Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Seasonal soil water storage changes beneath central Amazonian rainforest and pasture

Evaporation and infiltration were compared for tropical rainforest and pasture, near to Manaus, Brazil from October 1990 to February 1992 using measurements of soil water storage over a depth of 2 m. The soil is a clayey oxisol of low water available capacity. In both of the dry seasons studied, the maximum change in soil water storage in the forest was 154 mm and in the pasture it was 131 and 112 mm. Similar behaviour of the soil water reservoir below forest and pasture in the wet season implied that differences in evaporation and drainage were small. In the dry season, soil water storage behaviour in the upper metre of the soil was similar but there were marked differences in the second metre. The pasture took up little water from below 1.5 m but the forest appeared to utilise all of the available water in the 2 m profile in both seasons.

The water balance of the 2 m profile showed that the pasture evaporation rate was equal to that of the forest until storage had decreased 80 mm from the maximum. There was then a decline in pasture evaporation rate to 1.2 mm day⁻¹ as the storage decreased by a further 50 mm. In contrast, the forest uptake rate remained above 3.5 mm day⁻¹ until storage had decreased 140 mm from the maximum (within 15 mm of the extraction limit), before declining abruptly to less than 1.5 mm day⁻¹. There was strong evidence that the forest was able to abstract water from depths greater than 3.6 m.

Spatial variability of soil water storage was significantly greater beneath the pasture than beneath the forest, particularly following rainfall events in the dry season. This was largely the result of redistribution of rainfall as local surface runoff. There was no evidence of redistribution or runoff in the forest.     

Two‐dimensional physically based finite element runoff model for small agricultural watersheds: I. Model development

Soil erosion by water is the root cause of ecological degradation in the Shiwalik foothills of Northern India. Simulation of runoff and its component processes is a pre‐requisite to develop the management strategies to tackle the problem, successfully. A two‐dimensional physically based distributed numerical model, ROMO2D has been developed to simulate runoff from small agricultural watersheds on an event basis. The model employs the 2‐D Richards equation with sink term to simulate infiltration and soil moisture dynamics in the vadoze zone under variable rainfall conditions, and 2‐D Saint‐Venant equations under the kinematic wave approximation along with Manning's equation as the stage‐discharge equation for runoff routing. The various flow‐governing equations have been solved numerically by employing a Galerkin finite element method for spatial discretization using quadrilateral elements and finite difference techniques for temporal solutions. The ROMO2D computer program has been developed as a class‐based program, coded in C + + in such a way that with minor modifications, the model can be used to simulate runoff on a continuous basis. The model writes output for a runoff hydrograph of each storm. Model development is described in this paper and the results of model testing and field application are to be presented in a subsequent paper. Copyright © 2008 John Wiley & Sons, Ltd.     

Structure Function Analysis of Two-Scale Scalar Ramps. Part II: Ramp Characteristics and Surface Renewal Flux Estimation

Ramp features in the turbulent scalar field are associated with turbulent coherent structures, which dominate energy and mass fluxes in the atmospheric surface layer. Although finer scale ramp-like shapes embedded within larger scale ramp-like shapes can readily be perceived in turbulent scalar traces, their presence has largely been overlooked in the literature. We demonstrate the signature of more than one ramp scale in structure functions of the turbulent scalar field measured from above bare ground and two types of short plant canopies, using structure-function time lags ranging in scale from isotropic to larger than the characteristic coherent structures. Spectral analysis of structure functions was used to characterize different scales of turbulent structures. By expanding structure function analysis to include two ramp scales, we characterized the intermittency, duration, and surface renewal flux contribution of the smallest (i.e., Scale One) and the dominant (i.e., Scale Two) coherent structure scales. The frequencies of the coherent structure scales increase with mean wind shear, implying that both Scale One and Scale Two are shear-driven. The embedded Scale One turbulent structure scale is ineffectual in the surface-layer energy and mass transport process. The new method reported here for obtaining surface renewal-based scalar exchange works well over bare ground and short canopies under unstable conditions, effectively eliminating the α calibration for these conditions and forming the foundation for analysis over taller and more complex surfaces.     

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.     

Investigation of a eutrophic tidal basin: part 1—factors affecting the distribution and biomass of macroalgae

The distribution and biomass of macroalgae, principally Enteromorpha spp., have been estimated in Langstone Harbour, a 19 km² tidal basin in southenrn England. Comprehensive mapping was carried out annually at the time of maximum biomass and monthly mapping of selected areas allowed seasonal changes to be studied. Aerial false-colour photography and ground-level mapping were used for assessing the area and density of cover of macroalgae, but have identified no continuous trends between 1973 and 1982. In nine years, some 48% of the intertidal mudflat has supported >75% macroalgal cover at some stage, but generally only one-third of this potential has been achieved annually. The average peak biomass was determined by a stratified sampling method and varied about a mean of 38.5 g dry weight per square metre and showed significant annual differences. The processes controlling macroalgal growth and distribution reviewed, but, in general, factors other than nutrient availability are effective in determining areas supporting high macroalgal cover in any particular year.     

Tellurides from Sunrise Dam gold deposit, Yilgarn Craton, Western Australia: a new occurrence of nagyágite

Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.     

Application of sodars in the study and monitoring of the environment

Summary Application of acoustic sounders (sodars) to study the atmospheric boundary layer (ABL) began in the early 1970s. During the last two decades the scope of sodars applications enlarged considerably. The proceedings of eleven symposia of the International Society for Remote Acoustic Sensing of the Atmosphere and Oceans (ISARS) are a unique collection of papers, where all directions of the sodar use since 1981 are presented. In this paper, a review of sodar applications to atmospheric research is presented based on materials published in these proceedings in the following fields: conditions of microwave and light propagation; regional climatology of the ABL; air pollution meteorology and weather forecast; mesoscale phenomena under stable and unstable stratification; micrometeorology; peculiarities of the ABL in remote and complex terrain.     

New Models for Long Range Forecasts of Summer Monsoon Rainfall over North West and Peninsular India

Summary New models based on (a) Multivariate Principal Component Regression (PCR) (b) Neural Network (NN) and (c) Linear Discriminant Analysis (LDA) techniques were developed for long-range forecasts of summer monsoon (June–September) rainfall over two homogeneous regions of India, viz., North West India and Peninsular India. The PCR and NN models were developed with two different data sets. One set consisted 42 years (1958–1999) of data with 8 predictors and the other, 49 years (1951–1999) of data with 6 predictors. The predictors were subjected to the Principal Component Analysis (PCA) before model development. Two different neural networks were designed with 2 and 3 hidden neurons. To avoid the nonlinear instability, 20 ensemble runs were made while training the network and the ensemble mean results are discussed. The LDA model was developed with 42 years of data (1958–1999) for classifying three rainfall intervals with equal prior probability of 0.33. Both the PCR and NN models showed useful forecast skill for NW India and Peninsular India. Models with 8 predictors performed better than the models with only 6 predictors. The NN model with 3 hidden neurons performed better than model with 2 hidden neurons. For NW India, the NN model performed better than the PCR model. The RMSE of the NN model and PCR model with 8 predictors for NW India (Peninsular India) during the independent period 1984–99 was 12.5% (12.2%) and 12.6% (11.5%), respectively. Corresponding figures for the models with 6 predictors are 15.0% (13.0%) and 13.9% (11.4%) respectively. During the independent period, model errors were large in 1991, 1994, 1997 and 1999. However all the models showed deteriorating predictive skill after 1988, both for NW India and Peninsular India. The LDA model correctly classified 62% of grouped cases for NW India and Peninsular India. The LDA model showed better skill in classifying deficient rainfall (< − 8%) over NW India and excess rainfall (> 3%) over Peninsular India. Received October 2, 1999 Revised December 28, 1999     

An Early Cretaceous extinct spreading center in the northern Natal valley

We have identified an extinct E–W spreading center in the northern Natal valley on the basis of magnetic anomalies which was active from chron M11 (133 Ma) to 125.3 Ma, just before chron M2 (124 Ma) in the Early Cretaceous. Seafloor spreading in the northern Natal valley accounts for approximately 170 km of north–south motion between the Mozambique Ridge and Africa. This extension resolves the predicted overlap of the continental (central and southern) Mozambique Ridge and Antarctica in the chron M2 to M11 reconstructions from Mesozoic finite rotation parameters for Africa and Antarctica. In addition, the magnetic data reveal that the Mozambique Ridge was an independent microplate from at least 133 to 125 Ma. The northern Natal valley extinct spreading center connects to the spreading center separating the Mozambique Basin and the Riiser-Larsen Sea to the east. It follows that the northern Mozambique Ridge was either formed after the emplacement of the surrounding oceanic crust or it is the product of a very robust spreading center. To the west the extinct spreading center connects to the spreading center separating the southern Natal valley and Georgia Basin via a transform fault. Prior to chron M11, there is still a problem with the overlap of Mozambique Ridge if it is assumed to be fixed with respect to either the African or Antarctic plates. Some of the overlap can be accounted for by Jurassic deformation of the Mozambique Ridge, Mozambique Basin, and Dronning Maud land. It appears though that the Mozambique Ridge was an independent microplate from the breakup of Gondwana, 160 Ma, until it became part of the African plate, 125 Ma.