Sources and behavior of arsenic and trace elements in groundwater and surface water in the Poopó Lake Basin,Bolivian Altiplano

Water management in semiarid and arid catchments such as the Poopó Lake Basin requires improved understanding of the complex behavior of the various contaminants, which affect the drinking water quality and considered as crucial for sustainable development of the region. Mechanisms of arsenic (As) release in the surface and groundwater were studied. Hydrochemical data for surface water (4 samples) and groundwater (28 samples) were collected in a small watershed in the Poopó catchment at the highland of the Bolivian Andes (Altiplano). All of them show high electrical conductivity values and moderately oxidizing conditions. The surface water contains high concentration of sulfate and the trace elements As, Zn and Pb in the zone affected by acid mine drainage. There is a large variability of the concentration of As and of the trace elements in the groundwater in the five different regions within the Poopó catchment. The metal concentrations sensitive to changes of redox state and results of speciation modeling suggest that As (V) is a predominant aqueous species, which conforms to the prevailing oxidizing conditions in the shallow groundwater environment. Two generalized trends for As distribution were identified in groundwater: (a) high concentrations are found in the arid zone (100–250 μg/L) in the southern (region III) and in the northwestern (region V) regions, and (b) low concentrations (<50 μg/L) are found in the remaining part of the basin (region I, II and IV). However, the spatial distribution within these regions needs to be investigated further. A conclusion from the present study is that there are multiple sources of As as well as other trace elements (such as Cd, Mn and Zn) in the Poopó Lake Basin. Among the sources and the processes which led to the mobility of As and other trace metals in the region are: (a) weathering of sulfide minerals, (b) oxidation of pyrite and/or arsenopyrite in mineralized areas and (c) desorption from hydrous ferric oxide (HFO) surfaces. In non-mining areas, volcanic ash is suggested to be a significant source of As.     

A proposed probabilistic seismic tsunami hazard analysis methodology

Natural Hazards - We expand on existing probabilistic tsunami hazard analysis (PTHA) approaches by presenting a methodology wherein the epistemic uncertainties associated with tsunami timing,...     

Linear discriminant analysis to describe the relationship between rainfall and landslides in Bogotá, Colombia

Bogotá is located in the central Andean region of Colombia, which is frequently affected by landslide processes. These processes are mostly triggered during the rainy season in the city. This fact remarks the importance of determining what rain-derived parameters (e.g. intensity, antecedent rain, daily rain) are better related with the occurrence of landslides. For this purpose, the linear discriminant analysis (LDA), a technique derived from multivariate statistics, was used. The application of this type of analysis led to obtain simple mathematical functions that represent the probability of occurrence of landslides in Bogotá. The functions also allow to identify the most relevant variables derived from records of rainfall linked to the generation of landslides. A proof of concept using the proposed methodology was done using historic rainfall data from a 9-km² area of homogenous climatology and geomorphology in the south part of Bogotá. Landslides needed to be grouped for the LDA. Each one of these grouping categories represents landslides that occurred in similar geomorphologic conditions. Another set of events with no landslides was generated synthetically. Results of the proof of concept show that rainfall parameters such as normalized rainfall intensity I _MAP, normalized daily rainfall R _MAP and rainy-days normal RDN have the best statistical correlation with the landslides observed in the zone of analysis.     

Metamorphic gradients in burial metamorphosed vesicular lavas: Comparison of basalt and spilite in Cretaceous basic flows from central Chile

Partial spilitization of a 9 km thick pile of flood basalts with highly vesicular flow tops gave rise to patterns of secondary mineralogy at different scales: (a) a local pattern of mineralogical variation from the almost unaltered bottom towards the altered top of each flow, and (b) an overall pattern, comparing flow tops throughout the pile, with changes in mineralogical composition within a sequence of metamorphic zones and facies. The local patterns mimic the trend of the overall pattern, but are of opposite direction and telescoped. Thus, a gradual ordering and Andepletion of the secondary albite and increases in the Fe^*/Al ratio of epidote and pumpellyite upwards within individual flows are comparable in range to corresponding overall changes downwards throughout several kilometres. The mineralogical changes within the flows diminish in range towards the more altered deeper part of the pile.The local and overall patterns cannot be interpreted in terms of grade. They represent trends from metastable towards stable equilibrium, this latter only approached in the flow tops of the lower part of the pile. The patterns of secondary mineralogy were formed by an interplay of metamorphic gradients at different scales at any given time, and as burial proceeded. The overall pattern was caused by depth-controlled gradients: increasing P _fluid, temperature and temperature-induced increase of reaction rates, and decreasing fO₂ (downwards in the pile). The local patterns resulted from permeability-controlled gradients: increasing reaction rates, fO₂ and contrast in chemical activity between different domains, and decreasing P _fluid (upwards in each flow). The mineralogical observations reported in this paper fall into line if the overall temperature-induced increase of reaction rates and the local permeability-controlled rate factors played the leading role during burial metamorphism of the pile.     

The Precambrian geology of El Cristo,southern Tandilia Region,Argentina

Metamorphic and granitoid rocks of the El Cristo area, southern part of Tandilia Range, are considered in terms of structural, lithological and geochronological data.The abovementioned area was affected before 2000 m. y. by a first tectono-thermal event that was followed by a second episode of intense SW-NE folding. The latter accompanied or followed by a metamorphism of almandine grade and strong synkinematic to latekinematic granitization during the span 1800-1520 m. y.Succeeding episodes of metamorphism and deformation were less intense and culminated in the local development of a 900 m. y. granite, chloritization and some brittle deformation.

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Zusammenfassung Tektonische, lithologische und geochronologische Daten der metamorphen und granitischen Gesteine der El Cristo Gegend im südlichen Teil des Tandilia Gebirges werden diskutiert.Vor mehr als 2000 Ma wurde dieses Gebiet erstmals von einem tektonothermalen Ereignis erfa\t, gefolgt von einer zweiten Episode starker SW-NE gerichteter Faltung. Letztere wurde begleitet oder gefolgt von einer Almandingrad Metamorphose und starker synbis spÄtkinematischer Granitisierung wÄhrend der Zeitspanne 1800 bis 1520 Ma.Darauffolgende Metamorphosen und Deformationsereignisse waren weniger intensiv und endeten um 900 Ma in Lokaler Granitintrusion, Chloritisierung und spröder Deformation.

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Résumé Des roches métamorphiques et granitoÏdes de la région de Cristo font ici l'objet d'une discussion sur la base de données structurales, lithologiques et géochronologiques.La région mentionnée a été marquée d'abord, il y a plus de 2000 millions d'années, par une phénomène thermo-tectonique, suivi, dans une seconde phase, d'un plissement important dirigé SO-NE. Celui-ci a été accompagné ou suivi par un métamorphisme à almandin et par une intense granitisation syncinématique à tardicinématique au cours de la période 1800-1500 m. a.Des épisodes de métamorphisme et de déformation moins intenses s'ensuivirent, qui aboutirent au développement local, vers 900 m. a., d'une intrusion granitique, avec chloritisation et déformations cassantes.

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Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.     

The Middle Jurassic radiolarites and pelagic limestones of the Nieves unit (Rondaide Complex, Betic Cordillera): basin starvation in a rifted marginal slope of the western Tethys

Middle Jurassic radiolarites and associated pelagic limestones occur in the Rondaide Nieves unit of the Betic Cordillera, southern Spain. The Rondaide Mesozoic includes: (a) a thick succession of Triassic platform carbonates, comparable to the Alpine Hauptdolomit and Kössen facies; (b) Lower Jurassic pelagic limestones comparable to the Alpine Hierlatz and Adnet facies; (c) the Middle Jurassic Parauta Radiolarite Formation, described herein; and (d) a thin Upper Jurassic-Cretaceous condensed limestone succession. The Parauta Radiolarite Formation and associated limestones were studied with respect to stratigraphy, petrography, micropalaeontology (radiolarians, calcareous nanno- and microfossils) and facies. Radiolarite sedimentation occurred in the Middle Bathonian in a restricted and dysoxic deep Nieves basin, perched in the distal zone of a continental margin fringing the Tethyan ocean. This margin was adjacent to a young narrow oceanic basin between the South-Iberian margin and a continental block called Mesomediterranean Terrane. The Nieves basin was part of a marine corridor between the Proto-Atlantic and Piedmont-Ligurian basins of the Alpine Tethys. The regional tectonic position, the stratigraphical evolution since the Triassic, the age and the nature of the Mesozoic facies and the palaeogeographic relations to adjacent domains show striking analogies between the Betic Rondaide margin and coeval units of the Alps.     

An iron-bearing wave-dominated siliciclastic shelf: Facies analysis and palaeogeographic implications (Silurian-Lower Devonian Sierra Grande Formation,Southern Argentina)

The Sierra Grande Formation (Silurian-Early Devonian) consists of quartz arenites associated with clast supported conglomerates, mudstones, shales and ironstones. Eight sedimentary facies are recognized: cross-stratified and massive sandstone, plane bedded sandstone, ripple laminated sandstone, interstratified sandstone and mudstone, laminated mudstone and shale, oolitic ironstone, massive conglomerate and sheet conglomerate lags. These facies are interpreted as shallow marine deposits, ranging from foreshore to inner platform environments. Facies associations, based on vertical relationships among lithofacies, suggest several depositional zones: (a) beach to upper shoreface, with abundant plane bedded and massive bioturbated sandstones; (b) upper shoreface to breaker zone, characterized by multistorey cross-stratified and massive sandstone bodies interpreted as subtidal longshore-flow induced sand bars; (c) subtidal, nearshore tidal sand bars, consisting of upward fining sandstone sequences; (d) lower shoreface zone, dominated by ripple laminated sandstone, associated with cross-stratified and horizontal laminated sandstone, formed by translatory and oscillatory flows; and (e) transitional nearshore-offshore and inner platform zones, with heterolithic and pelitic successions, and oolitic ironstone horizons. Tidal currents, fair weather waves and storm events interacted during the deposition of the Sierra Grande Formation. However, the relevant features of the siliciclastics suggest that fair weather and storm waves were the most important mechanisms in sediment accumulation. The Silurian-Lower Devonian platform was part of a continental interior sag located between southern South America and southern Africa. The Sierra Grande Formation was deposited during a second order sea level rise, in which a shallow epeiric sea flooded a deeply weathered low relief continent.     

Sub-wavebase cross-bedded grainstones on a distally steepened carbonate ramp, Upper Miocene, Menorca, Spain

Cross‐bedded grainstones on carbonate ramps and shelves are commonly related to the locus of major wave energy absorption such as shorelines, shoals or shelf breaks. In contrast, on the Early Tortonian carbonate platform of Menorca (Balearic Islands), coarse‐grained, cross‐bedded grainstones are found at a distance from the palaeoshoreline where they were deposited below the wavebase. Excellent exposures along continuous outcrops on the sea cliffs of Menorca reveal the depositional profile and three‐dimensional distribution of the different facies belts of the Tortonian ramp depositional system. Basinward from the palaeoshoreline, fan deltas and beach deposits pass into 5‐km‐wide gently dipping bioturbated dolopackstone (inner and middle ramp), then into 12–20°‐dipping dolograinstone/rudstone clinobeds (ramp slope) and, finally, into subhorizontal fine‐grained basinal dolowackestone to dolopackstone (outer ramp). In this Miocene example, coarse‐grained grainstones exist in five different settings other than beach deposits: (1) on the middle ramp, where cross‐bedded grainstones were deposited by currents roughly parallel to the shoreline at 40–70 m estimated water depth and are interbedded with gently dipping bioturbated dolomitized packstones; (2) on the upper slope, where clinobeds are composed mostly of in situ rhodoliths and red‐algae fragments; (3) on the lower slope, as small‐scale bedforms (small three‐dimensional subaqueous dunes) migrating parallel to the slope; (4) at the transition between the lower slope and the outer ramp, where mollusc‐rich and rhodolithic rudstones and grainstones, interbedded in dolomitized laminated wackestones containing abundant planktonic foraminifera, infill slide/slump scars as upslope‐backstepping bodies (backsets); (5) at the toe of the slope, where coarse skeletal grainstones indicate bedform migration parallel to the platform margin, induced by currents at more than 150 m estimated water depth. This Late Miocene example also illustrates how changes in intrabasinal environmental conditions (nutrients and/or temperature) may produce changes in stratal patterns and facies architecture if they affect the biological system. Two depositional sequences compose the Miocene platform on Menorca, where a reef‐rimmed platform prograded onto an earlier distally steepened ramp. The transition from the ramp to the reef‐rimmed platform was effected by an increase in accommodation space caused by ecological changes, promoting a shift from a grain‐ to a framework‐producing biota.     

Cretaceous and Tertiary terrane accretion in the Cordillera Occidental of the Andes of Ecuador

New field, geochronological, geochemical and biostratigraphical data indicate that the central and northern parts of the Cordillera Occidental of the Andes of Ecuador comprise two terranes. The older (Pallatanga) terrane consists of an early to late (?) Cretaceous oceanic plateau suite, late Cretaceous marine turbidites derived from an unknown basaltic to andesitic volcanic source, and a tectonic mélange of probable late Cretaceous age. The younger (Macuchi) terrane consists of a volcanosedimentary island arc sequence, derived from a basaltic to andesitic source. A previously unidentified, regionally important dextral shear zone named the Chimbo-Toachi shear zone separates the two terranes. Regional evidence suggests that the Pallatanga terrane was accreted to the continental margin (the already accreted Cordillera Real) in Campanian times, producing a tectonic mélange in the suture zone. The Macuchi terrane was accreted to the Pallatanga terrane along the Chimbo-Toachi shear zone during the late Eocene, probably in a dextral shear regime. The correlation of Cretaceous rocks and accretionary events in the Cordillera Occidental of Ecuador and Colombia remains problematical, but the late Eocene event is recognised along the northern Andean margin.