Spatio-temporal variation and sensitivity analysis of aerosol particulate matter during the COVID-19 phase-wise lockdowns in Indian cities

Journal of Atmospheric Chemistry - At the pandemic of COVID-19, the movement of business and other non-essential activities were majorly restricted at the end of March 2020 in India and continued...     

Discovery and Significance of Diamonds and Moissanites in Chromitite within the Skenderbeu Massif of the Mirdita Zone Ophiolite, West Albania

In recent years diamonds and other unusual minerals(carbides,nitrides,metal alloys and native elements) have been recovered from mantle peridotites and chromitites(both high-Cr chromitites and high-Al chromitites) from a number of ophiolites of different ages and tectonic settings.Here we report a similar assemblage of minerals from the Skenderbeu massif of the Mirdita zone ophiolite,west Albania.So far,more than 20 grains of microdiamonds and 30 grains of moissanites(SiC) have been separated from the podiform chromitite.The diamonds are mostly light yellow,transparent,euhedral crystals,200~300 μm across,with a range of morphologies;some are octahedral and cuboctahedron and others are elongate and irregular.Secondary electron images show that some grains have well-developed striatums.All the diamond grains have been analyzed and yielded typical Raman spectra with a shift at ~1325 cm~(-1).The moissanite grains recovered from the Skenderbeu chromitites are mainly light blue to dark blue,but some are yellow to light yeUow.All the analyzed grains have typical Raman spectra with shifts at 766 cm~(-1),787 cm~(-1),and 967 cm~(-1).The energy spectrums of the moissanites confirm that the grains are composed entirely of silicon and carbon.This investigation expands the occurrence of diamonds and moissanites to Mesozoic ophiolites in the Neo-Tethys.Our new findings suggest that diamonds and moissanites are present,and probably ubiquitous in the oceanic mantle and can provide new perspectives and avenues for research on the origin of ophiolites and podiform chromitites.     

Outline of the Somalian basement

A sequence of events which has been recognized in the two basement regions of Somalia is outlined on the basis of new field and petrographic data and pre-existing published and unpublished reports. The evolution of the Somalian basement took place during the Pan-African event, However, much detailed work is necessary before the history of the basement can be integrated into the more detailed Pan-African picture recognized in the neighbouring regions.

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Zusammenfassung Eine Folge von Ereignissen, die sich in den zwei Basement-Regionen Somalias erkennen lie\en, wird auf der Basis neuer GelÄnde- und petrographischer Daten und früherer publizierter und nicht publizierter Berichte umrissen. Das Basement von Somalia entwickelte sich wÄhrend des Panafrikanischen Ereignisses.Viel Detailarbeit ist jedoch noch zu leisten, bis die Geschichte des Basements in das detailliertere Bild Panafrikas, wie es aus den Nachbarregionen gewonnen wurde, integriert werden kann.

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Résumé Dans les deux régions de la Somalie ou le socle affleure, on a reconnu une succession d'événements sur la base de nouvelles données géologiques et pétrographiques et de travaux pré-existants, publiés et non publiés. L'évolution du socle de la Somalie se déroula pendant l'événement Pan-Africain. Toutefois, beaucoup de travail doit Être encore fait avant que l'histoire du socle somalien puisse Être intégrée dans un cadre Pan-Africain plus détaillé, tel qu'on le connait dans les régions voisines.

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Groundwater Discharge as a Source of Dissolved Carbon and Greenhouse Gases in a Subtropical Estuary

Groundwater may be highly enriched in dissolved carbon species, but its role as a source of carbon to coastal waters is still poorly constrained. Exports of deep and shallow groundwater-derived dissolved carbon species from a small subtropical estuary (Korogoro Creek, Australia, latitude ?31.0478°, longitude 153.0649°) were quantified using a radium isotope mass balance model (²³³Ra and ²²⁴Ra, natural groundwater tracers) under two hydrological conditions. In addition, air-water exchange of carbon dioxide and methane in the estuary was estimated. The highest carbon inputs to the estuary were from deep fresh groundwater in the wet season. Most of the dissolved carbon delivered by groundwater and exported from the estuary to the coastal ocean was in the form of dissolved inorganic carbon (DIC; 687 mmol m^?2 estuary day^?1; 20 mmol m^?2 catchment day^?1, respectively), with a large export of alkalinity (23 mmol m^?2 catchment day^?1). Average water to air flux of CO₂ (869 mmol m^?2 day^?1) and CH₄ (26 mmol m^?2 day^?1) were 5- and 43-fold higher, respectively, than the average global evasion in estuaries due to the large input of CO₂- and CH₄-enriched groundwater. The groundwater discharge contribution to carbon exports from the estuary for DIC, dissolved organic carbon (DOC), alkalinity, CO₂, and CH₄ was 22, 41, 3, 75, and 100 %, respectively. The results show that CO₂ and CH₄ evasion rates from small subtropical estuaries surrounded by wetlands can be extremely high and that groundwater discharge had a major role in carbon export and evasion from the estuary and therefore should be accounted for in coastal carbon budgets.     

A new approach for estimating the transverse surface settlement curve for twin tunnels in shallow and soft soils

Increasing demand on infrastructures has led to increased attention to shallow soft ground tunneling methods in urbanized areas. Especially in metro tunnel excavations, it is important to control the surface settlements which are observed before and after excavation, which may cause damage to surface structures. Unlike motorway, sewage and other infrastructure tunnels, metro tunnels generally have to be excavated as twin tunnels and must have a larger diameter. Metro tunnels also have shallow depth. Due to their shallow depth, metro tunnels generally have been constructed in weak rocks or weak soils in cities. The construction of twin tunnels will generate ground movements which have the potential to cause damage to existing surface and subsurface structures. To solve this settlement problem, experts have used the Earth pressure balance machine (EPBM) and the slurry balance machine. In such excavations, especially in twin tunnels, the main challenges for constructers are estimating the maximum surface settlement, controlling the interaction of transverse surface settlement and shaping the settlement curve. Incorrect estimation of these parameters can lead to significant problems above the tunnels and in nearby structures. This paper focuses on surface settlement measurements, on the interaction of twin tunnel transverse surface settlement and on the relationship between shield parameters and transverse surface settlement for parallel tunnels using EPBM shields in clay and sand soils in shallow depth. Also, a new equation is proposed for estimating the transverse settlement curve of twin tunnels. The results from this proposed equation are compared with the results of field observations. The transverse settlement curve values obtained from the proposed equation have good agreement with the actual results for the Otogar–Kirazli metro case studies.     

Evaluating the geothermal heat pump potential from a thermostratigraphic assessment of rock samples in the St. Lawrence Lowlands,Canada

The installation cost and the performance of geothermal heat pump systems are influenced by the thermal state and properties of the subsurface. The ground ability to transfer heat described by thermal conductivity is a dominant factor affecting the favorability of closed-loop ground heat exchangers installed in vertical boreholes. A study that aimed at evaluating the geothermal heat pump potential by mapping the thermal conductivity of rock sequences was, therefore, performed for the St. Lawrence Lowlands sedimentary basin in Canada. Thermal conductivity was measured in the laboratory on rock samples collected in outcrops and used to complete design calculations of a geothermal system with a single borehole. Results allowed the definition of thermostratigraphic units that can be linked to depositional environments. Basal quartz-rich sandstones formed in a rift environment show a high geothermal potential. Overlying dolomites, argillaceous limestones and shales deposited in a passive margin evolving to a foreland basin exhibit a transition toward the top from high to low geothermal potential. Upper turbidites and molasses have a moderate geothermal potential. The thermal conductivity of the thermostratigraphic units is dominantly influenced by the mineralogy of the sedimentary rocks. Understanding their origin is a key to improve geothermal resource assessment and system design to anticipate new installations in the area.     

The Southern Sudanese migration to Khartoum and the resultant conflicts

Today, more than one third of the population of Khartoum are southerners who migrated to the capital mainly in the last eight years because of the civil war. Their conditions are very bad. They are starving in the town, for most of them are unemployed and have no means of living. Their housing conditions in the shanty towns are deplorable. The development of squatter settlements and the struggle for the demarcation of quarters are delineated in this paper. In Khartoum the southerners develop a strong sense of solidarity and develop a growing supra-southern-Sudanese identity replacing the former ethnic and local identities.     

Palynological studies in the western arm of Lake Superior

Lake Superior sediments contain pollen whose changes through time can be corelated with dated pollen diagrams from small lakes in the region. A core collected in 1972 from the deep trough (265 m) off Silver Bay (47° 09′N, 91°20′W) penetrated 6.25 cm of taconite tailings, 55 cm of postglacial silty clay, and 93.5 cm of late-glacial varves. Seven levels in the core were dated by stratigraphic and palynological techniques. The varves stopped forming about 9000 years ago, probably when glacial ice retreated to the north shore. The last 100 varves accumulated at about 10 mm/yr, but the average net sedimentation rate subsequently slowed to 0.05 mm/yr until the time of settlement about 1890. The sedimentation rate then increased by a factor of 10, to 0.5 mm/yr until 1956 when taconite processing began. The postsettlement interval can be recognized by marked increases of ragweed and chenopod pollen that result from land disturbance caused by forest clearance and agriculture. The postsettlement interval is also present at the top of six cores from four other sites in western Lake Superior, collected in water from 25–140 m deep. The postsettlement sedimentation rate varies from 0.1–0.8 mm/yr, suggesting that man has greatly increased sediment yield to the lake in the last 80 years.