The use of lanthanides for the reconstruction of Phanerozoic and Proterozoic sedimentation environments exemplified by sections in the cover and basement of the East European platform

Criteria were established for the estimation of the lanthanide composition of sedimentary complexes for the reconstruction of sedimentation conditions. The distribution of lanthanides was investigated in phosphorites and sedimentary rocks from the cover of the East European platform, and published data on the geochemistry of phosphorites from Eurasia were analyzed. Indicator lanthanide ratios were established for the determination of the climate and depth of sedimentation, and the possibility of the use of rare earth elements for the facies settings and transgression-regression cycles of sedimentation was demonstrated. The sedimentation conditions of the iron formations of the Proterozoic Kursk and Krivoi Rog sedimentary groups were inferred from the distribution of lanthanides: the hematite and magnetite quartzites are the deepest water complexes of the sedimentation profile; the climatic conditions of sedimentation were estimated as humid for shale subformations and humid-semihumid for iron formations; the depths of sedimentation in the Kursk basin was 50−300 m; the sources of iron were the material of weathering profiles and endogenous influx.     

Surface Oscillations of a Free-Falling Droplet of an Ideal Fluid

According to observations, drops freely falling in the air under the action of gravity are deformed and oscillate in a wide range of frequencies and scales. A technique for calculating surface axisymmetric oscillations of a deformed droplet in the linear approximation under the assumption that the amplitude and wavelength are small when compared to the droplet diameter is proposed. The basic form of an axisymmetric droplet is chosen from observations. The calculation results for surface oscillations agree with recorded data on the varying shape of water droplets falling in the air.     

Cosmic-ray-produced36Cl and53Mn in Allan Hills-77 meteorites

Cosmic-ray-produced⁵³Mn (t_1/2 = 3.7 × 10⁶years) has been determined by neutron activation in nine Allan Hills-77 meteorites. Additionally,³⁶Cl (_1/2 = 3.0 × 10⁵years) has been measured in seven of these objects using tandem accelerator mass spectrometry. These results, along with¹⁴C (t_1/2 = 5740years) and²⁶Al (7.2 × 10⁵ years) concentrations determined elsewhere, yield terrestrial ages ranging from 0.1 × 10⁵ to 7 × 10⁵ years. Weathering was not found to result in⁵³Mn loss.     

Geochemical signatures of two different coastal depositional environments within the same catchment

The geochemistry of lake (Renstradträsket) and estuarine (Pieni Pernajanlahti Bay) sediment was investigated in a medium sized watershed draining to the Gulf of Finland, Baltic Sea. Catchment land-use types were compared and found similar. Sediment cores were dated using ²¹⁰Pb- and ¹³⁷Cs-chronologies and analyzed for Al, K, Cu, Zn, Fe, Mn, phosphorus fractions, TN, TC and biogenic silica (BSi). Differences between the sediment cores were studied by using linear regression analysis and principal components analysis (PCA). Despite similarities in catchment land-use and history, the sediment geochemical profiles of the sites varied significantly. Some of the differences could be related to differences in chemical sedimentation environment (lacustrine versus estuarine). TP concentration was found to be positively correlated with sediment iron content in estuarine sediment but negatively correlated with Fe in lake sediment. In the estuarine core sedimentary iron was not correlated to lithogenic potassium and aluminum but in the lake core the iron seemed to be lithogenic in origin, as suggested by the strong positive correlations (r ² = 0.95–0.96) between these three variables. Most similarities among the cores were found in Al concentrations. Estuarine nutrient profiles appeared relatively monotonous compared to the lake core. This is probably due to more vigorous mixing of the sediments that may ensure more rapid and complete consumption of the organic matter deposited on the bottom of the estuary. Therefore the lake sediment appeared to preserve the historical record of eutrophication better. Biologically less active and more particle-bound materials like the trace metals Cu and Zn seemed to retain good records of anthropogenic impact also in the estuarine core. The study highlights the need to take the sedimentation environment into account when interpreting geochemical record.     

Diurnal variation of electron density in Saturn’s ionosphere: Model comparisons with Saturn Electrostatic Discharge (SED) observations

Using the Saturn Thermosphere Ionosphere Model (STIM), we present a study of the diurnal variation of electron density, with a focus on comparisons with peak electron densities (N_MAX) inferred from the low-frequency cutoff of radio emission due to lightning in the lower atmosphere, called Saturn Electrostatic Discharges (SEDs). It is demonstrated that photochemistry in Saturn’s ionosphere cannot reproduce the SED-inferred diurnal variation in N_MAX unless additional production and loss sources outside of the current best estimates are considered. Additional explanations of the SED-inferred diurnal variation of N_MAX are presented and analyzed, such as the possibility that the low-frequency cutoff seen in SEDs is due to the presence of sharp low-altitude layers of plasma, as frequently seen in radio occultation measurements. Finally, we outline the observational constraints that must be fulfilled by any candidate explanations of the SED-inferred diurnal variation of N_MAX.     

A numerical model of the partitioning of trace chemical solutes during drop freezing

Partitioning of volatile chemicals among the gas, liquid, and solid phases during freezing of liquid water in clouds can impact trace chemical distributions in the troposphere and in precipitation. We describe here a numerical model of this partitioning during the freezing of a supercooled liquid drop. Our model includes the time-dependent calculation of the coupled processes of crystallization kinetics, heat transport, and solute mass transport, for a freezing hydrometeor particle. We demonstrate the model for tracer partitioning during the freezing of a 1000 μm radius drop on a 100 μm ice substrate, under a few ambient condition scenarios. The model effectively simulates particle freezing and solute transport, yielding results that are qualitatively and quantitatively consistent with previous experimental and theoretical work. Results suggest that the ice shell formation time is governed by heat loss to air and not by dendrite propagation, and that the location of ice nucleation is not important to freezing times or the effective partitioning of chemical solutes. Even for the case of nucleation at the center of the drop, we found that dendrites propagated rapidly to form surface ice. Freezing then proceeded from the outside in. Results also indicate that the solid-liquid interfacial surface area is not important to freezing times or the effective partitioning of chemical solutes, and that the rate aspects of trapping are more important than equilibrium solid-liquid partitioning to the effective partitioning resulting from freezing.     

冕洞演化与太阳活动周的关系及在日地预报中的应用

冕洞的研究在近二十多年里取得了丰硕的成果。本文回顾了冕洞的发现及观测历史，系统阐述了冕洞的结构特征、形成及演化规律，讨论了冕洞对日地空间产生的影响，冕洞与超级活动区的关系以及冕洞在太阳活动预报中所起的作用，在此基础上利用１９７０—１９９５年的冕洞资料对冕洞的时空分布和磁极性演化规律与太阳活动周的关系，以及冕洞与太阳风速度、地磁扰动等方面进行分析研究，得出以下结论：（１）冕洞在南北半球的分布在形态上基本是对称的，但在冕洞数量上北半球稍占优势；（２）冕洞的盛衰演化呈周期性，表现为赤道冕洞周期与黑子周期是完全一致的，极冕洞周期与黑子周期相位相差１８０°；（３）赤道冕洞的纬度分布随太阳活动周上升而上升，当太阳活动周达到极大值时，它也达到极大，然后再随太阳活动周下降而下降，极冕洞的纬度延伸方向演化与赤道冕洞相反；（４）极冕洞的极场呈１１年周期性，并且极场反转出现在太阳活动峰年期间；（５）太阳风和地磁扰动与冕洞的演化有着密切的关系