Screening model for volatile pollutants in dual porosity soils

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.     

Identification of Mining Blasts at Mid- to Far-regional Distances Using Low Frequency Seismic Signals

—?This paper reports results from two recent monitoring experiments in Wyoming. Broadband seismic recordings of kiloton class delay-fired cast blasts and instantaneous calibration shots in the Black Thunder coal mine were made at four azimuths at ranges from 1° to 2°. The primary focus of this experiment was to observe and to explain low-frequency signals that can be seen at all azimuths and should routinely propagate above noise to mid-regional distances where most events will be recorded by International Monitoring System (IMS) stations.¶The recordings clearly demonstrate that large millisecond delay-fired cast blasts routinely produce seismic signals that have significant spectral modulations below 10?Hz. These modulations are independent of time, the azimuth from the source and the orientation of the sensor. Low-frequency modulations below 5?Hz are seen beyond 9°. The modulations are not due to resonance as they are not produced by the calibration shots. Linear elastic modeling of the blasts that is guided by mine-blast reports fails to reproduce the fine detail of these modulations but clearly indicates that the enhanced “spectral roughness” is due to long interrow delays and source finiteness. The mismatch between the data and the synthetics is likely due to source processes, such as nonlinear interactions between shots, that are poorly understood and to other effects, such as variations of shot time and yield from planned values, that are known to be omnipresent but cannot be described accurately. A variant of the Automated Time-Frequency Discriminant (Hedlin, 1998b), which uses low-frequency spectral modulations, effectively separates these events from the calibration shots.¶The experiment also provided evidence that kiloton class cast blasts consistently yield energetic 2–10 second surface waves. The surface waves are strongly dependent on azimuth but are seen beyond 9°. Physical modeling of these events indicates that the surface waves are due mainly to the extended source duration and to a lesser extent to the slap-down of spalled material. The directionality is largely a path effect. A discriminant that is based on the partitioning of energy between surface and body waves routinely separates these events from the calibration shots.¶The Powder River Basin has essentially no natural seismic activity. How these mining events compare to earthquake observations remains to be determined.     

Radionuclides in the Natural–Anthropogenic System Comprising a Nuclear Power Plant and a Cooling Reservoir

The sources of technological radionuclides coming into the ecosystem of a nuclear power plant (NPP) cooling reservoir are considered and estimated. The information about the volumetric and mass activity in the biotic and abiotic components of the reservoir ecosystem is analyzed. The activity distribution between the components was determined. The activity reserve in the ecosystems of the cooling reservoirs in central European Russia has been estimated. The real radioactive input from NPPs to the reservoir is shown to be insignificant. It is concluded that cooling reservoirs can be used for any needs of the national economy and for the recreation (with respect to the radiation factor).     

Regime of Low-Frequency Wave Motion in the Coastal Zone of the Northwestern Caspian Sea

Regime characteristics of infragravitational and wind-induced waves for the northwestern Caspian Sea are given. The role of infragravitational waves in the dynamics of the northern Caspian coastal zone is determined based on empiric regional relationships, used to improve the conventional methods, and wind wave calculations.     

Analysis of Space and Time Variations in the Suspended Matter Distribution in Kaliningrad Bay of the Baltic Sea

The distribution of suspension, its composition, and particle size characteristics are studied in Kaliningrad Bay. Zoning of the bay according to the water turbidity is made. The main factors controlling the formation and space and time variations in the suspended matter are determined.     

Mantle Convection Modeling with Viscoelastic/Brittle Lithosphere: Numerical Methodology and Plate Tectonic Modeling

--The earth's tectonic plates are strong, viscoelastic shells which make up the outermost part of a thermally convecting, predominantly viscous layer. Brittle failure of the lithosphere occurs when stresses are high. In order to build a realistic simulation of the planet's evolution, the complete viscoelastic/brittle convection system needs to be considered. A particle-in-cell finite element method is demonstrated which can simulate very large deformation viscoelasticity with a strain-dependent yield stress. This is applied to a plate-deformation problem. Numerical accuracy is demonstrated relative to analytic benchmarks, and the characteristics of the method are discussed.     

Efficacy of Annual Bacteria Monitoring and Shock Chlorination in Wells Finished in a Floodplain Aquifer

Public health authorities generally recommend annual water-quality monitoring of rural water wells and shock chlorination if coliforms are detected. It is implicitly assumed that shock chlorination is effective in ridding most wells of bacteriological pathogens for months to years. Neither annual monitoring nor shock chlorination was effective in addressing coliform contamination of selected water wells in a small town developed on an alluvial aquifer where septic system effluents are impacting well water quality. Considerable temporal variation in total and fecal coliforms was observed in water wells monitored for a six-month period. Individual wells intermittently met and exceeded the drinking water criteria, indicating annual sampling was insufficient. Shock chlorination of three contaminated wells and their associated distribution systems proved ineffective because colonies apparently originated from outside the wells and reappeared over relatively short time periods (ranging from less than one week up to 21 weeks). The relatively fast and similar rate of recovery of total heterotrophic bacteria suggested they are related to biofilm formation in the wells and not to ground water contamination.     

Geoecological Characteristics of Lake Seliger

Data of hydrological and hydrochemical observations conducted in August 2000 at Lake Seliger and its major tributaries are presented. The analyzed characteristics included: O₂, H₂S, CH₄, microelements; mineral and organic compounds of P and N, ionic composition components (HCO₃ ^–, Cl^–, Na⁺, K⁺, dry residue, pH; color index, electrical conductivity. Bottom sediment samples were analyzed for microelement concentrations, CH₄, oil hydrocarbons. The influence of the basin on the ecological state of the lake was assessed, and tendencies in the evolution of its ecosystem are analyzed. It is shown that the ecological conditions of the lake has not changed significantly since 1960–1991, however, nutrient concentrations in the lake water was found to increase.     

Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: Six Case Studies

—?The injection or production of fluids can induce microseismic events in hydrocarbon and geothermal reservoirs. By deploying sensors downhole, data sets have been collected that consist of a few hundred to well over 10,000 induced events. We find that most induced events cluster into well-defined geometrical patterns. In many cases, we must apply high-precision, relative location techniques to observe these patterns. At three sedimentary sites, thin horizontal strands of activity are commonly found within the location patterns. We believe this reflects fracture containment between stratigraphic layers of differing mechanical properties or states of stress. At a massive carbonate and two crystalline sites, combinations of linear and planar features indicate networks of intersecting fractures and allow us to infer positions of aseismic fractures through their influence on the location patterns. In addition, the fine-scale seismicity patterns often evolve systematically with time. At sedimentary sites, migration of seismicity toward the injection point has been observed and may result from slip-induced stress along fractures that initially have little resolved shear. In such cases, triggering events may be critical to generate high levels of seismic activity. At one crystalline site, the early occurrence of linear features that traverse planes of activity indicate permeable zones and possible flow paths within fractures. We hope the continued development of microseismic techniques and refinement of conceptual models will further increase our understanding of fluid behavior and lead to improved resource management in fractured reservoirs.