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11.
Freezing as a method of sample preservation for the analysis of dissolved inorganic nutrients in seawater 总被引:1,自引:0,他引:1
John E. Dore Terrence Houlihan Dale V. Hebel Georgia Tien Luis Tupas David M. Karl 《Marine Chemistry》1996,53(3-4)
It is often desirable or necessary to store collected seawater samples prior to analysis for dissolved inorganic nutrients. It is therefore important to establish preservation and storage techniques that will ensure sample integrity and will not alter the precision or accuracy of analysis. We have performed a series of experiments on the storage of nutrient samples collected at the oligotrophic North Pacific benchmark Station ALOHA, using both standard autoanalyses and low-level techniques. Our results reveal that for oligotrophic oceanic waters, the immediate freezing of an unfiltered water sample in a clean polyethylene bottle is a suitable preservation method. This procedure is simple, it avoids potentially contaminating sample manipulations and chemical additions, and it adequately preserves the concentrations of nitrate + nitrite, soluble reactive phosphate, and soluble reactive silicate within a single water sample. 相似文献
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Crystallization under confinement conditions is a very important process in geochemistry and geophysics. Computer simulations of fluids in nanometer scale pore spaces can provide a unique microscopic insight into the structure, dynamics and forces arising from the crystallization process. We discuss in this paper molecular dynamics computer simulations of crystallization in pores of nanometer dimensions. The crystallization pressure due to the freezing of a model of Argon in a nanopore is computed using molecular dynamics simulations. We also investigate the influence of pore geometry in determining the dynamics of confined fluids, as well as mass separation in binary mixtures. It turns out that the pore geometry reveals itself as an important variable, leading to 1) new mechanisms for fast diffusion in confined spaces, and 2) accumulation of solute in specific regions inside the pore. 相似文献
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Leticia Gmez-Mendoza Ernesto Vega-Pea M. Isabel Ramírez Jos Luis Palacio-Prieto Leopoldo Galicia 《Applied geography (Sevenoaks, England)》2006,26(3-4):276-290
The objective of study was to explore short-term trends of processes that determine land-use change in Sierra Norte of Oaxaca (SNO), Mexico. Land use and land cover changes (LULCC) were estimated in a complex mosaic of vegetation in the SNO from 1980 to 2000, and projected them to 2020 through a Markovian model. SNO is highly vulnerable to climatic change according to a 2050 GCM scenario. However, 3% annual rate of tropical and temperate forest deforestation from agriculture and livestock encroachment, suggest the threat from land-use change is higher than that from climatic change for this study site. Productive land-use strategies are needed to reduce such high deforestation rates for tropical regions. Controlling deforestation would also reduce short-term effects of CO2 emissions to the atmosphere. Because of the necessity to evaluate anthropogenic ecosystem changes, it is imperative to separate short-term influences such as deforestation, from long-term influences such as climatic change. 相似文献
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James E. Kaldy Christopher P. Onuf Peter M. Eldridge Luis A. Cifuentes 《Estuaries and Coasts》2002,25(4):528-539
It has been assumed that because seagrasses dominate macrophyte biomass in many estuaries they also dominate primary production. We tested this assumption by developing three carbon budgets to examine the contribution of autotrophic components to the total ecosystem net primary production (TENPP) of Lower Laguna Madre, Texas. The first budget coupled average photosynthetic parameters with average daily irradiance to calculate daily production. The second budget used average photosynthetic parameters and hourly in situ irradiance to estimate productivity. The third budget integrated temperature-adjusted photosynthetic parameters (using Q10=2) and hourly in situ irradiance to estimate productivity. For each budget TENPP was calculated by integrating production from each autotroph based on the producers’ areal distribution within the entire Lower Laguna Madre. All budgets indicated that macroalgae account for 33–42% of TENPP and seagrasses consistently accounted for about 33–38%. The contribution by phytoplankton was consistently about 15–20%, and the contribution from the benthic microalgae varied between 8% and 36% of TENPP, although this may have been underestimated due to our exclusion of the within bed microphytobenthos component. The water column over the seagrass beds was net heterotrophic and consequently was a carbon sink consuming between 5% and 22% of TENPP, TENPP ranged between 5.41×1010 and 2.53×1011 g C yr−1, depending on which budget was used. The simplest, most idealized budget predicted the highest TENPP, while the more realistic budgets predicted lower values. Annual production rates estimated using the third budget forHalodule urightii andThalassia testudinum compare well with field data. Macroalgae and microalgae contribute 50–60% of TENPP, and seagrass may be more important as three-dimensional habitat (i.e., structure) than as a source of organic carbon to the water column in Lower Laguna Madre. 相似文献
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Sub-wavebase cross-bedded grainstones on a distally steepened carbonate ramp, Upper Miocene, Menorca, Spain 总被引:1,自引:0,他引:1
Cross‐bedded grainstones on carbonate ramps and shelves are commonly related to the locus of major wave energy absorption such as shorelines, shoals or shelf breaks. In contrast, on the Early Tortonian carbonate platform of Menorca (Balearic Islands), coarse‐grained, cross‐bedded grainstones are found at a distance from the palaeoshoreline where they were deposited below the wavebase. Excellent exposures along continuous outcrops on the sea cliffs of Menorca reveal the depositional profile and three‐dimensional distribution of the different facies belts of the Tortonian ramp depositional system. Basinward from the palaeoshoreline, fan deltas and beach deposits pass into 5‐km‐wide gently dipping bioturbated dolopackstone (inner and middle ramp), then into 12–20°‐dipping dolograinstone/rudstone clinobeds (ramp slope) and, finally, into subhorizontal fine‐grained basinal dolowackestone to dolopackstone (outer ramp). In this Miocene example, coarse‐grained grainstones exist in five different settings other than beach deposits: (1) on the middle ramp, where cross‐bedded grainstones were deposited by currents roughly parallel to the shoreline at 40–70 m estimated water depth and are interbedded with gently dipping bioturbated dolomitized packstones; (2) on the upper slope, where clinobeds are composed mostly of in situ rhodoliths and red‐algae fragments; (3) on the lower slope, as small‐scale bedforms (small three‐dimensional subaqueous dunes) migrating parallel to the slope; (4) at the transition between the lower slope and the outer ramp, where mollusc‐rich and rhodolithic rudstones and grainstones, interbedded in dolomitized laminated wackestones containing abundant planktonic foraminifera, infill slide/slump scars as upslope‐backstepping bodies (backsets); (5) at the toe of the slope, where coarse skeletal grainstones indicate bedform migration parallel to the platform margin, induced by currents at more than 150 m estimated water depth. This Late Miocene example also illustrates how changes in intrabasinal environmental conditions (nutrients and/or temperature) may produce changes in stratal patterns and facies architecture if they affect the biological system. Two depositional sequences compose the Miocene platform on Menorca, where a reef‐rimmed platform prograded onto an earlier distally steepened ramp. The transition from the ramp to the reef‐rimmed platform was effected by an increase in accommodation space caused by ecological changes, promoting a shift from a grain‐ to a framework‐producing biota. 相似文献
19.
New field, geochronological, geochemical and biostratigraphical data indicate that the central and northern parts of the Cordillera Occidental of the Andes of Ecuador comprise two terranes. The older (Pallatanga) terrane consists of an early to late (?) Cretaceous oceanic plateau suite, late Cretaceous marine turbidites derived from an unknown basaltic to andesitic volcanic source, and a tectonic mélange of probable late Cretaceous age. The younger (Macuchi) terrane consists of a volcanosedimentary island arc sequence, derived from a basaltic to andesitic source. A previously unidentified, regionally important dextral shear zone named the Chimbo-Toachi shear zone separates the two terranes. Regional evidence suggests that the Pallatanga terrane was accreted to the continental margin (the already accreted Cordillera Real) in Campanian times, producing a tectonic mélange in the suture zone. The Macuchi terrane was accreted to the Pallatanga terrane along the Chimbo-Toachi shear zone during the late Eocene, probably in a dextral shear regime. The correlation of Cretaceous rocks and accretionary events in the Cordillera Occidental of Ecuador and Colombia remains problematical, but the late Eocene event is recognised along the northern Andean margin. 相似文献
20.
Data and model uncertainty estimation for linear inversion 总被引:1,自引:0,他引:1
Kasper van Wijk John A. Scales William Navidi Luis Tenorio 《Geophysical Journal International》2002,149(3):625-632