Interpretation of metal concentrations in estuarine sediments of Florida using aluminum as a reference element

Metal contamination of estuarine sediments is an increasing problem in Florida and elsewhere as urbanization extends into previously undeveloped areas. Effective estuarine management practices require scientifically valid tools to assess the extent of estuarine contamination. Interpretation of anthropogenic metal contributions has been hampered by the fact that natural metal concentrations in sediments vary by orders of magnitude in different sediments. Normalization of metal concentrations to a reference element, aluminum, appears to be a promising method for comparing estuarine sediment metal concentrations on a regional basis. In this paper we describe an interpretive method based on the relationship between sediment metals and aluminum derived from statewide data on natural estuarine sediments in Florida. We show how the method can be used to interpret metal concentrations with an example using data from the Miami River and Biscayne Bay.     

Sedimentary Processes and Depositional Characteristics of Coarse-grained Subaqueous Fans along Steep Slopes in a Lacustrine Rift Basin: A Case Study from the Dongying Depression, Bohai Bay Basin, China

Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin, China. The insufficient understanding of their sedimentary processes, depositional patterns, and controlling factors restricts efficient exploration and development. Coarse-grained subaqueous fans in the Yong′an area, Dongying Depression, are investigated in this study. These fans include nearshore subaqueous fans, and sublacustrine fans, and their sedimentary processes, depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology. Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence. Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction. While the topography was gentle, sublacustrine fans did not develop. During the late weak tectonic activity stage, late sublacustrine fans developed with multiple stages superimposed. Frequent fault activity and related earthquakes steepened the basin margin, and the boundary fault slopes were 25.9°–34°. During the early–middle deposition stage, hyperpycnal flows triggered by outburst floods developed. During the late deposition stage, with weak tectonic activity, seasonal floods triggered hyperpycnal flows, and hybrid event beds developed distally.     

Geographic signatures of North American West Coast estuaries

West Coast estuaries are geologically young and composed of a variety of geomorphological types. These estuaries range from large fjords to shallow lagoons; from large to low freshwater flows. Natural hazards include E1 Niños, strong Pacific storms, and active tectonic activity. West Coast estuaries support a wide range of living resources: five salmon species, harvestable shellfish, waterfowl and marine birds, marine mammals, and a variety of algae and plants. Although populations of many of these living resources have declined (salmonids), others have increased (marine mammals). West Coast estuaries are also centers of commerce and increasingly large shipping traffic. The West Coast human population is rising faster than most other areas of the U.S. and Canada, and is distributed heavily in southern California, the San Francisco Bay area, around Puget Sound, and the Fraser River estuary. While water pollution is a problem in many of the urbanized estuaries, most estuaries do not suffer from poor water quality. Primary estuarine problems include habitat alterations, degradation, and loss; diverted freshwater flows; marine sediment contamination; and exotic species introductions. The growing West Coast economy and population are in part related to the quality of life, which is dependent on the use and enjoyment of abundant coastal natural resources.     

The Anfeg post-collisional Pan-African high-K calc-alkaline batholith (Central Hoggar, Algeria), result of the LATEA microcontinent metacratonization

The Anfeg batholith (or composite laccolith) occupies a large surface (2000 km²) at the northern tip of the Laouni terrane, just south of Tamanrasset in Hoggar. It is granodioritic to granitic in composition and comprises abundant enclaves that are either mafic microgranular enclaves (MME) or gneissic xenoliths. It intruded an Eburnian (≈2 Ga) high-grade basement belonging to the LATEA metacraton at approximately 608 Ma (recalculated from the U–Pb dating of [Tectonics 5 (1986) 955]) and cooled at approximately 4 kbar, with a temperature of about 750 °C. This emplacement occurred mainly along subhorizontal thrust planes related to Pan-African subvertical mega-shear zones close to the attachment zone of a strike-slip partitioned transpression system. Although affected by some LILE mobility, the Anfeg batholith can be ascribed to a high-K calc-alkaline suite but characterized by low heavy REE contents and high LREE/HREE ratios. The MME belong to the Anfeg magmatic trend while some xenoliths belong to Neoproterozoic island arc rocks.The Anfeg batholith defines a Nd–Sr isotopic initial ratios trend (_Nd/(⁸⁷Sr/⁸⁶Sr)_i from −2.8/0.7068 to −11.8/0.7111) pointing to a mixing between a depleted mantle and an old Rb-depleted granulitic lower crust. Both sources have been identified within LATEA and elsewhere in the Tuareg shield (_Nd/⁸⁷Sr/⁸⁶Sr)_i of +6.2/0.7028 for the depleted mantle, −22/0.708 for the old lower crust.The model proposed relates the above geochemical features to a lithospheric delamination along the subvertical mega-shear zones that dissected the rigid LATEA former passive margin without major crustal thickening (metacratonization) during the general northward tectonic escape of the Tuareg terranes, a consequence of the collision with the West African craton. This delamination allowed the uprise of the asthenosphere. In turn, this induced the melting of the asthenosphere by adiabatic pressure release and of the old felsic and mafic lower crust due to the high heat flow. A gradient in the mantle/crust ratio within the source of the Pan-African magmatism is observed in LATEA from the northeast (Egéré-Aleksod terrane) where rare plutons are rooted within the Archaean/Eburnian basement to the southwest (Laouni terrane) where abundant batholiths, including Anfeg, have a mixed signature. Some mantle melts with only slight crustal contamination (Laouni troctolitic layered intrusions) are even present. This suggests that the southern boundary of LATEA microcontinent is not far south of the Tuareg shield.     

Osmium isotope ratios of PGM grains associated with the Freetown Layered Complex,Sierra Leone,and their origin

Osmium isotope ratios for two types of platinum group mineral (PGM) nuggets of eluvial (residual) origin, associated with the Freetown Layered Gabbro Complex, were determined in-situ using an ion microprobe. The values for erlichmanite nuggets are 1.08. Those for PGM inclusions in Pt–Fe alloy nuggets are higher, ranging from 1.2 to 2.1. Ratios of¹⁸⁷Os/¹⁸⁶Os vary between the nuggets, but they are consistent within individual nuggest. The data suggest early formation of the erlichmanite nuggets, prior to a postulated substantial contribution of crustal Os. The Pt–Fe alloy nuggets, on the other hand, were formed later in a residual melt which was contaminated by crustal Os due to the assimilation (<10%) or the gaseous/fluid transport of Os from Archaean host rocks into the magma. The lack of systematic mineralogical and chemical changes of the Complex and extensive granulitization in the adjacent host rocks and xenoliths may favor the latter process.The lack of high¹⁸⁷Os/¹⁸⁶Os ratios, consistent¹⁸⁷Os/¹⁸⁶Os values within individual nuggets and their textures and mineralogy suggest that the studied PGM nuggets were not formed during lateritization or in low-temperature depositional environments.     

The magnitude of error in conventional bulk-sediment radiocarbon dates from central North America

Although the carbon-reservoir problem with bulk-sediment radiocarbon dates from lakes has long been recognized, many synoptic studies continue to use chronologies derived from such dates. For four sites in central North America, we evaluate chronologies based on conventional radiocarbon dates from bulk sediment versus chronologies based on accelerator mass spectrometry (AMS) radiocarbon dates from terrestrial plant macrofossils. The carbon-reservoir error varies among sites and temporally at individual sites from 0 to 8000 yr. An error of 500–2000 yr is common. This error has important implications for the resolution of precise event chronologies.     

Validate global mapping of internal lunar magnetic field

In this work, we report a global mapping of vector lunar magnetic field based on new method of separation of internal and external fields. The magnetic measurements collected during the lifetime of lunar prospector (LP) extended mission during 1999 were strongly disturbed by the solar wind, a period which coincided with a maximum of the 23 cycle activity. The multiscale wavelength external fields were analyzed using spherical harmonic transform. The external field determined by inversion was then removed from each magnetic field component for each half orbit. To map the vector magnetic crustal anomalies, all LP magnetometer data collected at low altitudes in the three different lunar environments: (1) geomagnetic tail, (2) solar wind, and (3) geomagnetic sheath were processed using this new approach. The results obtained using these selection criteria allow us to get a global coverage of the lunar surface by the vector magnetic field at variable spacecraft low altitudes. To validate our mapping, we have developed and applied a method based on properties of potential fields functions. This method can be used to determine both horizontal north and east components using only vertical component. The validated lunar internal magnetic measurements obtained at variable spacecraft altitudes were then continued to a common altitude of 30 km using an inverse method. This mapping confirms firstly the nature of the crustal sources of lunar magnetic field and clearly shows that the strongest concentrations of anomalies are associated with high albedo and/or located antipodal to large young basins (Orientale, Serenitatis, Imbrium, and Crisium) of age about 3.9 Ga.     

Numerical Study on Coalescence of Pre-Existing Flaw Pairs in Rock-Like Material

The present numerical study, which is an extension of our previous numerical analysis on cracking processes of a single pre-existing flaw, focuses on the coalescence of two pre-existing parallel open flaws in rock subjected to a uniaxial compressive loading. To facilitate a systematic investigation, the arrangements of the flaw pair are classified into 11 categories. Simulations engaging AUTODYN are conducted on each category. The numerical results are compared with some published physical experimental test results. Eleven typical coalescence patterns are obtained, which are in good agreement with the experimental results, which include two coalescence patterns obtained in flaw pair arrangements (II) and (VIII″) not being reported in previous studies. The information gathered in the simulations helps identify the type (tensile/shear) of each crack segment involved in the coalescence. Most of the coalescence cracks initiate at or around the flaw tips, except those in flaw pair arrangements (II) and (IX′) with a very short ligament length, in which the coalescence cracks initiate on the flaw surfaces away from the flaw tip regions. Based on the numerical simulation results, the properties of the 11 coalescence patterns are obtained. Except those in flaw pair arrangements (II) and (IX′), the other coalescence patterns can be interpreted with respect to the basic crack types—tensile wing crack, horsetail crack and anti-wing crack. In addition, based on the type of crack segments involved in coalescence, namely tensile and shear, the coalescence can be classified into T mode (tensile mode), S mode (shear mode) and TS mode (mixed tensile–shear mode).