by and a large fraction of the mass participating in the accretion flow. Although the instantaneous structure of the flow is complex and dominated by convective eddies, long-time averages of the dynamical variables show remarkable correspondence to certain steady-state solutions. The two-dimensional structure of the time-averaged flow is marginally stable to the Høiland criterion, indicating that convection is efficient. Near the equatorial plane, the radial profiles of the time-averaged variables are power laws with an index that depends on the radial scaling of the shear stress. A stress in which ν ∝ r ^1/2 recovers the widely studied self-similar solution corresponding to an ' α -disc'. We find that, regardless of the adiabatic index of the gas, or the form or magnitude of the shear stress, the mass inflow rate is a strongly increasing function of radius, and is everywhere nearly exactly balanced by mass outflow. The net mass accretion rate through the disc is only a fraction of the rate at which mass is supplied to the inflow at large radii, and is given by the local, viscous accretion rate associated with the flow properties near the central object.     

Alignment and precession of a black hole with a warped accretion disc

We consider the shape of an accretion disc whose outer regions are misaligned with the spin axis of a central black hole and calculate the steady state form of the warped disc in the case where the viscosity and surface densities are power laws in the distance from the central black hole. We discuss the shape of the resulting disc in both the frame of the black hole and that of the outer disc. We note that some parts of the disc and also any companion star maybe shadowed from the central regions by the warp. We compute the torque on the black hole caused by the Lense–Thirring precession, and hence compute the alignment and precession time-scales. We generalize the case with viscosity and hence surface density independent of radius to more realistic density distributions for which the surface density is a decreasing function of radius. We find that the alignment time-scale does not change greatly but the precession time-scale is more sensitive. We also determine the effect on this time-scale if we truncate the disc. For a given truncation radius, the time-scales are less affected for more sharply falling density distributions.     

Pliocene and Quaternary regional uplift in western Turkey: the Gediz River terrace staircase and the volcanism at Kula

Along the upper reaches of the Gediz River in western Turkey, in the eastern part of the Aegean extensional province, the land surface has uplifted by 400 m since the Middle Pliocene. This uplift is revealed by progressive gorge incision, and its rate can be established because river terraces are capped by basalt flows that have been K–Ar and Ar–Ar dated. At present, the local uplift rate is 0.2 mm a⁻¹. Uplift at this rate began around the start of the Middle Pleistocene, following a span of time when the uplift was much slower. This was itself preceded by an earlier uplift phase, apparently in the late Late Pliocene and early Early Pleistocene, when the uplift rate was comparable to the present. The resulting regional uplift history resembles what is observed in other regions and is analogously interpreted as the isostatic response to changing rates of surface processes linked to global environmental change. We suggest that this present phase of surface uplift, amounting so far to 150 m, is being caused by the nonsteady-state thermal and isostatic response of the crust to erosion, following an increase in erosion rates in the late Early Pleistocene, most likely as a result of the first large northern-hemisphere glaciation during oxygen isotope stage 22 at 870 ka. We suggest that the earlier uplift phase, responsible for the initial 250 m of uplift, resulted from a similar increase in erosion rates caused by the deterioration in local climate at 3.1 Ma. This uplift thus has no direct relationship to the crustal extension occurring in western Turkey, the rate and sense of which are thought not to have changed significantly on this time scale. Our results thus suggest that the present, often deeply incised, landscape of western Turkey has largely developed from the Middle Pleistocene onwards, for reasons not directly related to the active normal faulting that is also occurring. The local isostatic consequences of this active faulting are instead superimposed onto this “background” of regional surface uplift. Modelling of this surface uplift indicates that the effective viscosity of the lower continental crust beneath this part of Turkey is of the order of 10¹⁹ Pa s, similar to a recent estimate for beneath central Greece. The lower uplift rates observed in western Turkey, compared with central Greece, result from the longer typical distances of fluvial sediment transport, which cause weaker coupling by lower-crustal flow between offshore depocentres and eroding onshore regions that provide the sediment source.     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Aridity changes in the Temperate-Mediterranean transition of the Andes since ad 1346 reconstructed from tree-rings

The Andes Cordillera acts as regional ??Water Towers?? for several countries and encompasses a wide range of ecosystems and climates. Several hydroclimatic changes have been described for portions of the Andes during recent years, including glacier retreat, negative precipitation trends, an elevation rise in the 0° isotherm, and changes in regional streamflow regimes. The Temperate-Mediterranean transition (TMT) zone of the Andes (35.5°?C39.5°S) is particularly at risk to climate change because it is a biodiversity hotspot with heavy human population pressure on water resources. In this paper we utilize a new tree-ring network of Austrocedrus chilensis to reconstruct past variations in regional moisture in the TMT of the Andes by means of the Palmer Drought Severity Index (PDSI). The reconstruction covers the past 657?years and captures interannual to decadal scales of variability in late spring?Cearly summer PDSI. These changes are related to the north?Csouth oscillations in moisture conditions between the Mediterranean and Temperate climates of the Andes as a consequence of the latitudinal position of the storm tracks forced by large-scale circulation modes. Kernel estimation of occurrence rates reveals an unprecedented increment of severe and extreme drought events during the last century in the context of the previous six centuries. Moisture conditions in our study region are linked to tropical and high-latitude ocean-atmospheric forcing, with PDSI positively related to Ni?o-3.4 SST during spring and strongly negatively correlated with the Antarctic Oscillation (AAO) during summer. Geopotential anomaly maps at 500-hPa show that extreme dry years are tightly associated with negative height anomalies in the Ross?CAmundsen Seas, in concordance with the strong negative relationship between PDSI and AAO. The twentieth century increase in extreme drought events in the TMT may not be related to ENSO but to the positive AAO trend during late-spring and summer resulting from a gradual poleward shift of the mid-latitude storm tracks. This first PDSI reconstruction for South America demonstrates the highly significant hindcast skill of A. chilensis as an aridity proxy.     

On the use of X-ray and γ-ray telescopes for identifying the origin of electrons and positrons observed by ATIC, Fermi, and PAMELA

X-ray and γ-ray observations can help understand the origin of the electron and positron signals reported by ATIC, PAMELA, PPB-BETS, and Fermi. It remains unclear whether the observed high-energy electrons and positrons are produced by relic particles, or by some astrophysical sources. To distinguish between the two possibilities, one can compare the electron population in the local neighborhood with that in the dwarf spheroidal galaxies, which are not expected to host as many pulsars and other astrophysical sources. This can be accomplished using X-ray and γ-ray observations of dwarf spheroidal galaxies. Assuming the signal detected by Fermi and ATIC comes from dark matter and using the inferred dark matter profile of the Draco dwarf spheroidal galaxy as an example, we calculate the photon spectrum produced by electrons via inverse Compton scattering. Since little is known about the magnetic fields in dwarf spheroidal galaxies, we consider the propagation of charged particles with and without diffusion. Extending the analysis of Fermi collaboration for Draco, we find that for a halo mass ∼10⁹ M_⊙, even in the absence of diffusion, the γ-ray signal would be above the upper limits. This conclusion is subject to uncertainties associated with the halo mass. If dwarf spheroidal galaxies host local magnetic fields, the diffusion of the electrons can result in a signal detectable by future X-ray telescopes.     

Palaeoenvironment reconstruction,volcanic evolution and geochronology of the Cerro Blanco subcomplex,Nevados de Chillán volcanic complex,central Chile

Nevados de Chillán Volcanic Complex, central Chile, has been active for at least 640 ka—a period spanning a number of glacial and interglacial periods. Geologic mapping, radiometric dating and geochemical analysis have identified six new volcanic units and produced four new ⁴⁰Ar/³⁹Ar ages for Cerro Blanco, the northern subcomplex of Nevados de Chillán volcano. Compositions range from dacite to basaltic-andesite and a new geologic map is presented. Examination of lava fracture structures on both newly mapped lavas and those mapped during previous studies has enabled interpretations of former eruptive environments. Palaeoenvironment reconstructions, combined with ⁴⁰Ar/³⁹Ar ages and comparison with the marine oxygen isotope record, show that at least three phases of volcanic activity have occurred during the evolution of Cerro Blanco: (1) a constructive, pre-caldera collapse period; (2) a period of caldera formation and collapse; and (3) a constructive period of dome growth forming the modern day volcanic centre. This style of volcanic evolution, whereby large-scale caldera collapse is followed by growth of a new stratocone is common at Andean volcanoes.