U–Pb,Re–Os,and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronology of the Nambija Au-skarn and Pangui porphyry Cu deposits,Ecuador: implications for the Jurassic metallogenic belt of the Northern Andes

New U–Pb, Re–Os, and ⁴⁰Ar/³⁹Ar dates are presented for magmatic and hydrothermal mineral phases in skarn- and porphyry-related ores from the Nambija and Pangui districts of the Subandean zone, southeastern Ecuador. Nambija has been one of the main gold-producing centers of Ecuador since the 1980s due to exceptionally high-grade ores (average 15 g/t, but frequently up to 300 g/t Au). Pangui is a recently discovered porphyry Cu–Mo district. The geology of the Subandean zone in southeastern Ecuador is dominated by the I-type, subduction-related, Jurassic Zamora batholith, which intrudes Triassic volcanosedimentary rocks. The Zamora batholith is in turn cut by porphyritic stocks, which are commonly associated with skarn formation and/or porphyry-style mineralization. High precision U–Pb and Re–Os ages for porphyritic stocks (U–Pb, zircon), associated prograde skarn (U–Pb, hydrothermal titanite), and retrograde stage skarn (Re–Os, molybdenite from veins postdating gold deposition) of the Nambija district are all indistinguishable from each other within error (145 Ma) and indicate a Late Jurassic age for the gold mineralization. Previously, gold mineralization at Nambija was considered to be Early Tertiary based on K–Ar ages obtained on various hydrothermal minerals. The new Jurassic age for the Nambija district is slightly younger than the ⁴⁰Ar/³⁹Ar and Re–Os ages for magmatic–hydrothermal minerals from the Pangui district, which range between 157 and 152 Ma. Mineralization at Nambija and Pangui is associated with porphyritic stocks that represent the last known episodes of a long-lived Jurassic arc magmatism (∼190 to 145 Ma). A Jurassic age for mineralization at Nambija and Pangui suggests that the Northern Andean Jurassic metallogenic belt, which starts in Colombia at 3° N, extends down to 5° S in Ecuador. It also adds a new mineralization style (Au-skarn) to the metal endowment of this belt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Magnetostratigraphy and detrital apatite fission track thermochronology in syntectonic conglomerates: constraints on the exhumation of the South‐Central Pyrenees

The syntectonic continental conglomerates of the South‐Central Pyrenees record the late stages of thin‐skinned transport of the South‐Pyrenean Central Units and the onset of exhumation of the Pyrenean Axial Zone (AZ) in the core of the orogen. New magnetostratigraphic data of these syntectonic continental conglomerates have established their age as Late Lutetian to Late Oligocene. The data reveal that these materials were deposited during intense periods of tectonic activity of the Pyrenean chain and not during the cessation of the deformation as considered previously. The magnetostratigraphic ages have been combined with new detrital apatite fission track (AFT) thermochronology from AZ‐derived granite cobbles within the syntectonic conglomerates. Distribution of the granitic cobbles with different AFT ages and track lengths combined with their depositional ages reveal information on the timing and rate of episodes of exhumation in the orogen. Some AFT ages are considerably older than the AFT ages of the outcropping AZ granitic massifs, indicating erosion from higher crustal levels within the massifs than presently exposed or from completely eroded plutons. Inverse thermal modelling reveals two well‐defined periods of rapid cooling in the hinterland at ca. 50–40 and ca. 30–25 Ma, with another poorly defined cooling episode at ca. 70–60 Ma. The lowest stratigraphic samples experienced postburial annealing caused by the deposition of younger syntectonic sediments during progressive burial of the south Pyrenean thrust and fold belt. Moreover, samples from the deeper stratigraphic levels also reveal postorogenic cooling during the Late Miocene as a response to the excavation of the Ebro River towards the Mediterranean Sea. Our data strongly support previous ideas about the burial of the South Pyrenean fold and thrust belt by Late Palaeogene syntectonic conglomerates and their subsequent re‐excavation and are consistent with other thermochronological data and thermal modelling from the interior part of the orogen.     

A simplified approach for including the incidence angle effect in seismic risk assessment

A simplified procedure is developed to consider the azimuthal orientation of buildings when estimating seismic risk. Two square-plan reinforced concrete building models are considered as a testbed, one with similar and one with dissimilar properties along the two principal horizontal axes. The fragility of both structures is analysed using a set of ground motion records rotated to multiple incidence angles to develop orientation-dependent fragility functions. It has been observed that, re-orienting all records so that these structures have the same azimuth vis-à-vis the corresponding epicentre leads to significant differences compared to assuming random orientations. Additional results stemming from single-degree-of-freedom oscillators further confirm such findings, showing a dependence to the proximity to the faults and the level of dissimilarity in the principal horizontal axes of the structure. The end results point to a non-negligible bias in assessment studies when a structure's orientation with respect to governing rupture scenarios is not taken into account. It is shown that the median of fragility curves calculated for un-rotated incidence angles can be bias-corrected through shifted by an amount that depends on the azimuthal orientation and level of axes-dissimilarity of structures.     

Lateral variation and frequency dependence of coda-Q in the southern part of Iberia

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A method based on the coda attenuation law: Q = Q ₀( f/f ₀)^v leads to the determination of the lateral variation of coda- Q in the southern part of the Iberian Peninsula using seismograms belonging to the seismological network of the Cartuja Observatory, located in Granada. The lateral variation of Q ₀ ( Q value corresponding to a reference frequency f ₀ of 1 Hz) and its frequency dependence for the 1 to 5 Hz frequency range are, in general, in agreement with coda- Q values for frequencies less than about 1 Hz, previously determined in the region under study.
To determine the coda- Q values analytical functions have been used to fit the magnification curves of the vertical component short-period seismographs belonging to the Cartuja network. The problem is solved by using least-squares techniques and non-linear inversion. The determined coda- Q ₀ values and its frequency dependence correlate well with several known geophysical parameters in the southern part of the Iberian Peninsula.     

Chrysophyte cyst relationships to water chemistry in Pyrenean lakes (NE Spain) and their potential for environmental reconstruction

Chrysophyte cysts were identified from the surface sediment of 105 mountain lakes in the Pyrenees (NE Spain), and their statistical relationship to water chemistry was examined using canonical correspondence analysis (CCA). The chemical parameters that explained significant and independent amounts of variability were alkalinity, pH, potassium, nitrate and magnesium. In a CCA using these parameters, the first canonical axis was related to a gradient of alkalinity and pH, which reflected the varying nature of the watershed bedrock in the Pyrenees, while the second axis was correlated with potassium (negatively) and nitrate (positively). The potential for environmental reconstructions of the five chemical parameters was further studied by: (i) analyzing the distribution of optima and tolerances calculated by weighted-averaging (WA); (ii) carrying out detrended canonical correspondence analysis (DCCA) with a single environmental variable; and (iii) examining the performance of WA-PLS transfer functions. Acceptable transfer functions were obtained for alkalinity, pH and nitrate. However, for potassium and magnesium the tolerance of cysts was too broad and the distribution of optima too skewed, respectively. The possibility of reconstructing nitrogen-related issues using chrysophyte cysts is particularly interesting because of the lack of direct chemical records of nitrogen compounds in sediments. Nitrate reconstructions using transfer functions may be complemented by a holistic reconstruction using partial CCA, where, after subtracting the effects of other chemicals, samples are ordered on a plain defined by potassium and nitrate. This ordination could show down-core trends in lake productivity and renewal time.     

Biomonitoring of coastal areas in Tunisia: Stable isotope and trace element analysis in the Yellow-legged Gull

We used Yellow-legged Gull (YLG) chicks to monitor trace elements in Tunisian areas subject to different pollution stresses: urban contamination (Chikly), industrial pollution (Thyna) and an unpolluted area (Kneis).We measured trace element concentrations (Hg, Se and Pb) in chick feathers. We also assessed their feeding ecology by analyzing both regurgitates and stable isotopes (SIA) in chick feathers and in their prey, to determine the main entry route of pollutants. SIA revealed that YLG feed mainly on aquatic resources from the Lake of Tunis (Chikly colony) and the Gulf of Gabès (Thyna and Kneis colonies). Moreover, the enriched δ¹⁵N found in feathers from Chikly are attributed to the eutrophication of the Lake of Tunis. Hg and Se were higher in Kneis and Thyna colonies, in agreement with the higher consumption of marine resources and the greater availability of these elements resulting from the impact of the industrial activity in the area. Pb concentrations were higher in Chikly, related to the heavier traffic around the Lake of Tunis and the use of leaded gasoline.     

Quaternary over-elevated torrential channels. Characteristics and depositional significance: the Maresme model (Catalonia,NE Spain)

International Journal of Earth Sciences - Channel-levee deposits that occur in some large sand-dominated fluvial systems are commonly elevated above the surrounding floodplain. However, the...     

Water management for acid mine drainage control at the polymetallic Zn–Pb–(Ag–Bi–Cu) deposit Cerro de Pasco, Peru

The geochemical and mineralogical study of the Quiulacocha tailings impoundment has shown that the hydrological connection of the three studied mine-waste systems at Cerro de Pasco (Pyrite-rich waste-rock dump Excelsior, old tailings impoundment Quiulacocha, and the active tailings impoundment Ocroyoc) is a critical concern for effective acid mine drainage (AMD) control and mine-waste management. The Quiulacocha tailings covered 114 ha, comprising 79 Mt of tailings, which contained  50 wt.% pyrite, and are located at 4340 m altitude in a tropical puna climate with about 1025 mm/a rainfall and 988 mm/a of evaporation. The tailings were partially overlain by the Excelsior waste-rock dump, which contains about 26,400,000 m³ of waste rocks that cover 94 ha and contained  60 wt.% of pyrite, which origin from a massive pyrite-quartz replacement body. Therefore, these two mine-waste deposits had a direct hydrological connection, resulting in the export of AMD produced at Excelsior towards Quiulacocha. In the Quiulacocha impoundment there are two different types of tailings recognized, that interact with the AMD from Excelsior: 1) Zn–Pb-rich tailings and 2) Cu–As-rich tailings. During the sampling, the Zn–Pb-rich part of Quiulacocha was not producing important excesses of AMD from the oxidation zone, since the pH increased to near neutral values at 1 m depth. The underlying tailings were still able to neutralize the acidity produced in the oxidation zone through sulfide oxidation by the carbonates (mainly dolomite and siderite) contained in the Zn–Pb mineral assemblage. The main source of AMD in this mine-waste system is the Excelsior waste-rock dump. Its acid seepage infiltrates into Quiulacocha forming a Fe–Zn–Pb plume with a pH 5.5–6.1 and containing up to 7440 mg/L Fe, 627 mg/L Zn, and 1.22 mg/L Pb. The plume was detected at 10–13 m depth in the stratigraphy of Quiulacocha tailings. Additionally, the AMD seepage outcropping at the base of the Excelsior waste-rock dump was channeled on the tailings surface into the Quiulacocha pond (pH 2.3), which covered the Cu–As-rich tailings. Infiltration of this Fe(III)-rich AMD increased tailings oxidation in the southwestern part of the impoundment, and subsequently liberated arsenic by enargite oxidation. Additionally, the AMD collected in the Quiulacocha pond was pumped into the active Ocroyoc tailings impoundment, where sulfide oxidation was strongly enhanced by the input of dissolved Fe(III). Therefore, the AMD management and a hydrological separation of the different mine-waste systems could be a first step to prevent further extension of the AMD problem in order to prevent increased sulfide oxidation by Fe(III)-rich solutions.