Effect of Different Sampling Methodologies on Measured Methane Concentrations in Groundwater Samples

Analysis of dissolved light hydrocarbon gas concentrations (primarily methane and ethane) in water supply wells is commonly used to establish conditions before and after drilling in areas of shale gas and oil extraction. Several methods are currently used to collect samples for dissolved gas analysis from water supply wells; however, the reliability of results obtained from these methods has not been quantified. This study compares dissolved methane and ethane concentrations measured in groundwater samples collected using three sampling methods employed in pre‐ and post‐drill sampling programs in the Appalachian Basin. These include an open‐system collection method where 40 mL volatile organic analysis (VOA) vials are filled directly while in contact with the atmosphere (Direct‐Fill VOA) and two alternative methods: (1) a semi‐closed system method whereby 40 mL VOA vials are filled while inverted under a head of water (Inverted VOA) and (2) a relatively new (2013) closed system method in which the sample is collected without direct contact with purge water or the atmosphere (IsoFlask^®). This study reveals that, in the absence of effervescence, the difference in methane concentrations between the three sampling methods was relatively small. However, when methane concentrations equaled or exceeded 20 mg/L (the approximate concentration at which effervescence occurs in the study area), IsoFlask^® (closed system) samples yielded significantly higher methane concentrations than Direct‐Fill VOA (open system) samples, and Inverted VOA (semi‐closed system) samples yielded lower concentrations. These results suggest that open and semi‐closed system sample collection methods are adequate for non‐effervescing samples. However, the use of a closed system collection method provides the most accurate means for the measurement of dissolved hydrocarbon gases under all conditions.     

Sedimentology,stratigraphy and architecture of the Nicobar Fan (Bengal–Nicobar Fan System), Indian Ocean: Results from International Ocean Discovery Program Expedition 362

Drill sites in the southern Bay of Bengal at 3°N 91°E (International Ocean Discovery Program Expedition 362) have sampled for the first time a complete section of the Nicobar Fan and below to the oceanic crust. This generally overlooked part of the Bengal–Nicobar Fan System may provide new insights into uplift and denudation rates of the Himalayas and Tibetan Plateau. The Nicobar Fan comprises sediment gravity-flow deposits, mostly turbidites, that alternate with hemipelagite drapes and pelagite intervals of varying thicknesses. The decimetre-thick to metre-thick oldest pre-fan sediments (limestones/chalks) dated at 69 Ma are overlain by volcanic material and slowly accumulated pelagites (0.5 g cm⁻² kyr⁻¹). At Expedition 362 Site U1480, terrigenous input began in the early Miocene at ca 22.5 Ma as muds, overlain by very thin-bedded and thin-bedded muddy turbidites at ca 19.5 Ma. From 9.5 Ma, sand content and sediment supply sharply increase (from 1–5 to 10–50 g cm⁻² kyr⁻¹). Despite the abundant normal faulting in the Nicobar Fan compared with the Bengal Fan, it offers a better-preserved and more homogeneous sedimentary record with fewer unconformities. The persistent connection between the two fans ceased at 0.28 Ma when the Nicobar Fan became inactive. The Nicobar Fan is a major sink for Himalaya-derived material. This study presents integrated results of International Ocean Discovery Program Expedition 362 with older Deep Sea Drilling Project/Ocean Drilling Program/International Ocean Discovery Program sites that show that the Bengal–Nicobar Fan System experienced successive large-scale avulsion processes that switched sediment supply between the Bengal Fan (middle Miocene and late Pleistocene) and the Nicobar Fan (late Miocene to early Pleistocene). A quantitative analysis of the submarine channels of the Nicobar Fan is also presented, including their stratigraphic frequency, showing that channel size/area and abundance peaked at ca 2 to 3 Ma, but with a distinct low at 3 to 7 Ma: the intervening stratigraphic [sub]unit was a time of reduced sediment accumulation rates.     

A detailed paleomagnetic and rock-magnetic investigation around Cretaceous-Paleogene boundary: the Autlan (Western Mexico) volcanic sequence revisited

We present a detailed rock-magnetic and paleomagnetic survey from Autlan volcanic succession in western Mexico. The principal aim of this study is to extend paleomagnetic data from Autlan lavas in order to confirm vertical-axis rotation observed in reconnaissance study and to evaluate long-term variation of the geomagnetic field strength based on existing and global data. The mean inclination (44.7°) is in agreement with the expected inclination for 60 and 70 Ma, as derived from available reference poles for the North American craton. The declination (333.6°), however, is significantly different from those expected, which suggests a statistically significant counterclockwise tectonic rotation ranging between 10° ± 6° and 14° ± 7°. As a measure of paleosecular variation (PSV), we obtained a geomagnetic field dispersion of 9.6° (upper and lower limits: 7.2°–11.9°) in perfect agreement with the previously published PSV compilation of selected Cretaceous data from lavas. The mean virtual dipole moments available for Autlan lavas are about 65% of the present geomagnetic axial dipole but are in reasonably good agreement with other comparable quality determinations between 5 and 90 Ma. This reinforces the hypothesis that low geomagnetic field strengths persisted for the entire Jurassic extending into the Upper Cretaceous.     

Assessing Methane in Shallow Groundwater in Unconventional Oil and Gas Play Areas,Eastern Kentucky

The expanding use of horizontal drilling and hydraulic fracturing technology to produce oil and gas from tight rock formations has increased public concern about potential impacts on the environment, especially on shallow drinking water aquifers. In eastern Kentucky, horizontal drilling and hydraulic fracturing have been used to develop the Berea Sandstone and the Rogersville Shale. To assess baseline groundwater chemistry and evaluate methane detected in groundwater overlying the Berea and Rogersville plays, we sampled 51 water wells and analyzed the samples for concentrations of major cations and anions, metals, dissolved methane, and other light hydrocarbon gases. In addition, the stable carbon and hydrogen isotopic composition of methane (δ¹³C‐CH₄ and δ²H‐CH₄) was analyzed for samples with methane concentration exceeding 1 mg/L. Our study indicates that methane is a relatively common constituent in shallow groundwater in eastern Kentucky, where methane was detected in 78% of the sampled wells (40 of 51 wells) with 51% of wells (26 of 51 wells) exhibiting methane concentrations above 1 mg/L. The δ¹³C‐CH₄ and δ²H‐CH₄ ranged from ?84.0‰ to ?58.3‰ and from ?246.5‰ to ?146.0‰, respectively. Isotopic analysis indicated that dissolved methane was primarily microbial in origin formed through CO₂ reduction pathway. Results from this study provide a first assessment of methane in the shallow aquifers in the Berea and Rogersville play areas and can be used as a reference to evaluate potential impacts of future horizontal drilling and hydraulic fracturing activities on groundwater quality in the region.     

Modeling and interpreting the seismic-reflection expression of sandstone in an ancient mass-transport deposit dominated deep-water slope environment

Subsurface mass-transport deposits (MTDs) commonly have a chaotic seismic-reflection response. Synthetic seismic-reflection profiles, created from a precise lithological model, are used to interpret reflection character and depositional geometries at multiple frequencies. The lithological model was created from an outcrop of deep-water lithofacies where sandstone deposition was influenced by mass-transport deposit topography. The influence of MTD topography on sandstone distribution should be considered in reservoir characterization and modeling when MTDs underlie the reservoir, especially if the reservoir is thin relative to the scale of the topography. MTD topography up to several tens of meters in both the horizontal and vertical dimensions (relative to local elevation) compartmentalizes significant quantities of sandstone and is not resolved at lower seismic-reflection frequencies. The resolvability of thick (up to 70 m) sandstone packages is hindered when they are encased in MTDs of at least equivalent thickness. Lateral and vertical changes in seismic-reflection character (e.g., amplitude, polarity, geometry) of sandstone packages in the synthetic profiles are due to lithology changes, tuning effects, resolution limits, and depositional geometries, which are corroborated by the lithological model. Similar reflection-character changes are observed in an actual seismic-reflection profile, of comparable scale to the synthetic profiles, from the Gulf of Mexico, which demonstrates similar lithofacies distributions. Synthetic profiles, when constrained by a precise lithological model, are particularly useful analogues for interpretation of lithofacies relationships, and depositional geometries, in complicated depositional environments, such as deep-water slope deposits.     

The 20th-century development and expansion of Louisiana shelf hypoxia,Gulf of Mexico

Since systematic measurements of Louisiana continental-shelf waters were initiated in 1985, hypoxia (oxygen content <2 mg L⁻¹) has increased considerably in an area termed the dead zone. Monitoring and modeling studies have concluded that the expansion of the Louisiana shelf dead zone is related to increased anthropogenically derived nutrient delivery from the Mississippi River drainage basin, physical and hydrographical changes of the Louisiana Shelf, and possibly coastal erosion of wetlands in southern Louisiana. In order to track the development and expansion of seasonal low-oxygen conditions on the Louisiana shelf prior to 1985, we used a specific low-oxygen foraminiferal faunal proxy, the PEB index, which has been shown statistically to represent the modern Louisiana hypoxia zone. We constructed a network of 13 PEB records with excess ²¹⁰Pb-derived chronologies to establish the development of low-oxygen and hypoxic conditions over a large portion of the modern dead zone for the last 100 years. The PEB index record indicates that areas of low-oxygen bottom water began to appear in the early 1910s in isolated hotspots near the Mississippi Delta and rapidly expanded across the entire Louisiana shelf beginning in the 1950s. Since ~1950, the percentage of PEB species has steadily increased over a large portion of the modern dead zone. By 1960, subsurface low-oxygen conditions were occurring seasonally over a large part of the geographic area now known as the dead zone. The long-term trends in the PEB index are consistent with the 20th-century observational and proxy data for low oxygen and hypoxia.     

Holocene evolution of Apalachicola Bay,Florida

A program of geophysical mapping and vibracoring was conducted to better understand the geologic evolution of Apalachicola Bay. Analyses of the geophysical data and sediment cores along with age control provided by 34 AMS ¹⁴C dates on marine shells and wood reveal the following history. As sea level rose in the early Holocene, fluvial deposits filled the Apalachicola River paleochannel, which extended southward under the central part of the bay and seaward across the continental shelf. Sediments to either side of the paleochannel contain abundant wood fragments, with dates documenting that those areas were forested at 8,000 ¹⁴C years b.p. As sea level continued to rise, spits formed of headland prodelta deposits. Between ∼6,400 and ∼2,500 ¹⁴C years b.p., an Apalachicola prodelta prograded and receded several times across the inner shelf that underlies the western part of the bay. An eastern deltaic lobe was active for a shorter time, between ∼5,800 and 5,100 ¹⁴C years b.p. Estuarine benthic foraminiferal assemblages occurred in the western bay as early as 6,400 ¹⁴C years b.p., and indicate that there was some physical barrier to open-ocean circulation and shelf species established by that time. It is considered that shoals formed in the region of the present barrier islands as the rising sea flooded an interstream divide. Estuarine conditions were established very early in the post-glacial flooding of the bay.