Sampling Methane-Bearing Coal Seams by Freezing Method: Coalbed Methane Desorption and Inhibition Characteristics Under Freezing Temperature

Methane content in coal seam is an essential parameter for the assessment of coalbed gas reserves and is a threat to underground coal mining activities. Compared with the adsorption-isotherm-based indirect method, the direct method by sampling methane-bearing coal seams is apparently more accurate for predicting coalbed methane content. However, the traditional sampling method by using an opened sample tube or collecting drill cuttings with air drilling operation would lead to serious loss of coalbed methane in the sampling process. The pressurized sampling method by employing mechanical-valve-based pressure corer is expected to reduce the loss of coalbed methane, whereas it usually results in failure due to the wear of the mechanical valve. Sampling of methane-bearing coal seams by freezing was proposed in this study, and the coalbed gas desorption characteristics under freezing temperature were studied to verify the feasibility of this method. Results show that low temperature does not only improve the adsorption velocity of the coalbed gas, but also extend the adsorption process and increase the total adsorbed gas. The total adsorbed methane gas increased linearly with decreasing temperature, which was considered to be attributed to the decreased Gibbs free energy and molecular average free path of the coalbed gas molecular caused by low temperature. In contrast, the desorption velocity and total desorbed gas are significantly deceased under lower temperatures. The process of desorption can be divided into three phases. Desorption velocity decreases linearly at the first phase, and then, it shows a slow decreases at the second phase. Finally, the velocity of desorption levels off to a constant value at the third phase. The desorbed coalbed gas shows a parabolic relation to temperature at each phase, and it increases with increasing temperature at the first phase, and then, it poses a declining trend with increasing temperature at the rest phases. The experimental results show that decreasing the system temperature can restrain desorption of coalbed methane effectively, and it is proven to be a feasible way of sampling methane-bearing coal seams.

     

印尼沿岸灾害性海浪模拟研究

印尼沿岸易受气旋生浪和咆哮西风带产生的涌浪的侵蚀,但其海浪发展及传播机理尚不明确,给海岸工程建设和防护带来极大困扰。本文基于第三代海浪模式WAVEWATCH Ⅲ,采用CCMP交叉校正多平台海洋表面V2.0风场(Cross-Calibrated Multi-Platform Ocean Surface Wind Velocity)作为驱动风场,建立自整个印度洋至印尼沿岸的三级嵌套海浪模型,模拟咆哮西风带及热带气旋作用下印尼沿岸灾害性海浪,并研究其海浪分布及传播特性。结果表明:(1)咆哮西风带单独作用下,印尼沿岸盛行南向海浪,有效波高等值线沿东北方向平行递减,海浪谱为多峰,西南向涌浪占主导地位,能量集中分布于60°—90°范围,呈现北传特性;(2)咆哮西风带和热带气旋联合作用下,气旋路径左侧出现涌浪低值区,东南向风浪主导,风浪能量集中分布于110°—130°范围,路径右侧西北向风浪和南向涌浪并存,60°—90°附近涌浪波动能量占主导,风浪能量集中在210°附近;近岸浅水海域涌浪能量主导,开敞海域涌浪能量集中在60°—90°范围,有掩护海域涌浪能量峰值位于0°附近。     

东北地区湿地的特点及形成与演替机制

东北地区湿地类型众多.通过分析解剖东北地区湿地的形成与演替机制,揭示了湿地的形成与演替过程中同时承受着自然与人为两种不同性质驱动力的影响,指出人类活动外在驱动力在较小的时空尺度下起着主导作用,如不加以正确引导而盲目开发,势必将导致湿地环境的恶化.     

Relationship between stand characteristics and soil properties of two typical forest plantations in the mountainous area of Western Sichuan,China

There is uncertainty and limited knowledge regarding stand characteristics and soil properties of middle-aged pure forest plantations in the mountainous area of Western Sichuan. Plantation forests are almost exclusively planted as monocultures in the Pengzhou forest farm in the western mountainous area of Sichuan Province. This study aimed to assess the spatial and ecological characteristics of middle-aged Cunninghamia lanceolata(Lamb.) Hook. and Cryptomeria fortunei Hooibr. in the Pengzhou forest farm. The relationships and differences between stand growth characteristics and forest soil composition were assessed on the two forests planted simultaneously within the same area and exposed to the same environmental conditions. Cr. fortunei grew sparse, and slower than Cun. lanceolata. Principal component analysis indicated that the soil properties in the Cr. fortunei plantation were better than those in the Cun. lanceolata plantation. Redundancy analysis revealed that the differences in stand structure were affected significantly by the total nitrogen content and pH value. Thus, we propose that Cr. fortunei is planted for priority consideration in the subtropical high mountain area. Further, tending operations and application of fertilizers need to be conducted in Cun. lanceolata forests. Based on theoretical and experimental data, the present study explains why local farmers are more willing to plant Cr. fortunei, and thus provides a useful theoretical reference for the development of sustainable plantations in the future.     

人工冻土观测的冻点对应的土壤温度研究

基于2018年12月至2020年3月喀左、沈阳、辽阳、满洲里4个国家级地面气象站人工冻土器与测温式冻土自动观测仪观测的资料,对人工冻土观测获得的冻点与测温式冻土自动观测仪获得的相应深度的温度进行对比分析.结果表明:人工冻土器获取的冻点对应的土壤温度与0℃总体一致,又不完全重合;0—35 cm深度范围,冻点对应的温度变化...     

基于FY-4A卫星和随机森林算法的西藏山南市雷电短临预报方法

针对青藏高原地区雷电短临预报缺乏雷达资料的问题,采用FY-4A卫星多通道数据、欧洲中心第5代再分析资料(ERA5)中的对流指数、闪电定位仪资料等多源监测数据,根据雷电的发生、发展机理,提出了18个关键预报因子,利用随机森林算法建立了适用于西藏山南地区的雷电短临预报模型。统计分析各预报因子在有无雷电天气样本中的概率密度分布与随机森林模型得到的特征重要度指标,结果表明提出的预报因子物理意义明确,建立的模型可信度较高。利用随机森林算法分别对未来10 min、20 min、30 min建立雷电预报模型,并与光流外推预报方法进行对比检验,结果表明：随机森林模型预报效果命中率(POD)、临界成功指数(CSI)均高于光流法,空报率(FAR)也相对较低;未来20 min的随机森林预报模型CSI评分最高,整体预报效果最佳。     

东海海底三柱状岩心重矿物分布研究

对东海沿岸陆架CJ08—630、CJ08923、CJ08—11853个柱状岩心56个重矿物样品63～125μm粒级重矿物的研究表明,重矿物种类有56种,最高含量可达53．1％,平均含量较低,为8．5％。矿物组成以闪石类、帘石类、辉石类、片状矿物、自生黄铁矿及金属矿物磁铁矿、褐铁矿等为主。重矿物来源复杂多样,包括陆源、自生等,其中沿岸河流输入物是主要陆源矿物来源,此外还有沿岸和岛屿等的剥蚀物、冲刷物。沉积环境是影响重矿物分布的主要因素。     

Heterogenous zircons from Mesozoic igneous rocks in the North China Craton and their tectonic implications

Based on a synthesis of zircon inheritance from Mesozoic igneous rocks in the eastern portion of the North China Craton （NCC） , it is proposed that inherited zircons with Neoproterozoie ages identified from these rocks are of a heterogenous derivation from the Yangtze/South China block, rather than from the NCC itself. The mechanism that introduces these zircons incorporated into the NCC is likely by tectonic underplating during the Triassic continental subduction of the Yangtze block beneath the NCC. Tectonic addition of abundant crustal materials represented by the heterogenous zircons into the NCC, probably along Moho or weak interfaces within the NCC＇s crust, led to the crustal thickening in the NCC. These heterogenous materials, either as （partial） source rocks or as contaminants of the magmas generated during an extension environment following the crustal thickening, were reworked and therefore have significant contribution to petrogenesis of the Mesozoic igneous rocks. The crustal thickening resulted from the tectonic underplating, as indicated by the distribution extent of the heterogenous zircons, is spatially similar to that of the lithospheric thinning, with both mainly occurring in the eastern segment of the NCC. This is probably suggestive of an intrinsic relation between the thickening and thinning events during the Mesozoic evolution of the NCC.     

1株分离自海水中芘降解菌的鉴定及其降解特性研究

以芘为唯一碳源,对采自于天津港石油污染区的海水和土壤样品进行富集培养,分离到1株芘降解菌,经显微形态观察、生理生化鉴定、16S rRNA基因序列的比对及系统发育进化的分析,确定该菌株为施氏假单孢菌Pseudomonas stutzeri,并采用室内培养方法,对其进行了芘降解性能的测定及降解途径的分析.结果表明,该菌株在...     

长江和长江口高含量无机氮的主要控制因素

根据1998－1998年长江和长江口河水和雨水的现场调查、历史资料以及相关文献，定量分析长江流域无机氮的主要来源和输送调查。估算表明，降水无机氮、农业非点源氮（化肥和土壤流失的氮）和点源污水氮的输入分别占长江口无机氮输出通量的62．3％、18．5％和14．4％。氮的降水输入是长江口高含量无机氮的主要来源，进入长江的降水氮仅仅大约占长江流域全部降水氮的36．8％。降水米要受控于化肥气态损失、化石燃料及动植物过程中释放的物质等。实际上，化肥N的气态损失和农业非点源流失大约占长江流域年化肥N使用量的60％，这是控制长江口高含量无机氮的关键因素。