Organics preserved in anhydrous interplanetary dust particles: Pristine or not?

The chondritic‐porous subset of interplanetary dust particles (CP‐IDPs) are thought to have a cometary origin. Since the CP‐IDPs are anhydrous and unaltered by aqueous processes that are common to chondritic organic matter (OM), they represent the most pristine material of the solar system. However, the study of IDP OM might be hindered by their further alteration by flash heating during atmospheric entry, and we have limited understanding on how short‐term heating influences their organic content. In order to investigate this problem, five CP‐IDPs were studied for their OM contents, distributions, and isotopic compositions at the submicro‐ to nanoscale levels. The OM contained in the IDPs in this study spans the spectrum from primitive OM to that which has been significantly processed by heat. Similarities in the Raman D bands of the meteoritic and IDP OMs indicate that the overall gain in the sizes of crystalline domains in response to heating is similar. However, the Raman Γ_G values of the OM in all of the five IDPs clearly deviate from those of chondritic OM that had been processed during a prolonged episode of parent body heating. Such disparity suggests that the nonaromatic contents of the OM are different. Short duration heating further increases the H/C ratio and reduces the δ¹³C and δD values of the IDP OM. Our findings suggest that IDP OM contains a significant proportion of disordered C with low H content, such as sp² olefinic C=C, sp³ C–C, and/or carbonyl contents as bridging material.     

Resource Assessment of Polymetallic Nodules Using Acoustic Backscatter Intensity Data from the Korean Exploration Area,Northeastern Equatorial Pacific

A high level of confidence in resource data is a key prerequisite for conducting a reliable economic feasibility study in deep water seafloor mining. However, the acquisition of accurate resource data is difficult when employing traditional point-sampling methods to assess the resource potential of polymetallic nodules, given the vast size of the survey area and high spatial variability in nodule distribution. In this study, we analyzed high-resolution acoustic backscatter intensity images to estimate nodule abundance and increase confidence levels in nodule abundance data. We operated a 120 kHz deep-towed sidescan sonar (DSL-120) system (1×1 m resolution) across a 75 km² representative area in the Korean Exploration Area for polymetallic nodules in the Northeastern Equatorial Pacific. A deep-towed camera system was also run along two tracks in the same area to estimate the abundance of polymetallic nodules on the seafloor. Backscatter data were classified into four facies based on intensity. The facies with the weakest and strongest backscatter intensities occurred in areas of high slope gradient and basement outcrops, respectively. The backscatter intensities of the two other facies correlated well with the nodule abundances estimated from still-camera images. A linear fit between backscatter intensity and mean nodule abundance for 10 zones in the study area yielded an excellent correlation (r² = 0.97). This allowed us to compile a map of polymetallic nodule abundance that shows greater resolution than a map derived from the extrapolation of point-sampling data. Our preliminary analyses indicate that it is possible to greatly increase the confidence level of nodule resource data if the relationship between backscatter intensity and nodule abundance is reliably established. This approach has another key advantage over point sampling and image analyses in that detailed maps of mining obstacles along the seafloor are produced when acquiring data on the abundance of polymetallic nodules. The key limitation of this work is a poor correlation between nodule coverage, as observed from photographs, and nodule abundance. Significant additional ground truth sampling using well located box cores should be completed to determine whether or not there is a real correlation between the backscatter and abundance.     

Characterization of Deep-sea Macrofauna in the Korean Exploration Claim Area in the Clarion-Clipperton Fracture Zone,Northeastern Pacific Ocean

Macrofauna in the Clarion-Clipperton Fracture Zone remain poorly understood, due both to gross undersampling and to the fact that most species collected from the area are new to science. Evaluation of the diversity and species distribution of the benthic fauna in this area is critical to predicting and managing the impacts of manganese nodule mining. In this study, we investigated the distribution of macrofauna to understand the natural variability in the macrobenthic community and, by extension, to establish a baseline for environmental risk assessment. Samples were collected from the KR5 block of the Korea Contract Area, within the abyssal area of the Clarion-Clipperton Fracture Zone in the northeastern Pacific Ocean, by the RV Onnuri from 2012–2014. A total of 36 core samples were examined in the survey, from which we identified 183 macrobenthic species in 25 faunal groups with a mean density of 257 ind/m2. Not taking into account meio-faunal groups such as nematodes and harpacticoid copepods, the highest percentage of individuals was represented by Arthropoda. The dominant species (> 1% of total density) were the tanaids Typhlotanais sp.1, and Akanthophoreus spp. and Stenotanais sp., the isopod Macrostylis sp.1, and the polychaetes Cirratulidae spp. and Levinsenia uncinata. The abundances of the two dominant species, the tanaid Typhlotanais sp1. and isopod Macrostylis sp.1., were positively correlated with total organic carbon (TOC). There were no differences in macrofaunal density and community structure between preserved areas (PRA), the potential benthic impacted site (BIS), and other areas near the BIS. In general, higher diversity was associated with homogeneous environmental conditions, with high nodule coverage (> 50%) and TOC.     

Heating experiments of the Tagish Lake meteorite: Investigation of the effects of short‐term heating on chondritic organics

We present in this study the effects of short‐term heating on organics in the Tagish Lake meteorite and how the difference in the heating conditions can modify the organic matter (OM) in a way that complicates the interpretation of a parent body's heating extent with common cosmothermometers. The kinetics of short‐term heating and its influence on the organic structure are not well understood, and any study of OM is further complicated by the complex alteration processes of the thermally metamorphosed carbonaceous chondrites—potential analogues of the target asteroid Ryugu of the Hayabusa2 mission—which had experienced posthydration, short‐duration local heating. In an attempt to understand the effects of short‐term heating on chondritic OM, we investigated the change in the OM contents of the experimentally heated Tagish Lake meteorite samples using Raman spectroscopy, scanning transmission X‐ray microscopy utilizing X‐ray absorption near edge structure spectroscopy, and ultraperformance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry. Our experiment suggests that graphitization of OM did not take place despite the samples being heated to 900 °C for 96 h, as the OM maturity trend was influenced by the heating conditions, kinetics, and the nature of the OM precursor, such as the presence of abundant oxygenated moieties. Although both the intensity of the 1s?σ* exciton cannot be used to accurately interpret the peak metamorphic temperature of the experimentally heated Tagish Lake sample, the Raman graphite band widths of the heated products significantly differ from that of chondritic OM modified by long‐term internal heating.     

南昌地区雷击事件雷达回波特征分析

【目的】南昌地区地处亚热带地区,为了更好地监测预警雷电天气,提醒人们减少雷击事件的发生。【方法】使用南昌市历史雷击事件资料、江西雷达拼图资料和南昌、九江SA雷达基数据等资料,采用天气学、雷达气象学等原理及方法,对南昌地区雷击事件的雷达回波特征进行分析。【结果】（1）2013—2022年雷击事件共出现23次,孤立单体回波有2段闪电高发期,超级单体、飑线回波带和短带回波只有1个闪电高发期。（2）500 hPa高空槽、中层切变及西南急流等天气系统重叠最易产生雷击事件。（3）飑线回波带是由多个对流单体、强回波单体甚至超级单体回波排列组成的带状回波;短带回波长度比飑线回波带要短,回波强度也偏弱。【结论】上述结论为南昌地区雷电天气的监测预警提供分析依据。     

Some Observations on the Changes of Physico-Chemical and Biological Factors in Victoria Harbour and Vicinity, Hong Kong, 1988–1996

This study analysed monthly physico-chemical and biological data collected from 18 marine monitoring stations in Victoria Harbour and its vicinity in Hong Kong, from 1988 to 1996. Cluster analysis based on all water quality parameters measured shows that the 18 monitoring stations can be grouped into four clusters: Cluster I consists of stations located in the Harbour proper; Cluster II consists of stations located west of the Harbour and along the Rambler Channel; Cluster III consists of stations located east of the Harbour near Junk Bay and Cluster IV consists of stations located west of the Harbour and near the Ma Wan, Kap Shui Mun and Western Fairways. Factor analysis shows high positive loadings for nutrients in the first two factors of the four clusters. This suggests that effluents from the 11 outfalls of sewage screening plants influence the water quality of Victoria Harbour and its vicinity. Other factors such as storm water runoff, marine traffic, construction and industrial activities and the Pearl River discharges also appear to play an important role in determining local water quality. Five stations located along an east–west transect across the Harbour were selected for trend analysis. The three stations located in the Harbour exhibit an increasing trend for temperature and levels of total phosphorus (TP), ortho-phosphate phosphorous (PO₄-P) and faecal bacteria and a decreasing trend for pH and levels of total nitrogen (TN), total kjeldahl-nitrogen (TKN), 5-day biochemical oxygen demand (BOD₅) and chlorophyll a. For the station located east of the Harbour, an increasing trend is observed for levels of TP, PO₄-P, but no decreasing trend in TN and TKN is detected. For the station located west of the Harbour, no decreasing trend in TN, TKN and chlorophyll a is observed. Changes in levels of phosphorus and nitrogen in Victoria Harbour and the immediate vicinity have led to significant increases in the ratios of Total Silica (TSi) to TN, as well as a decrease in TN to TP and TSi to TP in most stations. Results of the present study show that Victoria Harbour and its immediate vicinity remain polluted.     

Doubled CO2 impact on subarctic marine carbon cycle: a case study at Ocean Station P

Along with meteorological observations, complementary and systematic oceanographic observations of various physical, biological and chemical parameters have been made at Ocean Station P (OSP) (50°N, 145°W) since the early 1950s. These decadal time scale data have contributed to a better understanding of the physical, biological and chemical processes in the surface layer of the northeastern subarctic region of the Pacific Ocean. These data have demonstrated the importance of the North Pacific in the global carbon cycle and, in particular, the role of biological/chemical processes in the net exchange of CO₂ across the air–sea interface. Although we do not fully comprehend how climatic variations influence marine communities or marine biogeochemistry, previous studies have provided some basic understanding of the mechanisms controlling the seasonal and inter-annual variations of biological and chemical parameters (such as phytoplankton, bacteria, nitrate/ammonium concentration) at OSP, and how they affect the carbon cycling in the subarctic North Pacific. In this study, we investigate how these mechanisms might alter the seasonal variations of these parameters at OSP under a 2XCO₂ condition. We examine these influences using a new biological model calibrated by the climatological data from OSP. For the 2XCO₂ simulation, the biological model is driven off line (i.e., no feedback to the ocean/atmospheric model components) by the climatology plus 2XCO₂−1XCO₂ outputs from a global surface ocean model and the Canadian GCM. Under the 2XCO₂ condition, the upper layer ocean shows an increase in the entrainment rate at the bottom of the mixed layer for OSP during the late autumn and winter seasons, resulting in an increase in the f-ratio. Although there is an overall increase in the primary production (PP) by 3–18%, a decrease in the biomass of small phytoplankton and microzooplankton (due to mesozooplankton grazing) lowers the concentration of dissolved organic matter (DOM) by 4–25%. The model also predicts a significant increase in the concentrations of nitrate and ammonium, and in bacterial production during July and August. Doubling of the atmospheric CO₂ from 330 to 660 ppm forces the marine pCO₂ to increase by about 63%, much of which is driven by an increased flux of CO₂ from the atmosphere to the oceans.     

Geology, Mineralogy and Geochemistry of Carbonate Replacement-Type Lead-Zinc-Silver Deposits in Janggun Mine, Republic of Korea

INTRODUCTIONThe Janggun mine,Republic of Korea,is located in thesoutheast of the Seoul,about latitude36°5 1′N and longitude12 9°0 4′E. In this mine area is situated the Bonghwa m ineral-ized zone of the Taebaegsan mining district,Korea.The geo-logic setting of the region was described as the Samgeum riQuadrangle(Kim et al.,196 2 ) .The general and local geolo-gy near the mine area have been studied by L ee (196 7) ,Hwang and Reedman(1975 ) .This mine consists of four min-eral de…     

肝脏MR四种扫描序列比较

目的 探讨豺脏ＭＲ扫描序列的最佳选择。方法 对２９例患者采用四种（ＳＥ、ＦＬＡＳＨ、Ｔｓｅ１１、Ｔｓｅ２３）扫描序列进行肝脏ＭＲ扫描,测量和计算图像的信噪比９ＳＮＲ）和对比度噪声比（ＣＮＲ）,同时对影像进行视觉评价。结果 ＦＬＡＳＨ和ＴＳＥ２３序列的ＳＮＲ和ＣＮＲ均不及Ｔｓｅ１１序列。结论 肝脏ＭＲ扫描ＦＬＡＳＨ序列可作为首选,Ｔｓｅ２３序列可作为辅助使用。     

Effects of vertical mixing parameterization on the mixed layer depth over the North Pacific in a global OGCM

We present MLD variability over the North Pacific Ocean in a global ocean general circulation model and impacts of three different vertical mixing schemes on it, based on statistical measures (annual mean difference, root-mean-square difference and correlation coefficient). The constant vertical mixing scheme tends to underestimate MLD over the whole basin. The Pacanowski-Philander scheme tends to overestimate MLD (> 20 m) in the mid- to high latitude during summer, implying that vertical mixing in the mid- to high latitude may not be represented properly by simple internal mixing mechanisms such as stratification or vertical shear of horizontal velocity. On the other hand, the new vertical mixing scheme (Noh et al. 2002) gives the most consistent MLD and its seasonal and spatial variability when compared with observation. These results suggest that parameterization of vertical mixing has significant effects on simulation of the seasonal and spatial variability of MLD over the North Pacific Ocean.