Pollen sequence from the Chilean Lake District during the Llanquihue glaciation in marine Oxygen Isotope Stages 4–2

Pollen stratigraphy of a core taken from a fen at Fundo Nueva Braunau (40°17.49′S, 73°04.83′W), situated 2 km beyond the western border of Llanquihue‐age glacial drift, spans an age range from an estimated 60 000–70 000 BP to about 14 000 ¹⁴C yr BP (marine Oxygen Isotope Stages 4–2). The location at present is in the contact zone of Valdivian Evergreen Forest and Lowland Deciduous Beech Forest. Early and late in the pollen record, as indicated by assemblages of southern beech (Nothofagus dombeyi type) and grass (Gramineae), the site was located in Subantarctic Parkland. Intervening assemblages represent expansion of Valdivian–North Patagonian Evergreen Forest (> 49 355 to about 40 000 ¹⁴C yr BP) and North Patagonian Evergreen Forest–Subantarctic Parkland (approximately 40 000 to 30 000 ¹⁴C yr BP). Climate over the time span was under the storm regime of the Southern Westerlies and apparently uninterruptedly wet. When Subantarctic Parkland expanded, cold conditions with summer temperatures estimated at 8–9°C (7°C lower than present) resulted in episodes of glacier maxima. Climate moderated during the period of forest expansion, at which time glaciers were in a state of recession. Contrasting with the continuously wet climate of the Lake District for the period of record, climate in semi‐arid–arid, subtropical Chile underwent extended intervals of precipitation. Data from both the terrestrial and marine realm implicate the Southern Westerlies as the cause of intensified storm activity at lower latitudes. Copyright © 2000 John Wiley & Sons, Ltd.     

Assessing the Impact of Climate Change on the Great Lakes Shoreline Wetlands

Great Lakes shoreline wetlands are adapted to a variable water supply. They require the disturbance of water level fluctuations to maintain their productivity. However, the magnitude and rate of climate change could alter the hydrology of the Great Lakes and affect wetland ecosystems. Wetlands would have to adjust to a new pattern of water level fluctuations; the timing, duration, and range of these fluctuations are critical to the wetland ecosystem response. Two "what if" scenarios: (1) an increased frequency and duration of low water levels and (2) a changed temporal distribution and amplitude of seasonal water levels were developed to assess the sensitivity of shoreline wetlands to climate change. Wetland functions and values such as wildlife, waterfowl and fish habitat, water quality, areal extent, and vegetation diversity are affected by these scenarios. Key wetlands are at risk, particularly those that are impeded from adapting to the new water level conditions by man-made structures or geomorphic conditions. Wetland remediation, protection and enhancement policies and programs must consider climate change as an additional stressor of wetlands.     

Zircon from the East Orebody of the Bayan Obo Fe–Nb–REE deposit,China, and SHRIMP ages for carbonatite-related magmatism and REE mineralization events

Extremely U-depleted (<1 ppm) zircons from H8 banded ores in the East Orebody of the Bayan Obo REE–Nb–Fe deposit are presented, with mineral compositions, textures, ²³²Th–²⁰⁸Pb SHRIMP ages and petrological context. Cores of East Orebody zircon contain up to 7 wt% HfO₂ and are zoned, depicting bipyramidal crystal forms. A distinct generation of patchy, epitaxial rim zircon, similarly depleted in U, is intergrown with rare earth ore minerals (bastnäsite, parisite, monazite). Overprinting aegirine textures indicate paragenetically late, reactive Na-rich fluids. Chondrite-normalized REE patterns without Eu anomalies match closely with those from the Mud Tank and Kovdor carbonatitic zircons. Increased HREE in rims ((Lu/Gd)_N 43–112) relative to cores ((Lu/Gd)_N 6–7.5) and the localized presence of xenotime are attributable to reactive, mineralizing fluid compositions enriched in Y, REE and P. Cathodoluminescence further reveals HREE fractionation in rims, evidenced by a narrow-band Er³⁺ emission at 405 nm. The extreme depletion of U in core and rim zircon is characteristic for this mineral deposit and is indicative of a persistent common source. U depletion is also a characteristic for zircons from carbonatitic or kimberlitic systems. ²³²Th–²⁰⁸Pb (SHRIMP II) geochronological data reveal the age of zircon cores as 1,325 ± 60 Ma and a rim-alteration event as 455.6 ± 28.27 Ma. The combined findings are consistent with a protolithic igneous origin for zircon cores, from a period of intrusive, alkaline–carbonatitic magmatism. Fluid processes responsible for the REE–Nb mineralizations affected zircon rim growth and degradation during the widely reported Caledonian events, providing a new example in a localized context of HREE enrichment processes.     

Hydrogen isotope fractionation in lipids of the methane-oxidizing bacterium Methylococcus capsulatus

Hydrogen isotopic compositions of individual lipids from Methylococcus capsulatus, an aerobic, methane-oxidizing bacterium, were analyzed by hydrogen isotope-ratio-monitoring gas chromatography-mass spectrometry (GC-MS). The purposes of the study were to measure isotopic fractionation factors between methane, water, and lipids and to examine the biochemical processes that determine the hydrogen isotopic composition of lipids. M. capsulatus was grown in six replicate cultures in which the δD values of methane and water were varied independently. Measurement of concomitant changes in δD values of lipids allowed estimation of the proportion of hydrogen derived from each source and the isotopic fractionation associated with the utilization of each source.All lipids examined, including fatty acids, sterols, and hopanols, derived 31.4 ± 1.7% of their hydrogen from methane. This was apparently true whether the cultures were harvested during exponential or stationary phase. Examination of the relevant biochemical pathways indicates that no hydrogen is transferred directly (with C-H bonds intact) from methane to lipids. Accordingly, we hypothesize that all methane H is oxidized to H₂O, which then serves as the H source for all biosynthesis, and that a balance between diffusion of oxygen and water across cell membranes controls the concentration of methane-derived H₂O at 31%. Values for α_l/w, the isotopic fractionation between lipids and water, were 0.95 for fatty acids and 0.85 for isoprenoid lipids. These fractionations are significantly smaller than those measured in higher plants and algae. Values for α_l/m, the isotopic fractionation between lipids and methane, were 0.94 for fatty acids and 0.79 for isoprenoid lipids. Based on these results, we predict that methanotrophs living in seawater and consuming methane with typical δD values will produce fatty acids with δD between −50 and −170‰, and sterols and hopanols with δD between −150 and −270‰.     

Regional Nested Model Simulations of Present Day and 2 × CO2 Climate over the Central Plains of the U.S.

A nested regional climate model is used to generate a scenario of climate change over the MINK region (Missouri, Iowa, Nebraska, Kansas) due to doubling of carbon dioxide concentration (2 × CO₂) for use in agricultural impact assessment studies. Five-year long present day (control) and 2 × CO₂ simulations are completed at a horizontal grid point spacing of 50 km. Monthly and seasonal precipitation and surface air temperature over the MINK region are reproduced well by the model in the control run, except for an underestimation of both variables during the spring months. The performance of the nested model in the control run is greatly improved compared to a similar experiment performed with a previous version of the nested modeling system by Giorgi et al. (1994). The nested model generally improves the simulation of spatial precipitation patterns compared to the driving general circulation model (GCM), especially during the summer. Seasonal surface warming of 4 to 6 K and seasonal precipitation increases of 6 to 24% are simulated in 2 × CO₂ conditions. The control run temperature biases are smaller than the simulated changes in all seasons, while the precipitation biases are of the same order of magnitude as the simulated changes. Although the large scale patterns of change in the driving GCM and nested RegCM model are similar, significant differences between the models, and substantial spatial variability, occur within the MINK region.     

The Influence of O3, Relative Humidity, NO and NO2 on the Oxidation of α-Pinene and Δ3-Carene

Upto 13% of -pinene and ³-carene had reacted after 213 s in this dark experimental set-up, where O₃, NO and NO₂ were mixed with terpenes at different relative humidities (RHs). The different experiments were planned according to an experimental design, where O₃, NO₂, NO, RH and reaction time were varied between high and low settings (25 and 75 ppb, 15 and 42%, 44 and 213 s). An increased amount of -pinene and ³-carene reacted in the chamber was observed, when the level of O₃, NO and reaction time was increased and RH was decreased. In the study, it was found that different interactions affected the amount of terpene reacted as well. These interactions were between O₃ and NO, O₃ and reaction time, NO and RH, and between NO and reaction time.     

Nekton use of salt marsh creeks in the upper Tejo estuary

The use of the Tejo estuary, Portugal, salt marsh creeks by nekton was examined based on sampling surveys with a fyke net from September 1998 until August 2001. From the 20 taxa (14 fish species, 5 decapod crustacean species, and 1 cephalopod species) identified in the studied creeks, 16 were regularly caught throughout the sampling period. The shrimpPalaemonetes varians was the most numerically abundant species in the creeks, while the biomass was dominated by the mulletLiza ramada. The nekton assemblage was mainly represented by marine-estuarine opportunist species, comprising 85% of the total. A high seasonality was detected on the species abundance patterns: the most abundant species (P. varians, Crangon crangon, L. ramada, Pomatoschistus microps, Syngnathus sp., andAnguilla anguilla) occurred throughout the sampling period,Sardina pilchardus, Dicentrarchus, labrax, andAtherina boyeri were particularly abundant in spring and summer, andEngraulis encrasicholus, Liza aurata, Gambusia holbrooki, Palaemon longirostris, andPalaemon serratus were most abundant in autumn and winter.L. ramada occurred in the tidal creeks in high numbers during neap tides, while the majority of the remaining taxa were most abundant during spring tides, suggesting a differential pattern of habitat use occording to species.