The Breccia Museo formation, Campi Flegrei, southern Italy: geochronology, chemostratigraphy and relationship with the Campanian Ignimbrite eruption

The Breccia Museo is one of the most debated volcanic formations of the Campi Flegrei volcanic district. The deposit, made up of six distinctive stratigraphic units, has been interpreted by some as the proximal facies of the major caldera-forming Campanian Ignimbrite eruption, and by others as the product of several, more recent, independent and localized events. New geochemical and chemostratigraphical data and Ar–Ar age determinations for several units of the Breccia Museo deposits (~39 ka), correlate well with the Campanian Ignimbrite-forming eruption. The chemical zoning of the Breccia Museo deposits is interpreted here to be a consequence of a three-stage event that tapped a vertically zoned trachytic magma chamber. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Petrology of an ophiolitic cumulate sequence from Pindos,Greece

The ophiolitic sequence which crops out along the Aspropotamos Valley, Northern Pindos, Greece is composed from the bottom to the top of cumulates, dolerites, basaltic lavas, upper pillow lavas with basaltic/andesitic composition, and scarce basaltic dykes. The intrusive sequence, which is the subject of the present paper, exhibits magmatic layering more pronounced at the bottom than at the top where isotropic gabbros occur; they grade into the overlying dolerites. Troctolites with rare ultramafites prevail in the lower section and olivine gabbros in the upper section; at the top two-pyroxene gabbros appear. The rocks are mainly adcumulates and mesocumulates with subordinate heteradcumulates. The cumulus phases separated in the order: olivine and Cr-spinel, plagioclase, clinopyroxene, orthopyroxene. Olivine, plagioclase and pyroxenes frequently exhibit adeumulus overgrowth. Intercumulus phases may be plagioclase, clinopyroxene, orthopyroxene, pale brown amphibole and magnetite. Where pore material is present, it is composed of plagioclase, clinopyroxene, orthopyroxene, hornblende and ores. Cr-spinel occurs mainly at the bottom of the sequence (Cr₂O₃ between 30·5 and 39·8 per cent), while magnetite appears as a very rare phase in the upper section. Olivine, orthopyroxene, clinopyroxene exhibit slight cryptic variation (Mg × 100/(Mg + Fe) in the range 90–79, 90–70, 93–72 respectively). The investigated dolerites are non-cumulus rocks where clinopyroxene may be more magnesian than in the uppermost gabbros. The cumulate sequence and dolerites underwent variable but generally slight spilitization, in contrast to the overlying lavas. The sequence was generated through crystal accumulation probably from periodic pulses of tholeiitic magma; newly injected magma batches mixing with magma fractions already differentiated in the magma chamber. The high fluid pressure evidenced by the fluid inclusions in plagioclase and the whole chemical trend of the cumulate sequence are consistent with a genesis above a subduction zone, as already hypothesized for the overlying lavas.     

Linkages between the North Pacific Oscillation and central tropical Pacific SSTs at low frequencies

The North Pacific Oscillation (NPO) recently (re-)emerged in the literature as a key atmospheric mode in Northern Hemisphere climate variability, especially in the Pacific sector. Defined as a dipole of sea level pressure (SLP) between, roughly, Alaska and Hawaii, the NPO is connected with downstream weather conditions over North America, serves as the atmospheric forcing pattern of the North Pacific Gyre Oscillation (NPGO), and is a potential mechanism linking extratropical atmospheric variability to El Ni?o events in the tropical Pacific. This paper explores further the forcing dynamics of the NPO and, in particular, that of its individual poles. Using observational data and experiments with a simple atmospheric general circulation model (AGCM), we illustrate that the southern pole of the NPO (i.e., the one near Hawaii) contains significant power at low frequencies (7–10?years), while the northern pole (i.e., the one near Alaska) has no dominant frequencies. When examining the low-frequency content of the NPO and its poles separately, we discover that low-frequency variations (periods >7?years) of the NPO (particularly its subtropical node) are intimately tied to variability in central equatorial Pacific sea surface temperatures (SSTs) associated with the El Ni?o-Modoki/Central Pacific Warming (CPW) phenomenon. This result suggests that fluctuations in subtropical North Pacific SLP are important to monitor for Pacific low-frequency climate change. Using the simple AGCM, we also illustrate that variability in central tropical Pacific SSTs drives a significant fraction of variability of the southern node of the NPO. Taken together, the results highlight important links between secondary modes (i.e., CPW-NPO-NPGO) in Pacific decadal variability, akin to already established relationships between the primary modes of Pacific climate variability (i.e., canonical El Ni?o, the Aleutian Low, and the Pacific Decadal Oscillation).     

Salt Waters of the Northern Apennine Foredeep Basin (Italy): Origin and Evolution

The salt waters from the Emilia-Romagna sector of the Northern Apennine Foredeep have been investigated using major and trace element and stable isotope (δ²H, δ¹⁸O, δ³⁷Cl, δ⁸¹Br and ⁸⁷Sr/⁸⁶Sr ratio). Ca, Mg, Na, K, Sr, Li, B, I, Br and SO₄ vs. Cl diagrams suggest the subaerial evaporation of seawater beyond gypsum and before halite precipitation as primary process to explain the brine’s salinity, whereas saline to brackish waters were formed by mixing of evaporated seawater and water of meteoric origin. A diagenetic end-member may be a third component for mud volcanoes and some brackish waters. Salinization by dissolution of (Triassic) evaporites has been detected only in samples from the Tuscan side of the Apennines and/or interacting with the Tuscan Nappe. In comparison with the seawater evaporation path, Ca–Sr enrichment and Na–K–Mg depletion of the foredeep waters reveal the presence of secondary processes such as dolomitization–chloritization, zeolitization–albitization and illitization. Sulfate concentration, formerly buffered by gypsum-anhydrite deposition, is heavily lowered by bacterial and locally by thermochemical reduction during burial diagenesis. From an isotopic point of view, data of the water molecule confirm mixing between seawater and meteoric end-members. Local ¹⁸O-shift up to +11‰ at Salsomaggiore is related to water–rock interaction at high temperature (≈150°C) as confirmed by chemical (Mg, Li, Ca distribution) and isotopic (SO₄–H₂O) geothermometers. ³⁷Cl/³⁵Cl and ⁸¹Br/⁷⁹Br ratios corroborate the marine origin of the brines and evidence the diffusion of halogens from the deepest and most saline aquifers toward the surface. The ⁸⁷Sr/⁸⁶Sr ratio suggests a Miocene origin of Sr and rule out the hypothesis of a Triassic provenance of the dissolved components for the analyzed waters issuing from the Emilia-Romagna sector of the foredeep. Waters issuing from the Tuscan side of the Apennines and from the Marche sector of the foredeep show higher ⁸⁷Sr/⁸⁶Sr ratios because of the interaction with siliciclastic rocks.     

Numerical identification of soil-structure interaction pressures

A numerical approach is presented for the ‘identification’ (or back calculation) of the earth pressure acting on embedded or retaining structures. The procedure is applicable to structures of any shape and requires a set of in situ measurements that may include displacements of points on the structure, values of concentrated forces, values of distributed loads at some locations, etc. Possible limiting values of the unknown loads, non-linear structural behaviour, varying accuracies of the input data are accounted for in the problem formulation. Depending upon the type of problem, the solution is reached by means of the unconstrained or constrained minimization of a suitably defined error function. As an example, the proposed approach is applied to the identification of the earth pressure acting on some typical geotechnical engineering structures.     

Winter water mass distributions in the western Gulf of Mexico affected by a colliding anticyclonic ring

The winter water mass distributions in the western Gulf of Mexico, affected by the collision of a Loop Current anticyclonic ring, during January 1984 are analyzed. Two principal modes of Gulf Common Water (GCW) formation, arising from the dilution of the Caribbean Subtropical Underwater (SUW), are identified. Within the western gulf continental slope to the east of Tamiahua, the GCW is formed by the collision of anticyclonic rings. During these collision events, the SUW, entrapped at the core (200 m depth) of these features, is diluted by low salinity (36.1S36.3) water from the uppermost layer of the main thermocline. The end product of this mixture is GCW, which is further diluted by low salinity coastal water within the western gulf continental shelf. The second GCW formation mode is associated to the northerly wind stress which propagates over the western gulf during winter. During January, 1984, this wind stress gave rise to a 175 m mixed layer. This convective mixing destroyed the static stability of the summer thermocline and allowed for the partial dilution of the SUW with low salinity (S36.3) water from the western gulf continental shelf. Within the western gulf's upper 2000 m, the following water masses were identified to be present: GCW, SUW, Tropical Atlantic Central Water and associated dissolved oxygen minimum stratum, Antarctic Intermediate Water remnant, a mixture of the Caribbean Intermediate Water and the upper portion of North Atlantic Deep Water (NADW), and the NADW itself. The topographic distribution of these water masses' strata was dictated by the cyclonic-anticyclonic baroclinic circulation that evolved from the anticyclone's collision to the east of Tamiahua. Between the cyclonic and anticyclonic domains, the maximum pressure differential of these water masses' core occurrences was 150 to 280 dbar. The topographic transition zone defined by these strata occurred between the cyclonic and anticyclonic domains and coincided unambiguously with the anticyclone's collision zone. Within the continental shelf, we identified low temperature (12°C) and low salinity (31) coastal waters contributed by river runoff. Driven by the northerly wind stress, these coastal waters were advected toward the south hugging the coastline. The coastal and continental shelf waters demarcated a sea surface temperature, salinity, and dissolved oxygen discontinuity region that coincided with the horizontal baroclinic flow transition zone associated to the anticyclone's collision.     

The impact of commercial and recreational harvesting for Paracentrotus lividus on shallow rocky reef sea urchin communities in North-western Sardinia, Italy

The fishery for the edible sea urchin Paracentrotus lividus is of great importance to many European regions, although in some of them this species has shown a wide scale decline in recent years. This paper reports on direct (on P. lividus) and indirect (on the co-occurring but not fished echinoid, Arbacia lixula) effects of sea urchin harvesting in shallow rocky reefs in North-western Sardinia (Italy, central-western Mediterranean Sea), where this activity is intensively practised. Density, size (test diameter), and biomass of both species were assessed in autumn 2004 at two locations impacted by P. lividus fishery, and at two controls within an adjacent Marine Protected Area. Density of P. lividus and A. lixula was significantly greater at the controls than at the exploited locations. The average test diameter of P. lividus was also significantly larger at the controls, where large-sized specimens (i.e. >5 cm) were notably more abundant. The average size of A. lixula did not significantly differ between the impacted locations and the controls. The average biomass of P. lividus was significantly greater at the controls than at the exploited locations, whereas no differences were detected for A. lixula. These results reveal the existence of a heavy fishing impact on P. lividus in North-western Sardinia and the need for regulation of its harvesting to prevent severe direct effects on its populations. Since no indirect effects on A. lixula have been detected, it could be hypothesized that this species did not benefit from P. lividus fishery due to an only moderate competition for habitat and resources between these two echinoids. Implications for management of edible sea urchin fishery are also discussed.     

Intrinsic and forced interannual variability of the Gulf of Alaska mesoscale circulation

The response of the Gulf of Alaska (GOA) circulation to large-scale North Pacific climate variability is explored using three high resolution (15 km) regional ocean model ensembles over the period 1950-2004. On interannual and decadal timescales the mean circulation is strongly modulated by changes in the large scale climate forcing associated with PDO and ENSO. Intensification of the model gyre scale circulation occurs after the 1976-1977 climate shift, as well as during 1965-1970 and 1993-1995. From the model dynamical budgets we find that when the GOA experiences stronger southeasterly winds, typical during the positive phase of the PDO and ENSO, there is net large-scale Ekman convergence in the central and eastern coastal boundary. The geostrophic adjustment to higher sea surface height (SSH) and lower isopycnals lead to stronger cyclonic gyre scale circulation. The opposite situation occurs during stronger northwesterly winds (negative phase of the PDO).Along the eastern side of the GOA basin, interannual changes in the surface winds also modulate the seasonal development of high amplitude anticyclonic eddies (e.g. Haïda and Sitka eddies). Large interannual eddy events during winter-spring, are phase-locked with the seasonal cycle. The initial eddy dynamics are consistent with a quasi-linear Rossby wave response to positive SSH anomalies forced by stronger downwelling favorable winds (e.g. southwesterly during El Niño). However, because of the fast growth rate of baroclinic instability and the geographical focusing associated with the coastal geometry, most of the perturbation energy in the Rossby wave is locally trapped until converted into large scale nonlinear coherent eddies. Coastally trapped waves of tropical origin may also contribute to positive SSH anomalies that lead to higher amplitude eddies. However, their presence does not appear essential. The model ensembles, which do not include the effects of equatorial coastally trapped waves, capture the large Haïda and Sitka eddy events observed during 1982 and 1997 and explain between 40% and 70% of the tidal gauges variance along the GOA coast.In the western side of the GOA basin, interannual eddy variability located south of the Alaskan Stream is not correlated with large scale forcing and appears to be intrinsic. A comparison of the three model ensembles forced by NCEP winds and a multi-century-long integration forced only with the seasonal cycle, shows that the internal variability alone explains most of the eddy variance. The asymmetry between the eddy forced regime in the eastern basin, and the intrinsic regime in the western basin, has important implications for predicting the GOA response to climate change. If future climate change results in stronger wintertime winds and increased downwelling in the eastern basin, then increased mesoscale activity (perhaps more or larger eddies) might occur in this region. Conversely, the changes in the western basin are not predictable based on environmental forcing. Eastern eddies transport important biogeochemical quantities such as iron, oxygen and chlorophyll-a into the gyre interior, therefore having potential upscale effects on the GOA high-nutrient-low-chlorophyll region.     

Evaluation of microwave-assisted acid extraction procedures for the determination of metal content and potential bioavailability in sediments

Acid extractions represent a simple and effective tool for the assessment of metal contamination, origin and bioavailability in the aquatic environment. Optimized microwave-assisted procedures utilizing two extractions (8 M HNO₃ and 1 M HCl) were developed. Particular attention was given to the evaluation of efficiency and selectivity of the developed procedures. This involved an examination of the sediment and the extraction residues by Mössbauer spectroscopy and X-ray diffractometry. These instrumental approaches were used to identify the geochemical phases associated with acid decomposition. Microwave digestion with 8 M HNO₃ produced an efficient solubilization of the most important metal-bearing phases and left unaffected only the minerals (quartz, feldspars, muscovite) with a negligible metal content, thus providing a good estimate of the total metal concentrations. The 1 M HCl extraction, despite the limitation due to the incomplete solubilization of pyrite and to the partial dissolution of sheet silicates, represents a simple and effective technique for providing an estimate of the bioavailable metal fraction in sediments. The combined use of the two microwave-assisted acid extractions can provide a rapid and simple approach for the risk assessment of metal-polluted sediments.