磺基水杨酸光度法连续测定岩石中的铁和钛

本文提出用磺基水杨酸(SSA)作显色剂,在不同pH值和同一波长下.于一分试液中连续测定铁和钛的分析方法。测定波长为420nm,测铁的pH值为8—11,Fe量在0—10μg/ml范围内服从比尔定律;测钛的pH值为2,TiO_2量在0—14μg/ml范围内服从比尔定律。     

高分辨率中子俘获伽马能谱测井

叙述了NCGS测井的原理及元素含量计算方法;解决了现场测井中计算元素含量时必须得到的参数,如等效相对探测效率曲线的刻度、探管和井液中干扰(Fe、Ti、H)份额的扣除。用自己研制的仪器经山东几个煤田钻孔实测资料验证.计算的元素含量与岩芯化学分析对照结果,其精度不低于美国PGT公司和Schlumberger公司制造的仪器。此外,还介绍了连续测量获得的谱,经处理绘制成连续曲线,首次推出S_(511)、S_B、S_H/S_B等曲线,提供多种有用地质信息。     

流动注射-光度法测定地质样品中痕量碘

利用I~-对4,4′-四甲基二氨基二苯甲烷(4,4′-TMB-DPM)与氯胺T反应的催化作用,建立了流动注射-分光光度测定地质样品中痕量碘的方法。采用不等流速合并带法,分析速度快、节省试剂、灵敏度高。与高温水解法释放I~-相结合,使样品处理简单、干扰离子少。对于含I~-10μg/L的水样,其RSD(n=19)为1.1％,检出限为0.3ng/ml。用于水系沉积物、土壤分析时,含碘1.6×10~(-6)的样品RSD(n=10)为6.1％,检出限为0.08×10~(-6)。测量速度50N/h。     

2-(2-苯并噻唑偶氮)-5-二羧甲氨基苯甲酸的合成及其应用——多元显色体系光度法测定金属材料中的镍

报道了新显色剂2-(2-苯并噻唑偶氮)-5-二羧甲氨基苯甲酸(BTACB)的合成,研究了在十二烷基硫酸钠(NaLS)存在下Ni~(2+)与BTACB形成蓝紫色配合物的条件,其λ_(max)~(MR)=600nm,ε=2.79×10~4L·mol~(-1)·cm~(-1),Ni在0～0.6μg/ml范围内服从比尔定律,反应具有一定的选择性。方法已用于直接测定铝合金、纯镁及含一定量Co的钢铁中痕量Ni和经萃取分离后测定纯钴中痕量Ni。     

320矿床成因和找矿方向

320矿床的含矿土岩是一套强烈硅化(角)砾状和(角)砾质岩,是地洼初动期岩溶洞穴沉(堆)积岩——以钙屑岩为主的混杂陆源沉积岩,受硅化形成。硅化主要发育于岩溶沉积岩中,并波及它附近的地层。这一事件发生于地洼余动期初,形成于低温环境,硅来自沉积岩源,流体起源于大气降水。320矿床是一个硅化改造的古岩溶矿床,它与美国亚利桑那州的硅化溶解-塌陷角砾岩筒相同。这类矿床在华南碳酸盐岩地区找矿潜力很大。     

岩溶水流方式与成矿作用关系探讨

本文通过论述管道流与扩散流两种主要岩溶水流方式的水动力、水化学特征与成矿的关系,论证水流方式在岩溶成矿作用中的重要作用。此外,通过分析两种水流的运移特点与矿床特征的关系,指出具浸染状、脉状的矿石结构构造和呈似层状、透镜状、脉状产出的矿体多与扩散流有关,具含砾纹层状、角砾状的矿石结构构造、和呈不规则状、囊状产出的矿体多与管道流有关;具不同形态矿体和不同结构构造矿石共存的矿体,则可由不同岩溶水流方式共同作用造成。      

基于孔压静力触探的岩土参数正态性检验方法对比

岩土参数的正态分布是岩土工程可靠分析的基本假定之一。目前,岩土工程参数的正态性检验以KS （Kolmogorov-Smirnov）检验为主,然而诸多研究表明,对于小样本数据,KS检验的正态性检验结果并不可靠。本文以废黄河泛滥沉积相粉土中的孔压静力触探（CPTU）锥尖阻力q_t数据为研究对象,首先采用ANOVA （方差分析）检验,从CPTU测试资料中进行总体的样本筛选,然后应用SW （Shapiro-Wilk）检验、KS检验、LF （Lilliefors）检验和AD （Anderson-Darling）检验等4种正态性检验方法,在不同样本容量条件下,对测试数据进行正态性检验评价。当测试数据的样本容量充足时,分析结果表明：SW检验结果最为严格,KS检验结果最不保守,而LF检验和AD检验的严格性介于两者之间;对于常规岩土工程设计,采用KS检验结果即可满足稳定性分析要求,对于复杂岩土工程设计,采用SW检验对设计参数进行正态性检验,可降低设计的不确定性。     

硫介导细菌还原载砷铁矿对砷迁移转化的影响

硫在铁和砷的生物地球化学循环中发挥着重要作用,但地下水系统中硫循环的中间产物S(0)对细菌转化铁和砷的影响尚不清楚.采用室内模拟实验,研究硫参与下细菌D2201对液相和载砷针铁矿中Fe(Ⅲ)和As(Ⅴ)的还原作用.结果表明:细菌D2201具有很强的铁还原能力,可以将液相中74％的Fe(Ⅲ)还原;加入硫后,细菌还原S(0...     

Geochronological and geochemical evidence for a Late Ordovician to Silurian arc-back-arc system in the northern Great Xing'an Range,NE China

The early Paleozoic tectonic evolution of the Xing'an-Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing'an Block,i.e.,the Xinlin-Xiguitu Ocean and the Nenjiang Ocean.However,the early development of the Nenjiang Ocean remains unclear.Here,we present zircon U-Pb geochronology and whole-rock elemental and Sr-Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area.LA-ICP-MS zircon U-Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443-436 Ma and 452-451 Ma,respectively.The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs,and depleted in HFSEs,with relatively low U/Th ratios of 0.18-0.36 andεNd(t)values of-1.6 to+0.5.These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts,consistent with a back-arc basin setting.By contrast,the andesitic tuffs are characterized by high MgO(>5 wt.%),Cr(138-200 ppm),and Ni(65-110 ppm)contents,and can be termed as high-Mg andesites.Their low Sr/Y ratios of 15.98-17.15 and U/Th values of 0.24-0.25 and moderate(La/Sm)_n values of 3.07-3.26 are similar to those from the Setouchi Volcanic Belt(SW Japan),and are thought to be derived from partial melting of subducted sediments,and subsequent melt-mantle interaction.The Duobaoshan basalts have high Nb(8.44-10.30 ppm)and TiO2 contents(1.17-1.60 wt.%),typical of Nb-enriched basalts.They are slightly younger than regional adakitic rocks and have positiveεNd(t)values of+5.2 to+5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts.Synthesized with coeval arc-related igneous rocks from the southeastern Xing'an Block,we propose that the Duobaoshan high-Mg andesitic tuffs and Nbenriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi-Duobaoshan arc belt,and they were formed by the northwestern subduction of the Nenjiang Ocean.Such a subduction beneath the integrated Xing'an-Erguna Block also gave rise to the East Ujimqin-Xinglong igneous belt in a continental back-arc basin setting.Our new data support an early Paleozoic arc-back-arc model in the northern Great Xing'an Range.     

Corporate social responsibility,green credit,and corporate performance: an empirical analysis based on the mining,power, and steel industries of China

Natural Hazards - From the perspective of corporate social responsibility and environmental risk management, green credit will have an important impact on corporate performance. The influence of...