The Double Solid Reactant Method for modeling the release of trace elements from dissolving solid phases: I. Outline and limitations

A Double Solid Reactant Method was elaborated from a suggestion of Marini (Geological sequestration of carbon dioxide: Thermodynamics, kinetics, and reaction path modeling. Developments in Geochemistry, Elsevier, Amsterdam, 2007) to simulate the release of trace elements during the progressive dissolution of solid phases. The method is based on the definition, for each dissolving solid, of both an entity whose thermodynamic and kinetic properties are known (either a pure mineral or a solid mixture) and a special reactant, that is, a material of known stoichiometry and unknown thermodynamic and kinetic properties. The special reactant is utilised to take into account the concentrations of trace elements in the dissolving solid phase. In this communication, the influence of several trace elements on the ΔG _f ^o, ΔG _r ^o and log K of the minerals considered by Lelli et al. (Environ Geol, 2007) and Accornero and Marini (Geobasi, 2007a; Proceedings of IMWA symposium, Cagliari, 27–31 May 2007b) was evaluated assuming ideal mixing in the solid state. These effects were found to be negligible for albite and the leucite–latitic glass, limited for muscovites and chlorites, and slightly more important for apatites. These influences become progressively higher with increasing concentration of trace elements in these minerals. Based on these deviations in thermodynamic parameters, special reactants should not include oxide components with molar fractions higher than 0.003. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

A semi-rigid connector for buoys and marine platforms

A system is described which has the capability of maintaining two large structures apart, floating or submerged, but allowing their relative movements due to current, waves and wind.Such a system has been designed and built. The tests carried out show that the developed theory is correct within the specified limits of validity. A practical test in the sea has shown the efficiency of the system and suggested some possible improvements.Its main characteristics are simplicity, reliability and low cost.     

Search for radio pulsations in four anomalous X-ray pulsars and discovery of two new pulsars

We have performed deep searches for radio pulsations from four southern anomalous X-ray pulsars (AXPs) to investigate their physical nature in comparison with the rotation powered pulsars. The data were acquired using the Parkes radio telescope with the 1.4 GHz multibeam receiver. No pulsed emission with periodicity matching the X-ray ephemeris have been found in the observed targets down to a limit of ∼0.1 mJy. A blind search has also been performed on all the 13 beams of the multibeam receiver (the central beam being pointed on the target AXP), leading to the serendipitous discovery of two new radio pulsars and to the further detection of 18 pulsars. Also a search for single dispersed pulses has been performed in the aim to detect signals similar to those of the recently discovered rotating radio transients.      

Intracontinental tectonic melange in Southern Apennines

On the axial zone of the Southern Apennines the major tectonic boundary between the inner platform (Western platform unit) and the pelagic (Lagonegro units) domains is represented by a thick level of highly deformed rock‐assemblage. Structural analysis reveals that this tectonic unit represents an intracontinental melange complex characterized by a block‐in‐matrix fabric that contains blocks from both hangingwall platform and footwall basin units. This unit comprises different sets of structures that, caused by shearing processes, developed at depths ranging from about 8–9 km to the surface. These tectonites represent the product of a crustal shear zone developed at the major boundary between platform‐basin domains of Adria during the thick‐skinned tectonic processes controlling the Southern Apennines mountain building.     

A model for the calculation of the seismic properties of geologic units

A model for the calculation of a representative complete elastic tensor of a geologic body is presented here, in order to fill the gap between the small scale sample and the complex structural and lithological association of a geologic body, which may be of the same large scale as the wavelength used on the seismic survey. The major problems arising during the modelling are discussed, namely the representativity of a suite of hand samples and the evaluation of the volume fraction of the different lithologies comprising a formation. An application example is presented of a metapelitic sequence spanning the tectonic boundary of the Ivrea-Verbano zone with the Serie dei Laghi in Valle Cannobina (N. Italy). It is shown that the effective formation anisotropy is drastically reduced relative to that of hand samples when the structure is averaged over a large area, except for the sheared and mylonitic sub-areas comprising the tectonic contact zone (the Cossato-Mergozzo-Brissago- and Pogallo lines). In these subareas the effective anisotropy is slightly reduced (a few points of a percent) from the hand sample scale to that of the geologic formation. Moreover, because the polarization of the fastest shear wave and the plane of maximum shear wave splitting of the most common crustal rock types coincide with the foliation, there is an opportunity to infer the structure of deep rock formations from teleseismic shear waves.     

U-Pb Zircon Geochronology with an Integrated LA-ICP-MS Microanalytical Workstation: Achievements in Precision and Accuracy

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is a microanalytical tool especially suitable for providing fast and precise U-Pb geochronological results on zircon grains. A new 193 nm excimer laser adapted to a micromachining workstation, equipped with a newly designed two-volume ablation cell and coupled with a quadrupole ICP-MS, is presented here. The system was tuned routinely to achieve sensitivities in the range of 3000 cps/μg g⁻¹ for ²³⁸U (< 2% RSD), with a 34 μm spot size, at 5 Hz and ∼ 8 J cm⁻², while ablating the NIST SRM 612 glass reference material. The system was capable of providing fast (< 1.5 minutes each analysis) and precise (generally < 1.5% 1s errors) ²⁰⁶Pb/²³⁸U zircon ages. The ages of widely used reference material zircons (Plesovice, 337 Ma; Temora, 416 Ma; R33, 418 Ma; Sri Lanka, 564 Ma; 91500, 1065 Ma) could be precisely matched, with an accuracy on isotopic ratios that ranged from ∼ 2 to ∼ 6%, depending on the homogeneity of the natural reference materials.