Combined Use of Remote Sensing and Continuous Monitoring to Analyse the Variability of Suspended-Sediment Concentrations in San Francisco Bay, California

Analysis of suspended-sediment concentration data in San Francisco Bay is complicated by spatial and temporal variability. In situ optical backscatterance sensors provide continuous suspended-sediment concentration data, but inaccessibility, vandalism, and cost limit the number of potential monitoring stations. Satellite imagery reveals the spatial distribution of surficial-suspended sediment concentrations in the Bay; however, temporal resolution is poor. Analysis of thein situ sensor data in conjunction with the satellite reflectance data shows the effects of physical processes on both the spatial and temporal distribution of suspended sediment in San Francisco Bay. Plumes can be created by large freshwater flows. Zones of high suspended-sediment concentrations in shallow subembayments are associated with wind-wave resuspension and the spring-neap cycle. Filaments of clear and turbid water are caused by different transport processes in deep channels, as opposed to adjacent shallow water. Crown     

Temporary streams in a peatland catchment: pattern,timing, and controls on stream network expansion and contraction

In peatlands, poorly maintained baseflows mean that network expansion during storm events can be rapid and pronounced, resulting in large changes in catchment connectivity. This has implications for the timing and magnitude of material fluxes from these environments, understanding of which is becoming increasingly important due to peatlands' significance as global carbon stores. In this study, electrical resistance (ER) technology has been used to create sensors capable of detecting the presence and absence of flow in ephemeral portions of the channel network. These sensors provide data on the patterns of network variation in the Upper North Grain research catchment, a small peatland headwater in the South Pennines, UK. Networks of around 40 sensors were deployed in autumn 2007 and summer 2008, giving a total of almost four months of high‐resolution monitoring data. Drainage density in the catchment was found to vary between 1.4 and 30.0 km/km², suggesting significant differences in connectivity between the expanded and contracted networks. Water table depth was identified as the key factor determining the temporal pattern of streamflow at both the site‐ and catchment‐wide scales. Spatially, network expansion and contraction occurred in a disjointed manner, following a similar pattern between events, suggesting that localized controls are important for flow generation. Spatial controls on flow generation relate to local water table levels, and include drainage area, local dissection, channel slope and gully morphology. The importance of water table as the key control on catchment connectivity suggests that potential future change in catchment water tables, associated with projected climate change or with peatland restoration by rewetting, will modify the frequency of full catchment connectivity. Copyright © 2014 John Wiley & Sons, Ltd.     

Zero-valent iron and organic carbon mixtures for remediation of acid mine drainage: Batch experiments

A series of laboratory batch experiments was conducted to evaluate the potential for treatment of acid mine drainage (AMD) using organic C (OC) mixtures amended by zero-valent Fe (Fe⁰). Modest increases in SO₄ reduction rates (SRRs) of up to 15% were achieved by augmenting OC materials with 5 and 10 dry wt% Fe⁰. However, OC was essential for supporting SO₄ reducing bacteria (SRB) and therefore SO₄ reduction. This observation suggests a general absence of autotrophic SRB which can utilize H₂ as an electron donor. Sulfate reduction rates (SRRs), calculated using a mass-based approach, ranged from −12.9 to −14.9 nmol L⁻¹ d⁻¹  g⁻¹ OC. Elevated populations of SRB, iron reducing bacteria (IRB), and acid producing (fermentative) bacteria (APB) were present in all mixtures containing OC. Effective removal of Fe (91.6–97.6%), Zn (>99.9%), Cd (>99.9%), Ni (>99.9%), Co (>99.9%), and Pb (>95%) was observed in all reactive mixtures containing OC. Abiotic metal removal was achieved with Fe⁰ only, however Fe, Co and Mn removal was less effective in the absence of OC. Secondary disordered mackinawite [Fe_1+xS] was observed in field-emission scanning electron microscopy (FE-SEM) backscatter electron micrographs of mixtures that generated SO₄ reduction. Energy dispersive X-ray (EDX) spectroscopy revealed that Fe–S precipitates were Fe-rich for mixtures containing OC and Fe⁰, and S-rich in the absence of Fe⁰ amendment. Sulfur K-edges determined by synchrotron-radiation based bulk X-ray absorption near-edge structure (XANES) spectroscopy indicate solid-phase S was in a reduced form in all mixtures containing OC. Pre-edge peaks on XANES spectra suggest tetragonal S coordination, which is consistent with the presence of an Fe–S phase such as mackinawite. The addition of Fe⁰ enhanced AMD remediation over the duration of these experiments, however long-term evaluation is required to identify optimal Fe⁰ and OC mixtures.     

Sediments and history of the Rottnest Shelf, southwest Australia: a swell-dominated, non-tropical carbonate margin

The Rottnest Shelf is a narrow, wave-dominated open shelf on the passive continental margin of southwest Australia, adjacent to a hinterland of low relief and sluggish drainage. High physical energy, low nutrients in cool subtropical waters, and rapid postglacial transgression have limited carbonate productivity, restricted grain types, and reworked the transgressed surface to form only a thin ( < 1 m) blanket of carbonate and relict sediment, with little terrigenous influx. Subaerial weathering of the shelf during Late Pleistocene emergence was followed by postglacial drowning, erosional shoreface retreat, and generation of a transgressive lag deposit. Establishment of the warm temperate biota, dominated by bryozoans and calcareous red algae, resulted in bioerosion of the shelf disconformity surface and generation of hardground veneers and thin skeletal carbonate sheets. Linear topographic ridges of Pleistocene limestone partition the shelf into systems with varying physical energy, biota and sediment supply. The Holocene sediments are a shallowing-upward coastal sequence; wave-ripple cross-stratified grainstone (Inner Shelf); and bioturbated bryozoan grainstone to skeletal wackestone (Outer Shelf to Upper Continental Slope), characterised by seaward fining and increasing percentages of planktic carbonate sediment.

Given sufficient time, the Rottnest Shelf could recover from drowning, and form blanket-like skeletal carbonates. Thin ( < 1 m) lags overlying disconformities, which underlie shallowing-upward coastal and shelf sediments a few metres thick, will be generated by glacio-eustatic cycles of sedimentation (10⁵ y duration). Thick (several tens of metres) sediment bodies, composed of wave-rippled to bioturbated skeletal carbonate sediment with a temperate biota, will be formed during longer term (1–10 My) sedimentation cycles. Such cycles have characterised passive margins during the Cenozoic. The Rottnest Shelf thus provides a facies model for temperate shelf sedimentation along passive continental margins.