New insights into volcanic processes from deep mining of the southern diatreme within the Argyle lamproite pipe,Western Australia

Underground mining and deep drilling of the richly diamondiferous ~1.2 Ga Argyle lamproite in Western Australia has prompted a re-evaluation of the geology of the pipe. Argyle is considered to be a composite pipe that formed by the coalescence of several diatremes and has been offset and elongated by post-emplacement faulting. Recent geological studies have recognised at least five distinct volcaniclastic lamproite lithofacies with differing diamond grades. The new data suggest that the centre of the southern (main) diatreme is occupied by well-bedded, olivine lamproite lapilli tuff with very high diamond grades (>10 ct/t). Characteristic features include a clast-supported fabric and high modal abundance of densely packed lamproite lapilli and coarse-grained, likely mantle-derived olivine now replaced by serpentine and/or talc. The persistence of small-scale graded and cross-bedding in this lithofacies to depths of ~1.5 km below the original surface prior to erosion suggests phreatomagmatic volcanism forming the diatreme was syn-eruptively accompanied by subsidence of the tephra, maintaining a steep-walled diatreme in the water-saturated country rock sediments.

     

Elektrochemische Einschätzung des Oberflächenzustandes von Wasserreinigungskohlen

Electrochemical Characterization of the Surface of Activated Carbon Used in Water Treatment Plants. We tried to measure electrochemically those properties of activated carbons which are important for using them for water purification. A success was achieved with the electrochemical immersion potential U_i which is found to be a function of concentration of functional surface groups on the carbon surface. However, the expected direct proportionality for inert surfaces between BET surface area and amount of charge measured in recharge processes has not been observed.     

On the last explosions of carbonatite pipe G3b, Gross Brukkaros, Namibia

 Pipe G3b is part of the Upper Cretaceous carbonatitic Gross Brukkaros Volcanic Field in southern Namibia. The pipe represents the root zone of a diatreme and is located 2800 m west of the rim of Gross Brukkaros, a downsag caldera. The pipe is exposed approximately 550 m below the original Upper Cretaceous land surface. It cuts down into its own feeder dyke, 0.3 m thick. The pipe coalesced from two small pipes and in plan view is 19 m long and 12 m wide. It consists of fragmented Cambrian Nama quartzites and shales of the Fish River subgroup. Despite intensive brecciation, the stratigraphic sequence of the country rocks is almost preserved in the pipe. In addition, the feeder dyke became fragmented too and can be traced in a 2- to 3-m-wide zone full of carbonatite blocks along the southern margin of the pipe. The void space of the breccia is 30–50% in volume. Finally, after the disruption of country rocks and feeder dyke, a little carbonatite magma intruded some of the void space. The breccia of pipe G3b is considered to represent a root zone at the transition from the feeder dyke into a diatreme above. Formation of the breccia required a shock wave thought to have been associated with a last explosion of the diatreme immediately above the present level of exposure. The explosion can be shown to have been phreatomagmatic in origin. Received: 11 October 1996 / Accepted: 6 March 1997     

Volcanological features of a low-viscosity melt: the carbonatitic Gross Brukkaros Volcanic Field, Namibia

 In the Upper Cretaceous Gross Brukkaros Volcanic Field, southern Namibia, a radial dyke system surrounds a dome structure and its 74 closely related carbonatite diatremes. This paper focuses on volcanological features which seem to be typical for a low-viscosity melt in various settings such as dykes, sills and diatremes. The total or near absence of vesicles in carbonatite ash grains and lapilli inside the diatremes is evidence against explosive exsolution of volatile phases and in favour of a phreatomagmatic fragmentation mechanism and thus for a phreatomagmatic eruption mechanism of the carbonatite diatremes. Received: 15 August 1996 / Accepted: 13 January 1997     

Major and trace elements in German bottled water,their regional distribution,and accordance with national and international standards

The market for mineral water has been growing steadily over the last few years. Germany is the country with the highest number of bottled mineral water brands (908 bottled water samples from 502 wells/brands were analyzed). The per capita consumption of mineral water in Germany in 2003 was 129 L. A wide range of values of one to seven orders of magnitude was determined for 71 elements in the bottled water samples analyzed by ICP-QMS, ICP-AES, IC, titration, photometric, conductometric and potentiometric methods. A comparison of the element concentrations and the legal limits for both bottled and tap water (EU, Germany, US EPA, WHO) shows that only 70% of the 908 mineral water samples fulfill the German and EU drinking water (i.e., tap water) regulations for all parameters (not including pH) for which action levels are defined. Nearly 5% of the bottled water samples not fulfill the German and EU regulations for mineral and table water. Comparison of our results with the current German and European action levels for mineral and table water shows that only 42 of the bottled water samples exceed the limits for one or more of the following elements: arsenic, nitrate, nitrite, manganese, nickel and barium concentrations. Ten of the bottled water samples contain uranium concentrations above the 10 μg/L recommended limit.     

Tracing glacier wastage in the Northern Tien Shan (Kyrgyzstan/Central Asia) over the last 40 years

The status and dynamics of glaciers are crucial for agriculture in semiarid parts of Central Asia, since river flow is characterized by major runoff in spring and summer, supplied by glacier- and snowmelt. Ideally, this coincides with the critical period of water demand for irrigation. The present study shows a clear trend in glacier retreat between 1963 and 2000 in the Sokoluk watershed, a catchment of the Northern Tien Shan mountain range in Kyrgyzstan. The overall area loss of 28% observed for the period 1963–2000, and a clear acceleration of wastage since the 1980s, correlate with the results of previous studies in other regions of the Tien Shan as well as the Alps. In particular, glaciers smaller than 0.5 km² have exhibited this phenomenon most starkly. While they registered a medium decrease of only 9.1% for 1963–1986, they lost 41.5% of their surface area between 1986 and 2000. Furthermore, a general increase in the minimum glacier elevation of 78 m has been observed over the last three decades. This corresponds to about one-third of the entire retreat of the minimum glacier elevation in the Northern Tien Shan since the Little Ice Age maximum.     

Dry deposition of particles to a pine plantation

There has been some controversy concerning the rate of deposition of particles having diameters near 1.0 m to vegetated surfaces. In this size range, the processes of Brownian diffusion and inertial impaction are not effective and deposition to smooth surfaces reaches a minimum. However, most measurements of deposition of micrometer diameter particles to vegetated surfaces indicate a greater deposition than extrapolation of the results from less rough surfaces would suggest. In this study, the aerodynamic profile method was used to estimate deposition to a pine plantation. The deposition velocities were found to be sensitive to the displacement height and the form of the profile stability correction used in the calculations. An analysis of a limited set of Bowen ratio data, collected over the same forest, suggests that the data are reasonably described by using a displacement height of 7.9 m and the stability correction proposed by Raupach (1979).The average deposition velocities, measured over a 9-month period were 0.0043, 0.0078, and 0.0092 m/s for the three diameter classes 0.5\2-1.0, 1.0\2-2.0 and 2.0\2-5.0 \gmm. These deposition velocities are lower than the corresponding aerodynamic conductance for the same periods, indicating that the deposition rate is limited by surface phenomena. Average surface conductances calculated for the three size classes of particles were 0.0060, 0.0141, and 0.0276 m/s, respectively. A multiple regression analysis showed high correlation between deposition velocity and wind speed. No other measured environmental factor or linear combination of factors was significantly correlated with deposition velocity.This paper was prepared in connection with work done under Contract No. DE-AC09-76R00001 with the U.S. Department of Energy. By acceptance of this paper, the publisher and/or recipient acknowledges the U.S. Government's right to retain a nonexclusive, royalty-free license in and to any copyright covering this paper, along with the right to produce and to authorize others to reproduce all or part of the copyrighted paper.     

Origin, age and stratigraphic significance of distal fallout ash tuffs from the Carboniferous–Permian continental Saar–Nahe Basin (SW Germany)

Thin, widespread, fallout tuff layers interbedded within fluvio-lacustrine successions of the Carboniferous-Permian Saar-Nahe Basin provide important tephrostratigraphic markers. In addition, radiogeochronometric data derived from the tuffs serve as calibration points for the adjustment to regional chronostratigraphy and to numerical time scales. The Pappelberg-Tuff in the Meisenheim Formation (Glan Group) has been dated by U/Pb zircon SHRIMP technique at 297.0Dž.2 Ma. Taking the Carboniferous/Permian boundary at 296 Ma, the Meisenheim Formation coincides approximately with this boundary. Consequently, underlying strata, lithostratigraphically regarded as the basal part of the 'Rotliegend', chronostratigraphically belong to the Upper Carboniferous. Bed thicknesses, grain size and sorting characteristics of the tuffs and the absence of contemporaneously emplaced volcanics within the Saar-Nahe Basin point to an extrabasinal derivation of the wind-drifted volcanic ash. Decreasing grain sizes of juvenile pyroclastic particles towards the north suggest source areas south of the basin within 300 km distance. The majority of the tuffs are rhyolitic to rhyodacitic and indicate petrographic and geochemical affinities to Moldanubian S-type granitoids, in particular to highly differentiated two-mica granites, and related volcanic effusives. Within the time frame considered here, such potential source rocks were emplaced in the northern and central Black Forest (SW Germany) and the northern Vosges (E France) at 100-150 km distance south of the Saar-Nahe Basin.