青海省治多县查涌铜多金属矿床成矿年代学研究

三江"成矿带为我国重要的多金属成矿带,带内中北段玉树多彩矿集区发育多种类型的铜多金属矿床,资源潜力巨大,但成矿年龄不详,严重制约了对矿床和区域成矿规律的理解。因此,本次工作选取矿集区西北部查涌铜多金属矿床为研究对象,在详细地质踏勘的基础上,对其成矿年代进行了系统研究,以期填补该地区此类型矿床成矿年龄的空白。研究表明,查涌铜多金属矿床分别发育Cu-Mo矿体和Pb-Zn矿体,Cu-Mo矿体赋存在变质粉砂岩内,形成于石英硫化物阶段。角岩化砂岩中黑云母Mg-(Al^Ⅵ+Fe^3++Ti)-(Fe^2++Mn)的投图具镁质黑云母特征,Al2O3/Ti O2值介于6.359~10.087之间,Fe^2+/(Fe^2++Mg)值均一,为热液成因,且未受后期流体改造,40Ar-^39Ar同位素定年获得黑云母封闭年龄为129.59±1.58 Ma。穿切黄铜矿的辉钼矿Re含量为0.864×10^-6~9.624×10^-6,具壳源属性,其Re-Os同位素等时线年龄为124.75±0.86 Ma。热液黑云母与较晚的辉钼矿年龄相近,应为同期岩浆热液事件的产物。本次研究精确厘定了"三江"带中北段内一例典型的与岩浆热液成矿作用相关铜多金属矿床的成矿年龄,揭示出早白垩世的一期成矿事件,为"三江"成矿带的成矿规律总结和勘查找矿指明了新的方向。     

煤层气富集高产的主控因素

对煤岩的生储气能力、煤储层渗透率、煤层气保存条件等影响煤层气高产富集的主控因素进行了分析。煤岩组分和煤变质程度是影响煤层生储气能力的主控因素。煤层的储气能力与温度、压力、灰分及水分含量等亦有关。煤层的渗透率取决于煤层本身的裂隙系统,而裂隙的发育程度又与煤变质程度及构造活动的强弱相关。煤层气的保存则取决于顶底板的封盖能力、构造活动、水动力环境等条件。煤层气成藏条件是煤层气基础地质研究中的核心问题,应加强研究。     

准噶尔盆地石南地区清水河组一段层序地层特征

清水河组一段是石南31井区岩性油藏、石南44井区微幅构造油藏及整个腹部地区的重要产层，探究其层序地层特征对于指导研究区及整个腹部地区清水河组一段的隐蔽油气藏勘探有重要意义。通过对岩心、测井、地震等资料综合分析，指出清水河组一段相当于下白垩统第一个三级层序的低位及湖侵体系域。其层序地层特征显著，表现为:低位体系域以沟谷残余可容纳空间充填沉积为特点，分布较为局限，沟谷主要沉积辫状河道砂砾岩；湖侵体系域以退积型三角洲和三角洲前缘滑塌浊积扇沉积为主。建立了石南31井区的成藏模式，并指出三南凹陷中西部是岩性—地层油气藏勘探的有利区带。沟谷砂砾岩及三角洲前缘滑塌浊积扇可形成岩性圈闭，退积型三角洲可形成地层超覆圈闭；湖侵体系域顶部的泥岩可做为区域盖层；斜坡古地貌、深大断裂—中浅层断裂系统与不整合匹配为有效的输导体系。     

渤海湾盆地东濮凹陷古近系古湖盆氧化还原条件及其优质烃源岩的发育模式

通过分析东濮凹陷古近系沙河街组烃源岩样品的主微量元素含量,研究了东濮凹陷沙河街组优质烃源岩形成时的古氧化还原条件、古生产力水平及古水体的局限性,探讨了沙河街组沙三段优质烃源岩的发育模式。研究结果表明,东濮凹陷的北部沙三段优质烃源岩发育属于“深水窄盆水体分层沉积”模式。水体主要是咸水—超咸水,水体局限性较强,深度较深形成了稳定的盐度分层,从而造成底层水处于稳定的缺氧条件,有利于有机质的保存。根据主微量元素分析及古生产力的还原,沙三段沉积时水体表层富氧,发育大量有机质,生物死亡后有机质发生絮凝,在氧化还原界面吸附于铁锰氧化物的表面,沉降到底部,底部水体缺氧到还原的性质,适合保存有机质。东濮凹陷南部沙三段优质烃源岩发育属于“浅水广盆凹盆缺氧沉积”模式。湖泊水体为淡水,湖水局限性很弱,属于开阔水域,由于地表河流及洪水带来大量营养物质,表层水体古生产力较高,缺乏缺氧的保存条件,有机质生化阶段消耗较多,但是局部也可以发育弱还原水体,进而形成优 质烃源岩。     

我国各地膨润土的矿物学性质

运用X射线衍射分析技术对我国不同产地膨润土的矿物学性质进行考察；利用K值法测蒙脱石含量。实验表明，各地膨润土具有蒙脱石的含量较高且均为二八面体的矿物学特点；可能由于所处的矿层或局部地球化学环境不同，使得相同矿床的不同颜色膨润土矿物的蒙脱石含量有所差异。     

南海北部珠江口盆地中段伸展构造模型及其动力学

位于南海北部大陆边缘上的珠江口盆地发育NNE向、NE向、NW向、近EW向等多组基底断裂,盆地结构复杂,并表现出明显的时空差异性。本文基于珠江口盆地中段地震资料解释的构造样式的变化推断地壳中存在一条向南缓倾斜、呈坡坪式形态的拆离断层,古近系构造属于这条拆离断层上盘的伸展构造系统。北部的西江凹陷属于拆离断层伸展构造系统的头部,凹陷边界正断层铲式断层面形态向深层延伸并收敛在拆离断层面上,凹陷表现为半地堑“断陷”样式;中部的番禺低隆起对应于拆离断层的低角度断坪部位,拆离断层上盘断块的伸展位移导致两侧的恩平组超覆在低隆起上;南部的白云凹陷位于拆离断层的深部断坡部位,充填的文昌组和恩平组表现为“断坳”或“坳断”样式;南部隆起位于拆离断层深部断坪部位,其上盘发育的分支断层控制着荔湾凹陷古近系、新近系的发育并使之表现为复杂的断陷断坳构造样式。该模型强调拆离断层上盘与下盘、不同地壳结构层均发生不同程度的伸展变形,且伸展变形方式、应变量等存在时空差异,而拆离断层正是不同构造单元、不同地壳构造层之间的调节性构造面。总体上,拆离断层上盘以脆性伸展构造变形为主,分支断层控制不同构造单元古近纪的构造演化,下盘则是以韧性伸展变形为主,并拖曳上盘发生不均一的伸展应变;西江凹陷的伸展应变量大于拆离断层下盘的伸展应变量,白云凹陷的伸展应变量则小于拆离断层下盘的伸展应变量。以西江凹陷北部边缘的NE向铲式正断层为头部的拆离断层控制了文昌组沉积,但在恩平组沉积期被近EW向高角度正断层切割破坏而被遗弃,拆离断层系统的头部由西江凹陷北部边缘迁移至番禺低隆起。盆地结构及断裂系统的时空差异性受盆地基底先存构造、地壳与岩石圈结构及伸展量等多方面因素的影响,但主要是对软流圈流动及岩石圈热结构变化的响应。用软流圈由北西向南东流动拖曳上覆岩石圈发生伸展变形的动力学模型能合理地解释珠江口盆地中段古近系构造的形成和演化。     

河西内陆河流域水资源及其动态变化

The Qilian Mountains is the cradle of all inland rivers in the Hexi arid region. The mountain glaciers are an important water resources for this region. Changes of the mountain runoffs resulted from global climate warming will have important impacts on the development of human society and economy in the region. In this paper, the river runoffs from the Qilian Mountains and their dynamic changes are analyzed on the basis of the instrumental data of precipitation, air temperature, and discharge from the weather and hydrological stations in the study area. The results show that the annual change in the mountain runoffs is affected mainly by precipitation in the east of the region, but also by temeprature in the west of the region. There are some obvious regional differences in the influence of climatic change on surface runoffs in the Hexi region. River runoffs in the western part of the Hexi region have been increasing, whereas those in the eastern part have been decreasing. River runoffs in the central part such as the Heihe River, present a slow increasing trend, although it is not quite visible     

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.     

不同产地绿松石无损检测及岩相结构特征研究

概述了绿松石的使用历史和产地来源。利用质子激发X射线荧光光谱（PIXE）、X射线衍射（XRD）及扫描电镜（SEM）技术对来自伊朗、湖北郧县和西藏等地的绿松石样品进行岩石矿物学特征分析，从成分组成方面探讨绿松石的呈色机理。结果显示，不同产地、不同质地绿松石的成分组成存在较大差别，但主成分含量基本一致；绿松石的颜色主要由其中CuO和Fe2O3的含量比值变化决定，比值由大至小，实现了绿松石颜色由天蓝色到绿色的转变。     

武当地块基性岩席群及其地质意义

侵位于武当地块内部的大量的板状为基性侵入体近年来一直被认为是800Ma左右发生的扬子古大陆裂解的重要依据。然而作者在武当地块北缘与西南部所做的1：5万地质填图以及相应的构造学和同位素年代学研究表明，它们与武当地块顺层伸展滑脱构造主滑脱面之顺层韧性一韧性变形带有密切的空间关系，是被褶皱了的岩席群。最新获得的岩体单颗粒锆石U－Pb年龄为401－407Ma，结合已有的地球化学研究成果，并考虑到邻区同时代碱性岩浆的侵位，作者认为，这套基性岩群代表了泥盆纪时南秦岭地区曾发生过大规模的上地幔岩浆的底侵作用，并因此导致南秦岭上部地壳的伸展减薄。