Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.     

Changes in American urban floodplain occupancy since 1958: the experiences of nine cities

In 1958, researchers from the University of Chicago documented increases in the number of structures in the floodplains of 17 American cities, a phenomenon attributed to the prevalence of flood control structures. Because federal policies have shifted to managing floodplains, this paper updates the 1958 study for nine of the cities. Several trends are apparent. Development pressures determine flood-plain encroachment; floodplain management regulations have been implemented where it was easiest to do so. Further, structural measures continue to dominate. Thus, while many local officials are becoming more aware of advantages of flood-plain regulation, implementation and enforcement are inconsistent and uneven.     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

A Model of Magmatic Crystallization

A computer model simulating fractional crystallization at oneatmosphere pressure incorporates nine broadly-defined minerals—magnetite,olivine, hypersthene, augite, quartz, plagioclase, orthoclase,leucite, and nepheline. The crystallization temperature of eachmineral is considered to be a smooth function of the compositionof the magmatic liquid. These mineral temperature equationsare obtained by multiple linear regression analysis of informationfrom published silicate systems and rock melting experiments.The nine equations are solved for any primary liquid, withinthe broad range of common magma types, to select the crystallizingmineral or minerals. Partition ratios from published experimentsand analyses of lavas and phenocrysts permit calculation ofthe composition of the crystallizing mineral assemblage. Subtractionof a small amount of that composition from the primary liquidyields a new liquid, which may be recycled to yield a sequenceof liquids during fractional crystallization. The crystallizationmodel handles assemblages of co-precipitating minerals, andcan trace progressive saturation in new minerals, substitutionof a new mineral for an old mineral, and cessation of crystallizationof a mineral. The sequences of minerals and liquids derivedfrom a broad set of primary liquids are geologically realistic,so the model is useful in predicting phenocrysts in volcanicrocks and events during crystallization of shallow intrusions.     

Desert vegetation and timing of solar radiation

Timing and amount of solar radiation were examined as factors influencing the distribution of seven perennial plants on a small mountain located in the Chihuahuan Desert. Average direct beam solar radiation fluxes at differing times throughout the day and year were estimated with computer calculations. Principal components analysis was used to reduce the number of solar radiation parameters and include the maximum available information with a manageable number of variables. The remaining solar radiation parameters were compared to plant distributions using redundancy analysis and generalized additive models. Unimodal, bimodal, and monotonic responses were all found depending upon the species and solar radiation parameter. Niche separation at this location depends upon the timing as well as the amount of solar radiation.     

A 2D finite volume model for bebris flow and its application to events occurred in the Eastern Pyrenees

FLATModel is a 2D finite volume code that contains several original approaches to improve debris-flow simulation. Firstly, FLATModel incorporates a ＂stop-and-go＂ technique in each cell to allow continuous collapses and remobilizations of the debris-flow mass. Secondly, flow velocity and consequently yield stress is directly associated with the type of rheology to improve boundary accuracy. Thirdly, a simple approach for entrainment is also included in the model to analyse the effect of basal erosion of debris flows. FLATMODEL was tested at several events that occurred in the Eastern Pyrenees and simulation results indicated that the model can represent rather well the different characteristics observed in the field.     

Rock-weathering rates as functions of time

The scarcity of documented numerical relations between rock weathering and time has led to a common assumption that rates of weathering are linear. This assumption has been strengthened by studies that have calculated long-term average rates. However, little theoretical or empirical evidence exists to support linear rates for most chemical-weathering processes, with the exception of congruent dissolution processes. The few previous studies of rock-weathering rates that contain quantitative documentation of the relation between chemical weathering and time suggest that the rates of most weathering processes decrease with time. Recent studies of weathering rinds on basaltic and andesitic stones in glacial deposits in the western United States also clearly demonstrate that rock-weathering processes slow with time. Some weathering processes appear to conform to exponential functions of time, such as the square-root time function for hydration of volcanic glass, which conforms to the theoretical predictions of diffusion kinetics. However, weathering of mineralogically heterogeneous rocks involves complex physical and chemical processes that generally can be expressed only empirically, commonly by way of logarithmic time functions. Incongruent dissolution and other weathering processes produce residues, which are commonly used as measures of weathering. These residues appear to slow movement of water to unaltered material and impede chemical transport away from it. If weathering residues impede weathering processes then rates of weathering and rates of residue production are inversely proportional to some function of the residue thickness. This results in simple mathematical analogs for weathering that imply nonlinear time functions. The rate of weathering becomes constant only when an equilibrium thickness of the residue is reached. Because weathering residues are relatively stable chemically, and because physical removal of residues below the ground surface is slight, many weathering features require considerable time to reach constant rates of change. For weathering rinds on volcanic stones in the western United States, this time is at least 0.5 my.     

Changes in temperature and precipitation extremes in the CMIP5 ensemble

Twenty-year temperature and precipitation extremes and their projected future changes are evaluated in an ensemble of climate models participating in the Coupled Model Intercomparison Project Phase 5 (CMIP5), updating a similar study based on the CMIP3 ensemble. The projected changes are documented for three radiative forcing scenarios. The performance of the CMIP5 models in simulating 20-year temperature and precipitation extremes is comparable to that of the CMIP3 ensemble. The models simulate late 20th century warm extremes reasonably well, compared to estimates from reanalyses. The model discrepancies in simulating cold extremes are generally larger than those for warm extremes. Simulated late 20th century precipitation extremes are plausible in the extratropics but uncertainty in extreme precipitation in the tropics and subtropics remains very large, both in the models and the observationally-constrained datasets. Consistent with CMIP3 results, CMIP5 cold extremes generally warm faster than warm extremes, mainly in regions where snow and sea-ice retreat with global warming. There are tropical and subtropical regions where warming rates of warm extremes exceed those of cold extremes. Relative changes in the intensity of precipitation extremes generally exceed relative changes in annual mean precipitation. The corresponding waiting times for late 20th century extreme precipitation events are reduced almost everywhere, except for a few subtropical regions. The CMIP5 planetary sensitivity in extreme precipitation is about 6 %/°C, with generally lower values over extratropical land.     

Evaporation and radiation heat balance at the soil surface

Summary Evaporation from an area covered with short clover-grass has been determined by means of evapotranspirometers (4 m²), open (12 m²) and screened (1/3 m²) evaporimeters, and it has been estimated on the basis ofPenman's andThornthwaite's theories, too. The results of the measurements with the various instruments are compared with each other and with the results derived from the cited theories.Further, radiation heat balances have been made, including evaporation and heating of soil and atmosphere.

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Zusammenfassung Die Verdunstung über einer mit kurzem Kleegras bedeckten Fläche wurde mittels Evapotranspirometern (4 m²), offenen (12 m²) und abgeschirmten (1/3 m²) Evaporimetern gemessen und auch auf Grund vonPenmans undThornthwaites Theorien berechnet. Die Meßergebnisse der verschiedenen Instrumente werden untereinander verglichen und auch den mittels der angeführten Theorien abgeleiteten Resultaten gegenübergestellt.Weiters wurde eine Strahlungs-Wärme-Bilanz aufgestellt, die auch die Verdunstung und die Erwärmung von Boden und Atmosphäre berücksichtigt.

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Résumé On a mesuré l'évaporation sur une surface recouverte de trèfle court à l'aide d'évapotranspiromètres (4 m²) et d'évaporimètres ouverts (12 m²) et protégés (1/3 m²); les résultats de mesures, furent comparés entre eux et avec la théorie dePenman etThornthwaite.Puis on a dressé un bilan radiatif tenant compte, de l'évaporation et du réchauffement du sol et de l'atmosphère.

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With 8 Figures     

On the eigenvalues of kinematic α-effect dynamos

The kinematic α-effect dynamo problem is investigated in the case of an exterior perfect conductor. It is shown that certain approximate symmetries discovered in the numerical analysis of ROBERTS (1972) are exact for this case. As an illustration, an exact solution is given in a cylindrical geometry, where the equations can be written in terms of one variable. The implications for the earth's dynamo are discussed.