Tracing dissolved O2 and dissolved inorganic carbon stable isotope dynamics in the Nyack aquifer: Middle Fork Flathead River, Montana, USA

The geochemistry and microbiology of shallow groundwater aquifers is greatly influenced by the concentration of dissolved oxygen gas (DO); however, the mechanisms that consume DO in groundwater (e.g., biotic or abiotic) are often ambiguous. The use of stable isotopes of molecular O₂ (δ¹⁸O-DO), in conjunction with stable isotopes of dissolved inorganic carbon (δ¹³C-DIC), has potential to discriminate between the various mechanisms causing DO depletion in subsurface waters.Here we report the results of spatial and seasonal changes in δ¹⁸O-DO and δ¹³C-DIC at the Nyack floodplain aquifer along the Middle Fork of the Flathead River near West Glacier, Montana, USA. Over a short, well constrained flow path (∼100 m) near a main recharge zone of the floodplain, the δ¹⁸O-DO consistently increased as DO concentrations decreased with distance from the recharge source. Concurrently, DIC concentrations increased and δ¹³C-DIC values decreased. These observations are explained by community respiration coupled with dissolution of calcite from cobbles in the aquifer matrix. When these results are compared to data from wells distributed over the entire floodplain (several km) a much less predictable relationship was observed between DO concentration and δ¹⁸O-DO. Many wells with low DO concentrations (e.g., <125 μmol L⁻¹ or 4 mg L⁻¹) had anomalously low δ¹⁸O-DO values (e.g., <20‰). Mass balance calculations show that approximately equal amounts of O₂ may be contributed to the aquifer by diffusion from the vadose zone and by advection from the river recharge. Calculations presented here suggest that diffusion across a narrow air-water interface can contribute isotopically light δ¹⁸O-DO to the saturated zone. Possible contributions of light δ¹⁸O-DO from other processes, such as isotopic exchange and radial oxygen loss from plant roots in or near the water table, are compared and evaluated.     

Space-Time scales of internal waves

Abstract

We have contrived a model E(αω) α μ^?1ω^?p+1(ω ²?ω _i ²)^?+ for the distribution of internal wave energy in horizontal wavenumber, frequency-space, with wavenumber α extending to some upper limit μ(ω) α ω ^r-1 (ω ²?ω _i ²)^½, and frequency ω extending from the inertial frequency ω _i to the local Väisälä frequency n(y). The spectrum is portrayed as an equivalent continuum to which the modal structure (if it exists) is not vital. We assume horizontal isotropy, E(α, ω) = 2παE(α₁, α₂, ω), with α₁, α₂ designating components of α. Certain moments of E(α₁, α₂, ω) can be derived from observations. (i) Moored (or freely floating) devices measuring horizontal current u(t), vertical displacement η(t),…, yield the frequency spectra F _(u,η,…)(ω) = ∫∫ (U ², Z ²,…)E(α₁, ∞₂, ω) dα₁ dα₂, where U, Z,… are the appropriate wave functions. (ii) Similarly towed measurements give the wavenumber spectrum F _(…)(α1) = ∫∫… dα₂ dω. (iii) Moored measurements horizontally separated by X yield the coherence spectrum R(X, ω) which is related to the horizontal cosine transform ∫∫ E(α1, α2 ω) cos α₁ Xdα₁ dα₁. (iv) Moored measurements vertically separated by Y yield R(Y, ω) and (v) towed measurements vertically separated yield R(Y, α₁), and these are related to similar vertical Fourier transforms. Away from inertial frequencies, our model E(α, ω) α ω ^?p-r for α ≦ μ ω ω ^r, yields F(ω) ∞ ω ^?p, F(α₁) ∞ α₁ ^?q, with q = (p + r ? 1)/r. The observed moored and towed spectra suggest p and q between 5/3 and 2, yielding r between 2/3 and 3/2, inconsistent with a value of r = 2 derived from Webster's measurements of moored vertical coherence. We ascribe Webster's result to the oceanic fine-structure. Our choice (p, q, r) = (2, 2, 1) is then not inconsistent with existing evidence. The spectrum is E(∞, ω) ∞ ω ^?1(ω ²?ω _i ^{2 ?1}, and the α-bandwith μ ∞ (ω ²?ω _i ²)⁺ is equivalent to about 20 modes. Finally, we consider the frequency-of-encounter spectra F([sgrave]) at any towing speed S, approaching F(ω) as S ≦ S _o, and F(α₁) for α₁ = [sgrave]/S as S ≧ S _o, where S _o = 0(1 km/h) is the relevant Doppler velocity scale.     

Detection of radiation pressure acting on 2009 BD

We report the direct detection of radiation pressure on the asteroid 2009 BD, one of the smallest multi-opposition near-Earth objects currently known, with H ∼ 28.4. Under the purely gravitational model of NEODyS the object is currently considered a possible future impactor, with impact solutions starting in 2071. The detection of a radiation-related acceleration allows us to estimate an Area to Mass Ratio (AMR) for the object, that can be converted (under some assumptions) into a range of possible values for its average density. Our result AMR = (2.97 ± 0.33) × 10⁻⁴ m² kg⁻¹ is compatible with the object being of natural origin, and it is narrow enough to exclude a man-made nature. The possible origin of this object, its future observability, and the importance of radiation pressure in the impact monitoring process are also discussed.     

An Elliptical Model for Deformation Due to Groundwater Fluctuations

Historically, surface subsidence as a result of subsurface groundwater fluctuations have produced important and, at times, catastrophic effects, whether natural or anthropogenic. Over the past 30?years, numerical and analytical techniques for the modeling of this surface deformation, based upon elastic and poroelastic theory, have been remarkably successful in predicting the magnitude of that deformation (Le Mouélic and Adragna in Geophys Res Lett 29:1853, 2002). In this work we have extended the formula for a circular-shaped aquifer (Geertsma in J Petroleum Tech 25:734–744, 1973) to a more realistic elliptical shape. We have improved the accuracy of the approximation by making use of the cross terms of the expansion for the elliptic coordinates in terms of the eccentricity, e, and the mean anomaly angle, M, widely used in astronomy. Results of a number of simulations, in terms of e and M developed from the transcendental Kepler equation, are encouraging, giving realistic values for the elliptical approximation of the vertical deformation due to groundwater change. Finally, we have applied the algorithm to modeling of groundwater in southern California.     

The SCUBA HAlf Degree Extragalactic Survey – VI. 350-μm mapping of submillimetre galaxies

A follow-up survey using the Submillimetre High-Angular Resolution Camera (SHARC-II) at 350 μm has been carried out to map the regions around several 850-μm-selected sources from the Submillimetre HAlf Degree Extragalactic Survey (SHADES). These observations probe the infrared (IR) luminosities and hence star formation rates in the largest existing, most robust sample of submillimetre galaxies (SMGs). We measure 350-μm flux densities for 24 850-μm sources, seven of which are detected at ≥2.5σ within a 10 arcsec search radius of the 850-μm positions. When results from the literature are included the total number of 350-μm flux density constraints of SHADES SMGs is 31, with 15 detections. We fit a modified blackbody to the far-IR (FIR) photometry of each SMG, and confirm that typical SMGs are dust-rich  ( M _dust≃ 9 × 10⁸ M_⊙)  , luminous  ( L _FIR≃ 2 × 10¹² L_⊙)  star-forming galaxies with intrinsic dust temperatures of ≃35 K and star formation rates of  ≃400 M_⊙ yr⁻¹  . We have measured the temperature distribution of SMGs and find that the underlying distribution is slightly broader than implied by the error bars, and that most SMGs are at 28 K with a few hotter. We also place new constraints on the 350-μm source counts, N ₃₅₀(>25 mJy) ∼ 200–500 deg⁻².     

Aerosol Measurements in the Atmospheric Surface Layer at L’Aquila,Italy: Focus on Biogenic Primary Particles

Two year measurements of aerosol concentration and size distribution (0.25 μm < d < 30 μm) in the atmospheric surface layer, collected in L’Aquila (Italy) with an optical particle counter, are reported and analysed for the different modes of the particle size distribution. A different seasonal behaviour is shown for fine mode aerosols (largely produced by anthropogenic combustion), coarse mode and large-sized aerosols, whose abundance is regulated not only by anthropogenic local production, but also by remote natural sources (via large scale atmospheric transport) and by local sources of primary biogenic aerosols. The observed total abundance of large particles with diameter larger than 10 μm is compared with a statistical counting of primary biogenic particles, made with an independent technique. Results of these two observational approaches are analysed and compared to each other, with the help of a box model driven by observed meteorological parameters and validated with measurements of fine and coarse mode aerosols and of an atmospheric primary pollutant of anthropogenic origin (NO_x). Except in winter months, primary biogenic particles in the L’Aquila measurement site are shown to dominate the atmospheric boundary layer population of large aerosol particles with diameter larger than 10 μm (about 80 % of the total during summer months), with a pronounced seasonal cycle, contrary to fine mode aerosols of anthropogenic origin. In order to explain these findings, the main mechanisms controlling the abundance and variability of particulate matter tracers in the atmospheric surface layer are analysed with the numerical box-model.     

Pilot studies for the North American Soil Geochemical Landscapes Project – Site selection, sampling protocols, analytical methods, and quality control protocols

In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada sampled and chemically analyzed soils along two transects across Canada and the USA in preparation for a planned soil geochemical survey of North America. This effort was a pilot study to test and refine sampling protocols, analytical methods, quality control protocols, and field logistics for the continental survey. A total of 220 sample sites were selected at approximately 40-km intervals along the two transects. The ideal sampling protocol at each site called for a sample from a depth of 0–5 cm and a composite of each of the O, A, and C horizons. The <2-mm fraction of each sample was analyzed for Al, Ca, Fe, K, Mg, Na, S, Ti, Ag, As, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y, and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO₃, HClO₄, and HF. Separate methods were used for Hg, Se, total C, and carbonate-C on this same size fraction. Only Ag, In, and Te had a large percentage of concentrations below the detection limit. Quality control (QC) of the analyses was monitored at three levels: the laboratory performing the analysis, the USGS QC officer, and the principal investigator for the study. This level of review resulted in an average of one QC sample for every 20 field samples, which proved to be minimally adequate for such a large-scale survey. Additional QC samples should be added to monitor within-batch quality to the extent that no more than 10 samples are analyzed between a QC sample. Only Cr (77%), Y (82%), and Sb (80%) fell outside the acceptable limits of accuracy (% recovery between 85 and 115%) because of likely residence in mineral phases resistant to the acid digestion.A separate sample of 0–5-cm material was collected at each site for determination of organic compounds. A subset of 73 of these samples was analyzed for a suite of 19 organochlorine pesticides by gas chromatography. Only three of these samples had detectable pesticide concentrations. A separate sample of A-horizon soil was collected for microbial characterization by phospholipid fatty acid analysis (PLFA), soil enzyme assays, and determination of selected human and agricultural pathogens. Collection, preservation and analysis of samples for both organic compounds and microbial characterization add a great degree of complication to the sampling and preservation protocols and a significant increase to the cost for a continental-scale survey. Both these issues must be considered carefully prior to adopting these parameters as part of the soil geochemical survey of North America.     

Comparison of satellite and ship observations for total cloud amount

The data series of monthly clouldiness over global ocean from COADS was compared with that of from satellite Nimbus-7 during April 1979 to March 1985. The correspondence between them is good. Both the two methods of observation can provide useful information of the distribution of cloudiness and the two data sets can be mutually complementary.     

The impact of organic material on cloud and fog processes

Airborne surface-active organic substances can form adsorbed films at air-water and air-solid interfaces in the atmosphere. On the basis of considerable laboratory research, it has been suggested that these films can modify the microphysical processes of clouds and fog. The possible alterations of physical processes include retardation of the rate of growth and evaporation of water drops, passivation of cloud condensation nuclei, modification of drop coalescence efficiency, and the promotion of drop instability. The chemical structure of the film-forming compounds and the physical properties of the adsorbed films determine the degree to which the physical processes are modified. Upon consideration of the actual organic composition of the atmosphere, it was concluded that natural surface films will not greatly influence drop growth and evaporation. In addition, there is no definitive evidence from field experiments that other processes are influenced by natural organic films. The potential for useful weather modification through the intentional introduction of film-forming organic substances into the atmosphere was critically evaluated. Although numerous approaches have been suggested by laboratory studies, only the stabilization of airborne drops against evaporation has been unequivocally demonstrated in field experiments.     

An abundance model resource appraisal for some Canadian commodities

An abundance model resource appraisal has been undertaken for 10 mineral commodities in Canada: nickel, copper, zinc, lead, molybdenum, uranium, silver, gold, chromium, and tin. The purpose of the appraisal was to investigate the applicability of the model to the Canadian situation. Resource appraisals for the first 6 of the commodities studied have been published following deposit modeling studies. For many other commodities studied have been published following deposit modeling appraisals. The demonstration of the relevance of the abundance model to Canada would allow its application in such cases. The data presented in this paper indicate that the approximate relation, resource (short tons)=abundance (%)×10¹⁰. holds true for all commodities studied except chromium and tin. As the resources versus abundances relationship observed on a global scale is observable in Canada, it is concluded that Canada is a sufficiently large fraction (∼7%) of the earth's continental crust to represent a valid sample of that crust. Canada appears to be relatively well endowed with resources of copper, molybdenum, lead, and zinc, and poorly endowed with chromium and tin. It is proposed that the intersection of national boundaries with the boundaries of the world's metallogenic provinces is of greater importance than the intensity of past search, a feature that has been suggested in other studies. If these areas overlap, a nation may be self sufficient in a commodity: if they do not, the nation must import, or find a nationally available substitute. The sources of information used in the appraisal are outlined together with an analysis of the problems encounterea and the time requirements. This paper was presented at the International Geological Correlation Program (IGCP) Project 98: “Standards for Computer Applications in Resource Studies” held at Taita Hills Kenya, November 8–15, 1977.