A Study of Ozone Laminae Using Diabatic Trajectories, Contour Advection and Photochemical Trajectory Model Simulations.

In this paper, we show that the rate of ozone loss in both polar and mid-latitudes, derived from ozonesonde and satellite data, has almost the same vertical distribution (although opposite sense) to that of ozone laminae abundance. Ozone laminae appear in the lower stratosphere soon after the polar vortex is established in autumn, increase in number throughout the winter and reach a maximum abundance in late winter or spring. We indicate a possible coupling between mid-winter, sudden stratospheric warmings (when the vortex is weakened or disrupted) and the abundance of ozone laminae using a 23-year record of ozonesonde data from the World Ozone Data Center in Canada combined with monthly-mean January polar temperatures at 30 hPa.Results are presented from an experiment conducted during the winter of 1994/95, in phase II of the Second European Stratospheric And Mid-latitude Experiment (SESAME), in which 93 ozone-enhanced laminae of polar origin observed by ozonesondes at different time and locations are linked by diabatic trajectories, enabling them to be probed twice or more. It is shown that, in general, ozone concentrations inside laminae fall progressively with time, mixing irreversibly with mid-latitude air on time-scales of a few weeks. A particular set of laminae which advected across Europe during mid February 1995 are examined in detail. These laminae were observed almost simultaneously at seven ozonesonde stations, providing information on their spatial scales. The development of these laminae has been modelled using the Contour Advection algorithm of Norton (1994), adding support to the concept that many laminae are extrusions of vortex air. Finally, a photochemical trajectory model is used to show that, if the air in the laminae is chemically activated, it will impact on mid-latitude ozone concentrations. An estimate is made of the potential number of ozone molecules lost each winter via this mechanism.     

The paleomagnetism and magnetic polarity stratigraphy of the mammal-bearing section of Anza Borrego State Park, California

We sampled 150 sites in fine-grained Plio-Pleistocene sediments of the Palm Springs and Imperial Formations. Sampling was confined to 3000 m of stratigraphically continuous section containing abundant vertebrate fossil remains of the Vallecito Creek, Arroyo Seco, and Layer Cake local faunas of the Irvingtonian and Blancan Land Mammal Ages. The magnetic stability of these sediments was sufficient to delineate the magnetic stratigraphy, which ranges from below the Cochiti event at the base, to the Matuyama reversed magnetic epoch at the top of the section. Eight faunal events are placed relative to the magnetic polarity sequence. They are cf. Pliohippus extinction, Geomys appearance, cf. Equus appearance, Tremarctos appearance, Hypolagus extinction, cf. Odocoileus appearance, Smilodon and ? Euceratherium appearance. The latter two faunal events characterize Irvingtonian Land Mammal Age. The transition from the Blancan to Irvingtonian Land Mammal Age occurs in the lower Matuyama magnetic epoch close to the Pliocene-Pleistocene boundary. The appearance of European migrants during the lower Matuyama magnetic epoch indicates that the Bering land bridge was exposed for animal migration between Europe and North America at this time.     

Do paleoclimate proxies agree? A test comparing 19 late Holocene climate and sea‐ice reconstructions from Icelandic marine and lake sediments

Geochemical, mineralogical and biological indicators preserved in sediments are widely used to reconstruct past climate change, but proxies differ in the degree to which their utility as climate indicators has been validated via laboratory experiments, modern spatial calibrations, or down‐core comparisons with instrumental climate data. Multi‐proxy studies provide another means of evaluating interpretations of proxies. This paper presents a multi‐proxy assessment comparing 19 sub‐centennially resolved late Holocene proxy records, covering the period 300–1900 AD, from seven Icelandic marine and lacustrine core sites. We employ simple statistical comparisons between proxy reconstructions to evaluate their correlations over time and, ultimately, their utility as proxies for regional climate. Proxies examined include oxygen isotopic composition of benthic and planktonic foraminifera, abundance of the sea‐ice biomarker IP₂₅, allochthonous quartz in marine sediments (a proxy for drift ice around Iceland), marine carbonate abundance, total organic carbon concentration, chironomid assemblages, lacustrine biogenic silica and carbon/nitrogen ratios in lake sediments. Most of the examined proxy records, including temperature and sea‐ice proxies, correlate strongly with each other over multi‐centennial timescales, and thus do appear to record changes in regional climate. Copyright © 2011 John Wiley & Sons, Ltd.     

Late Quaternary moisture export across Central America and to Greenland: evidence for tropical rainfall variability from Costa Rican stalagmites

We present a high-resolution terrestrial archive of Central American rainfall over the period 100–24 and 8.1–6.5 ka, based on δ¹⁸O time series from U-series dated stalagmites collected from a cave on the Pacific Coast of Costa Rica. Our results indicate substantial δ¹⁸O variability on millennial to orbital time scales that is interpreted to reflect rainfall variations over the cave site. Correlations with other paleoclimate proxy records suggest that the rainfall variations are forced by sea surface temperatures (SST) in the Atlantic and Pacific Oceans in a fashion analogous to the modern climate cycle. Higher rainfall is associated with periods of a warm tropical North Atlantic Ocean and large SST gradients between the Atlantic and Pacific Oceans. Rainfall variability is likely linked to the intensity and/or latitudinal position of the intertropical convergence zone (ITCZ). Periods of higher rainfall in Costa Rica are also associated with an enhanced sea surface salinity gradient on either side of the isthmus, suggesting greater freshwater export from the Atlantic Basin when the ITCZ is stronger and/or in a more northerly position. Further, wet periods in Central America coincide with high deuterium excess values in Greenland ice, suggesting a direct link between low latitude SSTs, tropical rainfall, and moisture delivery to Greenland. Our results indicate that a stronger tropical hydrological cycle during warm periods and large inter-ocean SST gradients enhanced the delivery of low latitude moisture to Greenland.     

Nanometer‐scale anatomy of entire Stardust tracks

Abstract– We have developed new sample preparation and analytical techniques tailored for entire aerogel tracks of Wild 2 sample analyses both on “carrot” and “bulbous” tracks. We have successfully ultramicrotomed an entire track along its axis while preserving its original shape. This innovation allowed us to examine the distribution of fragments along the entire track from the entrance hole all the way to the terminal particle. The crystalline silicates we measured have Mg‐rich compositions and O isotopic compositions in the range of meteoritic materials, implying that they originated in the inner solar system. The terminal particle of the carrot track is a ¹⁶O‐rich forsteritic grain that may have formed in a similar environment as Ca‐, Al‐rich inclusions and amoeboid olivine aggregates in primitive carbonaceous chondrites. The track also contains submicron‐sized diamond grains likely formed in the solar system. Complex aromatic hydrocarbons distributed along aerogel tracks and in terminal particles. These organics are likely cometary but affected by shock heating.     

Evidence of space weathering in regolith breccias II: Asteroidal regolith breccias

Abstract– Space weathering products, such as agglutinates and nanophase iron‐bearing rims are easily preserved through lithification in lunar regolith breccias, thus such products, if produced, should be preserved in asteroidal regolith breccias as well. A study of representative regolith breccia meteorites, Fayetteville (H4) and Kapoeta (howardite), was undertaken to search for physical evidence of space weathering on asteroids. Amorphous or npFe⁰‐bearing rims cannot be positively identified in Fayetteville, although possible glass rims were found. Extensive friction melt was discovered in the meteorite that is difficult to differentiate from weathered materials. Several melt products, including spherules and agglutinates, as well as one irradiated rim and one possible npFe⁰‐bearing rim were identified in Kapoeta. The existence of these products suggests that lunar‐like space weathering processes are, or have been, active on asteroids.     

Pristine stratospheric collection of interplanetary dust on an oil‐free polyurethane foam substrate

We performed chemical, mineralogical, and isotopic studies of the first interplanetary dust particles (IDPs) collected in the stratosphere without the use of silicone oil. The collection substrate, polyurethane foam, effectively traps impacting particles, but the lack of an embedding medium results in significant particle fragmentation. Two dust particles found on the collector exhibit the typical compositional and mineralogical properties of chondritic porous interplanetary dust particles (CP‐IDPs). Hydrogen and nitrogen isotopic imaging revealed isotopic anomalies of typical magnitude and spatial variability observed in previous CP‐IDP studies. Oxygen isotopic imaging shows that individual mineral grains and glass with embedded metal and sulfide (GEMS) grains are dominated by solar system materials. No systematic differences are observed in element abundance patterns of GEMS grains from the dry collection versus silicone oil‐collected IDPs. This initial study establishes the validity of a new IDP collection substrate that avoids the use of silicone oil as a collection medium, removing the need for this problematic contaminant and the organic solvents necessary to remove it. Additional silicone oil‐free collections of this type are needed to determine more accurate bulk element abundances of IDPs and to examine the indigenous soluble organic components of IDPs.     

Evidence of space weathering in regolith breccias I: Lunar regolith breccias

Abstract— We have analyzed a suite of lunar regolith breccias in order to assess how well space weathering products can be preserved through the lithification process and therefore whether or not it is appropriate to search for space weathering products in asteroidal regolith breccia meteorites. It was found that space weathering products, vapor/sputter deposited nanophase‐iron‐bearing rims in particular, are easily identified in even heavily shocked/compacted lunar regolith breccias. Such rims, if created on asteroids, should thus be preserved in asteroidal regolith breccia meteorites. Two additional rim types, glass rims and vesicular rims, identified in regolith breccias, are also described. These rims are common in lunar regolith breccias but rare to absent in lunar soils, which suggests that they are created in the breccia‐forming process itself. While not “space weathering products” in the strictest sense, these additional rims give us insight into the regolith breccia formation process. The presence or absence of glass and/or vesicular rims in asteroidal regolith breccias will likewise tell us about environmental conditions on the surface of the asteroid body on which the breccia was created.