White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Regional tectonic trends on the inner continental shelf off Konkan and Central West Coast of India

Satellite imagery and offshore magnetic data were analysed to correlate regional tectonic elements on the inner continental shelf off Konkan and the adjacent Deccan plateau. Three statistically important lineament trends—N-S, WNW-ESE and ENE-WSW—that prevail on land are correlatable well with the offshore trends. This positive correlation suggests simultaneous deformation. The major magnetic lineament observed off Jaigad Bay, west coast of India, may be the extension of onshore lineaments. The correlation of both the offshore and onshore trends indicates that the fracture pattern of the crystalline basement has also controlled the offshore structural pattern.     

China's population: an alternative perspective

The author presents a selection of cartograms designed to illustrate aspects of the demography of China. Topics covered include population growth, density, regional variations in fertility, and age distribution. A discussion of the advantages of using cartograms (maps drawn proportional to a given variable) as opposed to conventional, area-based maps, is included.     

The homologous flare events in solar active regions

This paper consists of two parts. We first discuss recent general results on the study of properties of flare homology, and their relevance to the physical interpretation of the flare phenomenon at large. We devote particular attention to the discovery of homologous flares which occur in rapid succession, within a few minutes of each other in many cases. We name these kind of flares rafales. These flares signal the existence of several episodes of energy release within the same magnetic configuration. We also show the existence of particular sites in the solar atmosphere which have peculiar characteristics in terms of solar rotation, and where recurrent flaring may take place over and over again in different solar rotations. This indicates that the disturbance causing the emergence of activity is deep seated, below the solar photosphere. Finally, in the second part, we discuss an extensive set of observations of two homologous flares of a rafale, stressing the dynamic aspects of the observations, particularly the presence of peaks in the vertical component of the velocity field. These results are shown to be in agreement with studies of filament activations and the surging arches which are observed before the flash phase of solar flares.     

Far beyond the Gulf: the implications of warfare for Asian labour migration

The implications of the Gulf War are assessed for the countries in Asia that send labor migrants to the Middle East. "This paper seeks to examine the effects of...the loss of remittances (and related issues, including return migration), primarily in terms of the long-term implications of the War for the future of contract labour migration in the Asian region...."     

Labour circulation and the village economy in Fiji

The author examines circular labor migration in Fiji. "This paper is organized into five sections. The first section provides a brief discussion of two major perspectives of labour circulation in developing countries. The second section presents the state of the Fijian village in the context of the current pattern of uneven development in Fiji. The practice of labour circulation by Fijian villagers is dealt with in the third section. In the last two sections, issues concerning the maintenance of the polarized pattern and the preservation of the village mode of production are discussed."     

Rosat wide field camera data and the temperature of the interstellar medium

The shadowing effects of the molecular clouds in the nearby interstellar medium on the soft x-ray background has been investigated, using ROSAT WFC data in conjunction with previous rocket B and C band surveys. Shadowing over a 5° extent occurs only for a few percent of the sky, but the mixed model of the ISM is supported.Detailed modelling of the Draco shadowing region shows little evidence for a multi-temperature, hot ISM component.