Monte Carlo Simulations as a Decision Support to Interpret δ15N Values of Nitrate in Groundwater

Intense farming is often associated with the excessive use of manure or fertilizers and the subsequent deterioration of the groundwater quality in many aquifers worldwide. Stable isotopes of dissolved nitrate (δ¹⁵N and δ¹⁸O) are widely used to determine sources of nitrate contamination and denitrification processes in groundwater but are often difficult to interpret. Thus, Monte Carlo simulations were carried out for a site in lower Bavaria, Germany, in order to explain δ¹⁵N observations in a porous groundwater system with two aquifers, the main aquifer (MA) and several smaller perched aquifers (PA). For evaluating potential contributions, frequency distributions of δ¹⁵N were simulated deriving from (I) the mixing of different nitrate sources, related to land use, as input to groundwater, combined with (II) transport of nitrate in groundwater and (III) microbial denitrification. Simulation results indicate a source-driven isotopic shift to heavier δ¹⁵N values of nitrate in groundwater, which may be explained by land use changes toward a more intensified agriculture releasing high amounts of manure. Microbial denitrification may play a role in the PA, with simulated δ¹⁵N distributions close to the observations. Denitrification processes are however unlikely for the MA, as reasonable simulation curve fits for such a scenario were obtained predominantly for unrealistic portions of nitrate sources and related land use. The applied approach can be used to qualitatively and quantitatively evaluate the influence of different potential contributions, which might mask each other due to overlapping δ¹⁵N ranges, and it can support the estimation of nitrate input related to land use.     

Application of Four Measurement Techniques to Understand Natural Source Zone Depletion Processes at an LNAPL Site

There are several key data gaps in our understanding of Natural Source Zone Depletion (NSZD) processes at sites impacted by light nonaqueous phase liquid (LNAPL), and quantifying NSZD rates can be challenging due to the inherent differences in measurement methods. In this study, four different NSZD measurement methods (oxygen influx measured by the Gradient Method, long-term carbon dioxide efflux measured with Carbon Traps, instantaneous carbon dioxide efflux measured with Dynamic Closed Chambers (DCC LI-COR), and the long-term heat flux from biodegradation measured by Thermal NSZD monitoring), as well as LNAPL composition and dissolved gas sampling, were applied at a site in Southern California. These techniques were used to evaluate key questions such as: (1) how do different NSZD rate measurement methods compare, and what causes variability in NSZD results?; (2) to what extent NSZD processes are occurring in LNAPL within the saturated zone?; and (3) how is NSZD related to LNAPL composition change over time? Carbon Traps and Thermal NSZD monitoring measurement methods provided the most consistent NSZD data at this geologically heterogeneous site, with two location average NSZD rates of 540 and 480 gal/acre/year, respectively. Overall, comparisons of NSZD rates between methods were challenging due to different measurement timeframes, significant temporal and spatial heterogeneity, and operational challenges with two of the NSZD methods. Finally, samples of subsurface LNAPL were collected for analysis in 2007 and 2016; results indicated that diesel-range constituents were already very degraded and anaerobic degradation of gasoline-range constituents was ongoing. A LNAPL depletion model (Douglas et al. 1996) applied to the measured LNAPL composition change appeared to greatly overestimate the amount of LNAPL depletion compared to the measured NSZD rate, but did provide an independent semiqualitative line of evidence that LNAPL was being depleted by active NSZD processes at the site.     

A paleointensity study of Cretaceous volcanic rocks from the Western Cordillera,Colombia

The Cretaceous Normal Superchron is a period of great interest to investigate global scale variations of the geomagnetic field. Long periods of single polarity are still a matter of debate: up to now there are two contradicting theories, which try to relate geomagnetic field intensity and reversal rate. We aim to shed light on the geomagnetic field strength during the Cretaceous Normal Superchron because data are still scarce and of dissimilar quality. To obtain reliable, absolute paleointensity determinations we investigate volcanic rocks from the Western Cordillera of Colombia. Several age determinations allow relating the samples to an age of about 92.5 Ma. To characterize the samples, we investigate rock magnetic properties and determine the characteristic remanent magnetization behavior. To determine paleointensities, we use a multimethod approach: first, we apply the classic Thellier-Coe protocol, and then, the relatively new multispecimen method. Rock magnetic measurements indicate magnetite as the main ferrimagnetic mineral, a stable magnetization revealed by reversible and nearly reversible thermomagnetic curves, and grain sizes that are either in the pseudosingle domain range or a mixture of single and multidomain grains. Alternating field and thermal demagnetization are rather complex, although we observe a few vector diagrams with a single, essentially uni-vectorial component with a small viscous overprint. Paleointensity determination with the Thellier-Coe protocol was unsuccessful, while with the multispecimen protocol we obtained four successful determinations out of 20. The failure of the Thellier-Coe protocol can be attributed to multidomain grains, which were observed during demagnetization and in rock magnetic experiments, and to the inhomogeneity of the volcanic rocks. Our multispecimen paleointensity determinations support low field strength at around 90 Ma during the Cretaceous Normal Superchron.     

Sustainable livelihoods approaches to inform government‐local partnerships and decision‐making in vulnerable environments

Sustainable livelihoods approaches used in international development are applied to a vulnerable New Zealand catchment. The Waiapu Catchment has a high proportion of indigenous residents, and is one of the most remote and deprived areas in the country. Linear and centralised approaches to indigenous development have failed to bring about desired changes. We identify “capitals” (social, human/political, physical, natural, financial and cultural) present in the catchment. From this assessment, we propose capital‐based holistic approaches to bring about community‐led change. The assessment and resulting approaches can be used in other vulnerable environments around the world.     

Between plate and salt tectonics—New stratigraphic constraints on the architecture and timing of the Dead Sea basin during the Late Quaternary

The Dead Sea is an extensional basin developing along a transform fault plate boundary. It is also a terminal salt basin. Without knowledge of precise stratigraphy, it is difficult to differentiate between the role of plate and salt tectonics on sedimentary accumulation and deformation patterns. While the environmental conditions responsible for sediment supply are reasonably constrained by previous studies on the lake margins, the current study focuses on deciphering the detailed stratigraphy across the entire northern Dead Sea basin as well as syn and post-depositional processes. The sedimentary architecture of the late Quaternary lacustrine succession was examined by integrating 851 km of seismic reflection data from three surveys with gamma ray and velocity logs and the stratigraphic division from an ICDP borehole cored in 2010. This allowed seismic interpretation to be anchored in time across the entire basin. Key surfaces were mapped based on borehole lithology and a newly constructed synthetic seismogram. Average interval velocities were used to calculate isopach maps and spatial and temporal sedimentation rates. Results show that the Amora Formation was deposited in a pre-existing graben bounded by two N-S trending longitudinal faults. Both faults remained active during deposition of the late Pleistocene Samra and Lisan Formations—the eastern fault continued to bound the basin while the western fault remained blind. On-going plate motion introduced a third longitudinal fault, increasing accommodation space westwards from the onset of deposition of the Samra Formation. During accumulation of these two formations, sedimentation rates were uniform over the lake and similar. High lake levels caused an increase in hydrostatic pressure. This led to salt withdrawal, which flowed to the south and southwest causing increased uplift of the Lisan and En Gedi diapirs and the formation of localized salt rim synclines. This induced local seismicity and slumping, resulting in an increased thickness of the Lisan succession within the lake relative to its margins. Sedimentation rates of the Holocene Ze'elim Fm were 4–5 times higher than before. The analysis presented here resolves central questions of spatial extent and timing of lithology, deposition rates and their variability across the basin, timing of faulting at and below the lake floor, and timing and extent of salt and plate tectonic phases and their effect on syn and post-depositional processes. Plate tectonics dictated the structure of the basin, while salt tectonics and sediment accumulation were primarily responsible for its fill architecture during the timeframe examined here.     

Physical reworking by near-bottom flow alters the metazoan meiofauna of Fieberling Guyot (northeast Pacific)

Although much of the deep sea is physically tranquil, some regions experience near-bottom flows that rework the surficial sediment. During periods of physical reworking, animals in the reworked layer risk being suspended, which can have both positive and negative effects. Reworking can also change the sediment in ecologically important ways, so the fauna of reworked sites should differ from that of quiescent locations. We combined data from two reworked, bathyal sites on the summit of Fieberling Guyot (32°27.631′N, 127°49.489′W; 32°27.581′N, 127°47.839′W) and compared the results with those of more tranquil sites. We tested for differences in the following parameters, which seemed likely to be sensitive to the direct or indirect effects of reworking: (1) the vertical distribution of the meiofauna in the sea bed, (2) the relative abundance of surface-living harpacticoids, (3) the proportion of the fauna consisting of interstitial harpacticoids, (4) the ratio of harpacticoids to nematodes. We found that the vertical distributions of harpacticoid copepods, ostracods, and kinorhynchs were deeper on Fieberling. In addition, the relative abundance of surface-living harpacticoids was less, the proportion of interstitial harpacticoids was greater, and the ratio of harpacticoids to nematodes was greater on Fieberling. These differences between Fieberling and the comparison sites suggest that physical reworking affects deep-sea meiofauna and indicate the nature of some of the effects.     

DIRECT DATING OF LEFT-LATERAL SLIP ALONG THE RED RIVER SHEAR ZONE

DIRECT DATING OF LEFT-LATERAL SLIP ALONG THE RED RIVER SHEAR ZONE     

The influence of geological, geochemical, and biogenic habitat heterogeneity on seep biodiversity

Cold seeps are among the most heterogeneous of all continental margin habitats. Abiotic sources of heterogeneity in these systems include local variability in fluid flow, geochemistry, and substrate type, which give rise to different sets of microbial communities, microbial symbiont-bearing foundation species, and associated heterotrophic species. Biogenic habitats created by microbial mats and the symbiotic species including vesicomyid clams, bathymodiolin mussels, and siboglinid tubeworms add an additional layer of complexity to seep habitats. These forms of habitat heterogeneity result in a variety of macrofaunal and meiofaunal communities that respond to changes in structural complexity, habitat geochemistry, nutrient sources, and interspecific interactions in different ways and at different scales. These responses are predicted by a set of theoretical metacommunity models, the most appropriate of which for seep systems appears to be the 'species sorting' concept, an extension of niche theory. This concept is demonstrated through predictable patterns of community assembly, succession, and beta-level diversity. These processes are described using a newly developed analytical technique examining the change in the slope of the species accumulation curve with the number of habitats examined. The diversity response to heterogeneity has a consistent form, but quantitatively changes at different seep sites around the world as the types of habitats present and the size-classes of fauna analyzed change. The increase in beta diversity across seep habitat types demonstrates that cold seeps and associated biogenic habitats are significant sources of heterogeneity on continental margins globally.     

Zonal winds and southeast Australian rainfall in global and regional climate models

Southeast Australia is a region of high rainfall variability related to major climate drivers, with a long-term declining trend in cool-season rainfall. Projections of future rainfall trends are uncertain in this region, despite projected southward shifts in the subtropical ridge and mid-latitude westerlies. This appears to be related to a poor representation of the spatial relationships between rainfall variability and zonal wind patterns across southeast Australia in the latest Coupled Model Intercomparison Project ensemble, particularly in the areas where weather systems embedded in the mid-latitude westerlies are the main source of cool-season rainfall. Downscaling with regional climate models offers improvements in the mean rainfall climatology, and shows some ability to correct for poor modelled relationships between rainfall and zonal winds along the east coast of Australia. However, it provides only minor improvements to these relationships in southeast Australia, despite the improved representation of topographic features. These results suggest that both global and regional climate models may fail to translate projected circulation changes into their likely rainfall impacts in southeast Australia.     

用树轮密度及宽度资料重建新疆吉木萨尔县的季节降水和最高温度

依据新疆吉木萨尔县天山云杉树木年轮宽度、最大密度和最小密度标准化年表,讨论了晚材宽度、最大密度和最小密度,与月平均最高温度和降水的响应函数基本特征,采用逐步回归方法,确定了利用晚材宽度指数、最大密度指数和最小密度指数重建该地６～９月份降水,以及利用最大密度指数和最小密度指数重建该地４～９月份平均最高温度。重建结果可靠且与实际情况较为一致。分析发现,该地区在过去１５０年中,月平均最高温度和降水有明显的阶段性变化。