Size-segregated characterization of PM10 at the EMEP site Melpitz (Germany) using a five-stage impactor: a six year study

Size-segregated particle samples were collected using a Berner 5-stage impactor (stages 1?C5: 0.05?C0.14?C0.42?C1.2?C3.5?C10???m aerodynamic diameter). The means for all 169?days and for different categories of days were used for a characterization. The sorting criteria were (a) the distinction between winter (Wi, November to April) and summer (Su, May to October), (b) the distinction between air mass inflow from a sector West (W, 210?°?C320?°) and from a sector East (E, 35?°?C140?°). For the assignment of the air mass origin 96-h backward trajectories were used and four categories (WiW, WiE, SuW and SuE) with 48, 18, 42 and 29?days were established. The lowest mean particle mass concentrations were found for SuW and the highest for WiE with relative mass concentration distributions of 5.9, 28.2, 36.5, 18.0, and 11.4?% and 3.5, 22.7, 52.6, 16.7, and 4.5?% for stages 1?C5, respectively. The mass closure for water soluble ions, water, organic material (OM) and elemental carbon (EC) accounts for 81?C99?% of the gravimetric mass in Wi and for 60?C81?% for Su, depending on the stage. The fractions of nitrate were relatively high for WiW while sulphate fractions are high for WiE. The estimated concentrations of secondary organic carbon (SOA) on stage 3 for WiW, WiE, SuW and SuE were 0.32, 1.25, 0.27 and 0.58???gm^?3, respectively. The highest amount of SOA is found for WiE, representing 59?% of organic carbon (OC). The highest difference in the percentages of SOA in OC was found between winter (WiW 55?%, WiE 59?%) and summer (SuW and SuE 74?%) indicating photochemical processes during long-range transport. The mean Carbon Preference Indices (CPI) are highest for SuE (stage 4: 7.57 and stage 5: 9.82) resulting mainly from plant wax abrasion in the surrounding forests. For WiE the mean PAH concentration on stage 3 (9.7?ngm^?3) is about five times higher than for WiW, indicating long range transport following domestic heating and other combustion processes.     

Particle transport and distribution on the Mars Science Laboratory mission: Effects of triboelectric charging

We report on the nature of fine particle (<150 μm) transport under simulated martian conditions, in order to better understand the Mars Science Laboratory’s (MSL) sample acquisition, processing and handling subsystem (SA/SPaH). We find that triboelectric charging due to particle movement may have to be controlled in order for successful transport of fines that are created within the drill, processed through the Collection and Handling for In situ Martian Rock Analysis (CHIMRA) sample handing system, and delivered to the Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments. These fines will be transferred from the surface material to the portioner, a 3 mm diameter, 8 mm deep distribution center where they will drop ∼2 cm to the instrument inlet funnels. In our experiments, movement of different material including terrestrial analogs and martian soil simulants (Mars Mojave Simulant - MMS) resulted in 1-7 nanocoulombs of charge to build up for several different experimental configurations. When this charging phenomenon occurs, several different results are observed including particle clumping, adherence of material on conductive surfaces, or electrostatic repulsion, which causes like-charged particles to move away from each other. This electrostatic repulsion can sort samples based upon differing size fractions, while adhesion causes particles of different sizes to bind into clods. Identifying these electrostatic effects can help us understand potential bias in the analytical instruments and to define the best operational protocols to collect samples on the surface of Mars.     

The diverse nature of optical emission lines in brightest cluster galaxies: IFU observations of the central kiloparsec

We present integral field spectroscopy of the nebular line emission in a sample of nine brightest cluster galaxies (BCGs). The sample was chosen to probe both cooling flow and non-cooling flow clusters, as well as a range of cluster X-ray luminosities. The line emission morphology and velocity gradients suggest a great diversity in the properties of the line emitting gas. While some BCGs show evidence for filamentary or patchy emission (Abell 1060, Abell 1668 and MKW 3s), others have extended emission (Abell 1204, Abell 2199), while still others have centrally concentrated emission (Abell 2052). We examine diagnostic line ratios to determine the dominant ionization mechanisms in each galaxy. Most of the galaxies show regions with active galactic nucleus like spectra, however, for two BCGs, Abell 1060 and Abell 1204, the emission line diagnostics suggest regions which can be described by the emission from young stellar populations. The diversity of emission-line properties in our sample of BCGs suggests that the emission mechanism is not universal, with different ionization processes dominating different systems. Given this diversity, there is no evidence for a clear distinction of the emission-line properties between cooling flow and non-cooling flow BCGs. It is not always cooling flow BCGs which show emission (or young stellar populations), and non-cooling flow BCGs which do not.     

Landscape variations in stream water SO4 and δSSO4 in a boreal stream network

Despite reduced anthropogenic deposition during the last decades, deposition sulphate may still play an important role in the biogeochemical cycles of S and many catchments may act as net sources of S that may remain for several decades. The aim of this study is to elucidate the temporal and spatial dynamics of both SO₄²⁻ and δ³⁴S_SO4 in stream water from catchments with varying percentage of wetland and forest coverage and to determine their relative importance for catchment losses of S. Stream water samples were collected from 15 subcatchments ranging in size from 3 to 6780 ha, in a boreal stream network, northern Sweden. In forested catchments (<2% wetland cover) S-SO₄²⁻ concentrations in stream water averaged 1.7 mg L⁻¹ whereas in wetland dominated catchments (>30% wetland cover) the concentrations averaged 0.3 mg L⁻¹. A significant negative relationship was observed between S-SO₄²⁻ and percentage wetland coverage (r² = 0.77, p < 0.001) and the annual export of stream water SO₄²⁻ and wetland coverage (r² = 0.76, p < 0.001). The percentage forest coverage was on the other hand positively related to stream water SO₄²⁻ concentrations and the annual export of stream water SO₄²⁻ (r² = 0.77 and r² = 0.79, respectively). The annual average δ³⁴S_SO4 value in wetland dominated streams was +7.6‰ and in streams of forested catchments +6.7‰. At spring flood the δ³⁴S_SO4 values decreased in all streams by 1‰ to 5‰. The δ³⁴S_SO4 values in all streams were higher than the δ³⁴S_SO4 value of +4.7‰ in precipitation (snow). The export of S ranged from 0.5 kg S ha⁻¹ yr⁻¹ (wetland headwater stream) to 3.8 kg S ha⁻¹ yr⁻¹ (forested headwater stream). With an average S deposition in open field of 1.3 kg S ha⁻¹ yr⁻¹ (2002-2006) the mass balance results in a net export of S from all catchments, except in catchments with >30% wetland. The high temporal and spatial resolution of this study demonstrates that the reducing environments of wetlands play a key role for the biogeochemistry of S in boreal landscapes and are net sinks of S. Forested areas, on the other hand were net sources of S.     

Biological and Physical Clogging in Infiltration Wells: Effects of Well Diameter and Gravel Pack

Gravity-driven infiltration into the shallow subsurface via small-diameter wells (SDWs), i.e., wells with an inner diameter smaller than 7.5 cm (3 inches) and no gravel pack) has proven to be a cost-efficient and flexible tool for managed aquifer recharge (MAR), as it provides relatively high recharge rates with minimal construction effort. SDWs have a significantly smaller open filter area than larger diameter wells with gravel pack, making the infiltration of low-quality waters through these wells more at risk clogging. To investigate their susceptibility for biological and physical clogging, 24 physical models with different well setups were evaluated by infiltrating either nutrient-poor but turbid water or nutrient-rich but clear water. The experiments showed that smaller diameters and the lack of a gravel pack increase the well's susceptibility to both kinds of clogging. However, this effect was observed to be much more pronounced for physical than for biological clogging. Our conclusion is that SDWs show severe disadvantages with respect to the infiltration of highly turbid waters in comparison to large diameter wells with a gravel pack. Nevertheless, this disadvantage is much less severe when it comes to the infiltration of clear but nutrient-rich waters (e.g., treated wastewater). Depending on the economic and geological circumstances of a MAR-project, this disadvantage could be outweighed by the significantly lower construction costs of SDWs.     

Spatial and temporal dynamics of nitrogen exchange in an upwelling reach of a groundwater-fed river and potential response to perturbations changing rainfall patterns under UK climate change scenarios

We report the complex spatial and temporal dynamics of hyporheic exchange flows (HEFs) and nitrogen exchange in an upwelling reach of a 200 m groundwater-fed river. We show how research combining hydrological measurement, geophysics and isotopes, together with nutrient speciation techniques provides insight on nitrogen pathways and transformations that could not have been captured otherwise, including a zone of vertical preferential discharge of nitrate from deeper groundwater, and a zone of rapid denitrification linking the floodplain with the riverbed. Nitrate attenuation in the reach is dominated by denitrification but is spatially highly variable. This variability is driven by groundwater flow pathways and landscape setting, which influences hyporheic flow, residence time and nitrate removal. We observed the spatial connectivity of the river to the riparian zone is important because zones of horizontal preferential discharge supply organic matter from the floodplain and create anoxic riverbed conditions with overlapping zones of nitrification potential and denitrification activity that peaked 10–20 cm below the riverbed. Our data also show that temporal variability in water pathways in the reach is driven by changes in stage of the order of tens of centimetres and by strength of water flux, which may influence the depth of delivery of dissolved organic carbon. The temporal variability is sensitive to changes to river flows under UK climate projections that anticipate a 14%–15% increase in regional median winter rainfall and a 14%–19% reduction in summer rainfall. Superimposed on seasonal projections is more intensive storm activity that will likely lead to a more dynamic and inherently complex (hydrologically and biogeochemically) hyporheic zone. We recorded direct evidence of suppression of upwelling groundwater (flow reversal) during rainfall events. Such flow reversal may fuel riverbed sediments whereby delivery of organic carbon to depth, and higher denitrification rates in HEFs might act in concert to make nitrate removal in the riverbed more efficient.     

Analysis of uncertainties in the hydrological response of a model‐based climate change impact assessment in a subcatchment of the Spree River,Germany

Climate change impact assessments form the basis for the development of suitable climate change adaptation strategies. For this purpose, ensembles consisting of stepwise coupled models are generally used [emission scenario → global circulation model → downscaling approach (DA) → bias correction → impact model (hydrological model)], in which every item is affected by considerable uncertainty. The aim of the current study is (1) to analyse the uncertainty related to the choice of the DA as well as the hydrological model and its parameterization and (2) to evaluate the vulnerability of the studied catchment, a subcatchment of the highly anthropogenically impacted Spree River catchment, to hydrological change. Four different DAs are used to drive four different model configurations of two conceptually different hydrological models (Water Balance Simulation Model developed at ETH Zürich and HBV‐light). In total, 452 simulations are carried out. The results show that all simulations compute an increase in air temperature and potential evapotranspiration. For precipitation, runoff and actual evapotranspiration, opposing trends are computed depending on the DA used to drive the hydrological models. Overall, the largest source of uncertainty can be attributed to the choice of the DA, especially regarding whether it is statistical or dynamical. The choice of the hydrological model and its parameterization is of less importance when long‐term mean annual changes are compared. The large bandwidth at the end of the modelling chain may exacerbate the formulation of suitable climate change adaption strategies on the regional scale. Copyright © 2013 John Wiley & Sons, Ltd.