Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Upwelling and river runoff as sources of dissolved nitrous oxide to the Alsea estuary,Oregon

Surface waters of Alsea Bay, an unpolluted estuary on the Oregon coast, were analysed for nitrous oxide, nitrate and nitrite on a weekly or biweekly basis during the summer of 1979. The estuary was found to be a variable source of N₂O to the atmosphere. Large and rapid increases in the concentrations of N₂O, NO₃^?, and NO₂^? occurred at the beginning of the sampling period and are attributed to the influx of nutrient-rich upwelling water into the estuary with the tide. The subsequent decline in concentrations of nitrate, nitrite and nitrous oxide over the remainder of the summer is attributed to a decrease in upwelling intensity, a decline in nitrification rates and to assimilatory nitrate reduction. Measurements of nitrous oxide at six stations along the Alsea River were also made in September and October before and after the onset of the rainy season. Samples taken after flood conditions were established were systematically 50% higher than pre-flood samples. The data suggest that soil runoff results in elevated concentrations of N₂O in rivers.     

Carbon dioxide partial pressures in North Pacific surface waters — Time variations

Observations were made of time variations of the carbon dioxide partial pressures (Pco₂) of the atmosphere and surface sea waters in the Pacific subarctic region. Data were obtained on a cruise of the USC & GSSSURVEYOR in October, 1968 and on the TRANSPAC expedition of the CNAVENDEAVOUR in March–April, 1969. A rise in surface water Pco₂ of 18×10^–6 atm occurred in a period of 30–45 days in March–April due principally to spring warming of surface waters. An average increase of 60×10^–6 atm occurred between October, 1968 and March, 1969 as a result mainly of cessation of summer phytoplankton production and the onset of winter-storm-driven vertical mixing. Because the air-sea Pco₂ gradient not only changed appreciably in magnitude but also changed sign, there are important implications for calculations of air-sea exchange of carbon dioxide on the ocean wide scale.Data contained in this paper comprise part of a dissertation to be submitted by Louis I. Gordon in partial fulfillment of the requirements for the Ph. D. at Oregon State University.     

A sample changer for automated seawater nutrient analysis systems

An automatic sample changer based upon a commercially available 20-port rotary valve has been developed for use in automated seawater nutrient analyses. All parts exposed to seawater are of stainless steel, Teflon®, or Kel-F®. The sampler has proven to be rugged and efficient in both shore and shipboard laboratories.     

Aspects of Deep Ocean Mixing

The turbulent motions responsible for ocean mixing occur on scales much smaller than those resolved in numerical simulations of oceanic flows. Great progress has been made in understanding the sources of energy for mixing, the mechanisms, and the rates. On the other hand, we still do not have adequate answers to first order questions such as the extent to which the thermohaline circulation of the ocean, and hence the earth's climate, is sensitive to the present mixing rates in the ocean interior. Internal waves, generated by either wind or flow over topography, appear to be the principle cause of mixing. Mean and eddy flows over topography generate internal lee waves, while tidal flows over topography generate internal tides. The relative importance of these different internal wave sources is unknown. There are also great uncertainties about the spatial and temporal variation of mixing. Calculations of internal tide generation are becoming increasingly robust, but we do not know enough about the subsequent behavior of internal tides and their eventual breakdown into turbulence. It does seem, however, that most internal tide energy flux is radiated away from generation sites as low modes that propagate over basin scales. The mechanisms of wave-wave interaction and topographic scattering both act to transfer wave energy from low modes to smaller dissipative scales. This revised version was published online in August 2006 with corrections to the Cover Date.     

Significance of quaternary sea-level fluctuations for delta construction along the Brazilian coast

Many important areas of Quaternary deltaic sedimentation along the Brazilian coast are practically unknown in the geologic literature, especially outside Brazil. Our studies show that these areas, previously considered as highly destructive wave-dominated deltas of Holocene age, were affected by a wave-dominated phase during the Pleistocene, succeeded by highly constructive, intralagoonal stage in the Holocene, in turn followed by wave-dominated deltaic sedimentation that continues until today. The geologic evolution of these coastal plains is exemplified here by the Doce River mouth area, State of Espírito Santo, where relative sea-level fluctuations during the Quaternary played an important role in the construction of the deltaic complex.     

Modelling weathering processes at the catchment scale: The WITCH numerical model

A numerical model of chemical weathering in soil horizons and underlying bedrock (WITCH) has been coupled to a numerical model of water and carbon cycles in forest ecosystems (ASPECTS) to simulate the concentration of major species within the soil horizons and the stream of the Strengbach granitic watershed, located in the Vosges Mountains (France). For the first time, simulations of solute concentrations in soil layers and in the catchment river have been performed on a seasonal basis. The model is able to reproduce the concentrations of most major species within the soil horizons, as well as catching the first-order seasonal fluctuations of aqueous calcium, magnesium and silica concentrations. However, the WITCH model underestimates concentrations of Mg²⁺ and silica at the spring of the catchment stream, and significantly underestimates Ca²⁺ concentration. The deficit in calculated calcium can be compensated for by dissolution of trace apatite disseminated in the bedrock. However, the resulting increased Ca²⁺ release yields important smectite precipitation in the deepest model layer (in contact with the bedrock) and subsequent removal of large amount of silica and magnesium from solution. In contrast, the model accurately accounts for the concentrations of major species (Ca, Mg and silica) measured in the catchment stream when precipitation of clay minerals is not allowed. The model underestimation of Mg²⁺ and H₄SiO₄ concentrations when precipitation of well crystallized smectites is allowed strongly suggests that precipitation of well crystallized clay minerals is overestimated and that more soluble poorly crystallized and amorphous materials may be forming. In agreement with observations on other watersheds draining granitic rocks, this study indicates that highly soluble trace calcic phases control the aqueous calcium budget in the Strengbach watershed.     

Timing of deformation in the Norseman-Wiluna Belt, Yilgarn Craton, Western Australia

Establishing relative and absolute time frameworks for the sedimentary, magmatic, tectonic and gold mineralisation events in the Norseman-Wiluna Belt of the Archean Yilgarn Craton of Western Australia, has long been the main aim of research efforts. Recently published constraints on the timing of sedimentation and absolute granite ages have emphasized the shortcomings of the established rationale used for interpreting the timing of deformation events. In this paper the assumptions underlying this rationale are scrutinized, and it is shown that they are the source of significant misinterpretations. A revised time chart for the deformation events of the belt is established. The first shortening phase to affect the belt, D₁, was preceded by an extensional event D_1e and accompanied by a change from volcanic-dominated to plutonic-dominated magmatism at approximately 2685–2675 Ma. Later extension (D_2e) controlled deposition of the ca 2655 Ma Kurrawang Sequence and was followed by D₂, a major shortening event, which folded this sequence. D₂ must therefore have started after 2655 Ma—at least 20 Ma later than previously thought and after the voluminous 2670–2655 Ma high-Ca granite intrusion. Younger transcurrent deformation, D₃–D₄, waned at around 2630 Ma, suggesting that the crustal shortening deformation cycle D₂–D₄ lasted approximately 20–30 Ma, contemporaneous with low-volume 2650–2630 Ma low-Ca granites and alkaline intrusions. Time constraints on gold deposits suggest a late mineralisation event between 2640–2630 Ma. Thus, D₂–D₄ deformation cycle and late felsic magmatism define a 20–30 Ma long tectonothermal event, which culminated with gold mineralisation. The finding that D₂ folding took place after voluminous high-Ca granite intrusion led to research into the role of competent bodies during folding by means of numerical models. Results suggest that buoyancy-driven doming of pre-tectonic competent bodies trigger growth of antiforms, whereas non-buoyant, competent granite bodies trigger growth of synforms. The conspicuous presence of pre-folding granites in the cores of anticlines may be a result from active buoyancy doming during folding.