Evidence for ocean acidification in the Great Barrier Reef of Australia

Geochemical records preserved in the long-lived carbonate skeleton of corals provide one of the few means to reconstruct changes in seawater pH since the commencement of the industrial era. This information is important in not only determining the response of the surface oceans to ocean acidification from enhanced uptake of CO₂, but also to better understand the effects of ocean acidification on carbonate secreting organisms such as corals, whose ability to calcify is highly pH dependent. Here we report an ∼200 year δ¹¹B isotopic record, extracted from a long-lived Porites coral from the central Great Barrier Reef of Australia. This record covering the period from 1800 to 2004 was sampled at yearly increments from 1940 to the present and 5-year increments prior to 1940. The δ¹¹B isotopic compositions reflect variations in seawater pH, and the δ¹³C changes in the carbon composition of surface water due to fossil fuel burning over this period. In addition complementary Ba/Ca, δ¹⁸O and Mg/Ca data was obtained providing proxies for terrestrial runoff, salinity and temperature changes over the past 200 years in this region. Positive thermal ionization mass spectrometry (PTIMS) method was utilized in order to enable the highest precision and most accurate measurements of δ¹¹B values. The internal precision and reproducibility for δ¹¹B of our measurements are better than ±0.2‰ (2σ), which translates to a precision of better than ±0.02 pH units. Our results indicate that the long-term pre-industrial variation of seawater pH in this region is partially related to the decadal-interdecadal variability of atmospheric and oceanic anomalies in the Pacific. In the periods around 1940 and 1998 there are also rapid oscillations in δ¹¹B compositions equivalent changes in pH of almost 0.5 U. The 1998 oscillation is co-incident with a major coral bleaching event indicating the sensitivity of skeletal δ¹¹B compositions to loss of zooxanthellate symbionts. Importantly, from the 1940s to the present-day, there is a general overall trend of ocean acidification with pH decreasing by about 0.2-0.3 U, the range being dependent on the value assumed for the fractionation factor α_(B3-B4) of the boric acid and borate species in seawater. Correlations of δ¹¹B with δ¹³C during this interval indicate that the increasing trend towards ocean acidification over the past 60 years in this region is the result of enhanced dissolution of CO₂ in surface waters from the rapidly increasing levels of atmospheric CO₂, mainly from fossil fuel burning. This suggests that the increased levels of anthropogenic CO₂ in atmosphere has already caused a significant trend towards acidification in the oceans during the past decades. Observations of surprisingly large decreases in pH across important carbonate producing regions, such as the Great Barrier Reef of Australia, raise serious concerns about the impact of Greenhouse gas emissions on coral calcification.     

BIFoR FACE: Water–soil–vegetation–atmosphere data from a temperate deciduous forest catchment,including under elevated CO2

The ecosystem services provided by forests modulate runoff generation processes, nutrient cycling and water and energy exchange between soils, vegetation and atmosphere. Increasing atmospheric CO₂ affects many linked aspects of forest and catchment function in ways we do not adequately understand. Global levels of atmospheric CO₂ will be around 40% higher in 2050 than current levels, yet estimates of how water and solute fluxes in forested catchments will respond to increased CO₂ are highly uncertain. The Free Air CO₂ Enrichment (FACE) facility of the University of Birmingham's Institute of Forest Research (BIFoR) is the only FACE in mature deciduous forest. The site specializes in fundamental studies of the response of whole ecosystem patches of mature, deciduous, temperate woodland to elevated CO₂ (eCO₂). Here, we describe a dataset of hydrological parameters – seven weather parameters at each of three heights and four locations, shallow soil moisture and temperature, stream hydrology and CO₂ enrichment – retrieved at high frequency from the BIFoR FACE catchment.     

Fast lagrangian particle tracking in unstructured ocean model grids

Ocean Dynamics - Lagrangian particle tracking, based on currents derived from hydrodynamic models, is an important tool in quantifying bio-physical transports in the ocean. Particle tracking in the...     

A limit on the number density of bright z≈ 7 galaxies

We present a survey of bright optical dropout sources in two deep, multiwavelength surveys comprising 11 widely separated fields, aimed at constraining the galaxy luminosity function at   z ≈ 7  for sources at  5–10  L * ( z = 6)  . Our combined survey area is 225 arcmin² to a depth of   J _AB= 24.2  (3σ) and 135 arcmin² to   J = 25.3  (4σ). We find that infrared data longwards of 2 μm are essential for classifying optical dropout sources, and in particular for identifying cool Galactic star contaminants. Our limits on the number density of high-redshift sources are consistent with current estimates of the Lyman break galaxy luminosity function at   z = 6  .     

Southern high latitude climate variability in the Late Cretaceous greenhouse world

A palynological study of oil exploration wells in the Gippsland Basin southeastern Australia has provided a record of southern high latitude climate variability for the last 12 million years of the Cretaceous greenhouse world. During this time, the vegetation was dominated by a cool to temperate flora of Podocarpaceae, Proteaceae and Nothofagidites spp. at a latitude of 60°S. Milankovitch forced cyclic alternations from drier to wetter climatic periods caused vegetation variability from 72 to 77 Ma. This climate change was probably related to the waxing and waning of ephemeral (100 ky) small ice sheets in Antarctica during times of insolation minima and maxima. Drying and cooling after 72 Ma culminated from 68 to 66 Ma, mirroring trends in global δ¹⁸O data. Quantitative palynofloral analyses have the potential to provide realistic proxies for small-scale climate variability in the predominantly ice-free Late Cretaceous.     

Shortage in the midst of plenty: Labour strategies in four Central and Eastern European cities

Labour shortage was an integral feature of the communist system of economic management and one that seemed most unlikely to persist in the face of systemic transformation. A casual examination of the unemployment rates that have emerged throughout most of Central and Eastern Europe (CEE) during the course of the past decade might suggest that this early assumption was correct. However, within the region the aggregate rate of joblessness, as well as the behaviour of national output, mask the fact that certain, major urban centres appear to have weathered well the storms caused by exposure to western markets and stringent fiscal and monetary policies. In these centres transformation has meant, to a greater or lesser degree, industrial modernisation and this begs the question of whether the human capital portfolios of the inherited labour force match up to the requirements of the new environment. This paper examines the meaning of the concept of labour shortage and presents the findings from a survey of employers in four leading cities of three major CEE economies designed to elicit if, and how, manpower requirements are being met in the present climate. The results indicate that, somewhat paradoxically, labour shortage persists in the more flexible markets of the post-communist era and that firms do not expect the situation to change radically in the near future. This revised version was published online in July 2006 with corrections to the Cover Date.     

Experimental validation of seismic retrofit solutions for URM chimneys

Clay-brick unreinforced masonry (URM) chimneys are a common architectural feature of vintage domestic and commercial URM and timber-framed buildings widely encountered worldwide. URM chimneys include a cantilevered appendage above the roofline that during earthquakes-induced shaking is susceptible to significant damage and collapse, which can result in fatalities, injuries, and property damage. To mitigate this risk, many vintage URM chimneys are removed, braced, or eventually replaced with modern alternatives. The earthquake performance of 15,400 URM chimneys damaged during the 2010/2011 Canterbury earthquake sequence was investigated using a photographic database and insurance claims data. The widespread damage and failure of a large proportion of retrofitted chimneys was the impetus for an experimental shake-table testing campaign that was undertaken to assess the performance of five prototypical URM chimneys in their as-built and retrofitted conditions. Cost-effective retrofit techniques with low aesthetic impact, including the use of near surface mounted carbon-fibre reinforced polymer strips and post-tensioning, were investigated. Tested chimneys were constructed to replicate the most commonly encountered geometric characteristics and construction details collected during an in-field pilot survey of 351 undamaged vintage URM chimneys.     

The Effect of Hydraulic Gradient and Pattern of Conduit Systems on Tracing Tests: Bench-Scale Modeling

Tracer breakthrough curves provide valuable information about the traced media, especially in inherently heterogeneous karst aquifers. In order to study the effect of variations in hydraulic gradient and conduit systems on breakthrough curves, a bench scale karst model was constructed. The bench scale karst model contains both matrix and a conduit. Eight tracing tests were conducted under a wide range of hydraulic gradients from 1 to greater than 5 for branchwork and network-conduit systems. Sampling points at varying distances from the injection point were utilized. Results demonstrate that mean tracer velocities, tracer mass recovery and linear rising slope of the breakthrough curves were directly controlled by hydraulic gradient. As hydraulic gradient increased, both one half the time for peak concentration and one fifth the time for peak concentration decreased. The results demonstrate the variations in one half the time for peak concentration and one fifth the time for peak concentration of the descending limb for different sampling points under differing hydraulic gradients are mainly controlled by the interactions of advection with dispersion. The results are discussed from three perspectives: different conduit systems, different hydraulic-gradient conditions, and different sampling points. The research confirmed the undeniable role of hydrogeological setting (i.e., hydraulic gradient and conduit system) on the shape of the breakthrough curve. The extracted parameters (mobile-fluid velocity, tracer-mass recovery, linear rising limb, one half the time for peak concentration, and one fifth the time for peak concentration) allow for differentiating hydrogeological settings and enhance interpretations the tracing tests in karst aquifers.