Land surface coupling in regional climate simulations of the West African monsoon

Coupling of the Community Land Model (CLM3) to the ICTP Regional Climate Model (RegCM3) substantially improves the simulation of mean climate over West Africa relative to an older version of RegCM3 coupled to the Biosphere Atmosphere Transfer Scheme (BATS). Two 10-year simulations (1992–2001) show that the seasonal timing and magnitude of mean monsoon precipitation more closely match observations when the new land surface scheme is implemented. Specifically, RegCM3–CLM3 improves the timing of the monsoon advance and retreat across the Guinean Coast, and reduces a positive precipitation bias in the Sahel and Northern Africa. As a result, simulated temperatures are higher, thereby reducing the negative temperature bias found in the Guinean Coast and Sahel in RegCM3–BATS. In the RegCM3–BATS simulation, warmer temperatures in northern latitudes and wetter soils near the coast create excessively strong temperature and moist static energy gradients, which shifts the African Easterly Jet further north than observed. In the RegCM3–CLM3 simulation, the migration and position of the African Easterly Jet more closely match reanalysis winds. This improvement is triggered by drier soil conditions in the RegCM3–CLM3 simulation and an increase in evapotranspiration per unit precipitation. These results indicate that atmosphere–land surface coupling has the ability to impact regional-scale circulation and precipitation in regions exhibiting strong hydroclimatic gradients.     

Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.     

Consequences of change and variability in sea ice on marine ecosystem and biogeochemical processes during the 2007–2008 Canadian International Polar Year program

Change and variability in the timing and magnitude of sea ice geophysical and thermodynamic state have consequences on many aspects of the arctic marine system. The changes in both the geophysical and thermodynamic state, and in particular the timing of the development of these states, have consequences throughout the marine system. In this paper we review the ??consequences?? of change in sea ice state on primary productivity, marine mammal habitats, and sea ice as a medium for storage and transport of contaminants and carbon exchange across the ocean-sea-ice-atmosphere interface based upon results from the International Polar Year. Pertinent results include: 1) conditions along ice edges can bring deep nutrient-rich ??pacific?? waters into nutrient-poor surface waters along the arctic coast, affecting local food webs; 2) both sea ice thermodynamic and dynamic processes ultimately affect ringed seal/polar bear habitats by controlling the timing, location and amount of surface deformation required for ringed seal and polar bear preferred habitat 3) the ice edges bordering open waters of flaw leads are areas of high biological production and are observed to be important beluga habitat. 4) exchange of climate-active gases, including CO₂, is extremely active in sea ice environments, and the overall question of whether the Arctic Ocean is (or will be) a source or sink for CO₂ will be dependent on the balance of competing climate-change feedbacks.     

Picophytoplankton and bacterioplankton in the Mississippi River plume and its adjacent waters

Picoplankton abundance and distribution in the Mississippi River plume and its adjacent waters were studied during two cruises in April (high discharge) and October (low discharge) 2000 using flow cytometry. Concentrations of photosynthetic picoplankton,Synechococcus and picoeukaryotes were low in the turbid plume water but high in the coastal waters—i.e., the green waters resulting from mixing of river and oceanic waters. In this region, three types ofSynechococcus, characterized by their phycoerythrin chromophore composition, were found:Synechococcus cells with a low phycourobilin to phycoerythrobilin ratio (PUB:PEB) occurred throughout the region and dominated the totalSymechococcus abundance during both seasons; high PUB:PEB cells, which are the dominant strains in the open or blue ocean, occurred only at the outer shelf stations; and PEB-onlySynechococcus were abundant in most of the surveyed area during april, but were not observed during October.Prochlorococcus cyanobacteria only occurred at the oceanic stations, but extended farther inshore in October compared to April. This was a consequence of the reduced discharge and plume size during October. Picophytoplankton were a less important component of total phytoplankton biomass in the turbid river water and more important in the oligotrophic Gulf water. Seasonally, the contribution of picophytoplankton to total phytoplankton biomass in the surveyed area was higher during low discharge in October than during high discharge in April, even though the spring 2000 river discharge was unusually low and might not present a typical high discharge scenario. The abundance of heterotrophic bacteria was weakly correlated to chlorophylla (chla) concentration, but better correlated to picophytoplankton biomass. A higher proportion of High DNA bacteria occurred in the river-impacted regions during both seasons, with the ratio of High DNA bacteria to Low DNA bacteria significantly higher in April.     

Polyorogenic reworking of ore‐controlling shear zones at the South Range of the Sudbury impact structure: A telltale story from in situ U–Pb titanite geochronology

The post‐impact orogenic evolution of the world class Ni–Cu–PGE Sudbury mining camp in Ontario remains poorly understood. New temporal constraints from ore‐controlling, epidote–amphibolite facies shear zones in the heavily mineralised Creighton Mine (Sudbury, South Range) illuminate the complex orogenic history of the Sudbury structure. In situ U–Pb dating of shear‐hosted titanite grains by LA‐ICP‐MS reveals new evidence for shear zone reworking during the Yavapai (ca. 1.77–1.7 Ga), Mazatzalian–Labradorian (1.7–1.6 Ga) and Chieflakian–Pinwarian (1.5–1.4 Ga) accretionary events. The new age data show that the effects of the Penokean orogeny (1.9–1.8 Ga) on the structural architecture of the Sudbury structure have been overestimated. At a regional scale, the new titanite age populations corroborate that the Southern Province of the Canadian Shield documents the same tectonothermal episodes that are recorded along orogenic strike within the accretionary provinces of the Southwestern United States.     

Energetics of a double flare on November 8, 1980

Here we complete an energy balance analysis of a double impulsive hard X-ray flare. From spatial observations, we deduce both flares probably occur in the same loop within the resolution of the data. For the first flare, the energy in the fast electrons (assuming a thick-target model) is comparable to the convective up-flow energy, suggesting that these are related successive modes of energy storage and transfer. The total energy lost through radiation and conduction, 2.0 × 10²⁸ erg, is comparable to the energy in fast electrons 2.5 × 10²⁸ erg. For the second flare, the energy in the fast electrons is more than one order of magnitude greater than the energy of the convective up-flow. Total energy losses are within a factor of two lower than the calculated fast electron energy. We interpret the observations as showing that the first flare occurred in a small loop with fast electrons heating the chromosphere and resulting in chromospheric evaporation increasing the density in the loop. For the second flare most of the heating occurred at the electron acceleration site. The two symmetrical components of the Ca xix resonance line and a high velocity down-flow of 115 km s ^–1 observed at the end of the second hard X-ray burst are consistent with the flare eruption (reconnection) region being high in the flare loop. The estimated altitude of the acceleration site is 5500 km above the photosphere.     

Global cooling inferred from dropstones in the Cretaceous: fact or wishful thinking?

Traditionally, the Cretaceous has been considered as a long period of global warmth, a 'greenhouse' world. This view has been challenged in recent years by several lines of evidence; palaeobotany, stable isotopes, and palaeoclimatic modelling in particular. However, although these data demonstrate that cooling is likely, the only first-hand evidence which demonstrates the presence of substantial ice build-up in Cretaceous high palaeolatititudes are dropstones. These outsized or exotic clasts set in a fine-grained sediment are often interpreted as a direct result of ice rafting. The reliability of this dropstone evidence and particularly its validity is questioned in demonstrating ice age interludes within the Cretaceous greenhouse.     

Induction of Metamorphosis in the Asian Shore Crab <Emphasis Type="Italic">Hemigrapsus sanguineus</Emphasis>: Effects of Biofilms and Substratum Texture

Since its initial invasion in the late 1980s, the Asian shore crab Hemigrapsus sanguineus has spread over 650 km along the Atlantic Coast of the United States. Larvae of this species can live in the water column for over 3 weeks, which provides ample time for transport to new locations. Previous research on the settlement and metamorphosis of H. sanguineus showed that postlarvae (megalopae) accelerate metamorphosis in response to very specific water-soluble cues. However, the response to substratum cues appears to be much broader. The experiments presented here were designed to test the metamorphic response to biofilms and substratum texture. We found that nylon mesh with pore size of 100 and 1,000 μm had a greater effect on mean time to metamorphosis than 10 and 2,000 μm mesh. Results also showed a positive response to natural rock substrata, and this response was most pronounced when megalopae were exposed to substrata with rough texture. In addition, we found that a combination of a textured surface and a natural biofilm accelerated metamorphosis more than either an abiotic substratum or a smooth surface covered with natural biofilm. A final experiment compared the effect of textural cues to that of a water-soluble cue found in exudate from adult H. sanguineus. Results indicated that both types of cue-induced metamorphosis to the same extent.     

‘Jack of all trades’? The negotiation of interdisciplinarity within geography

This paper explores the relationship between interdisciplinary studies and research and researchers’ positionalities, both within and beyond geography. The profound degree to which researchers’ assumptions, expectations and attitudes (which in turn are affected by their personal backgrounds, training, location, etc.) influences the very notion of interdisciplinarity, and what it involves and consists of, is often neither noted nor appreciated. This paper will illustrate, particularly through personal examples, how positionality is part of the circuit of knowledge production, informing academic research, employment and publishing to no small extent. The boundaries of interdisciplinary research are shown to be under constant negotiation, still far from mutual understanding or consensus, a fact which explains the often uneasy identification and negotiation of oneself as an interdisciplinary scholar. The paper concludes by making recommendations at individual and institutional level on how to overcome some of the constraints imposed by researchers’ positionalities to the promotion of interdisciplinary research.