Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.     

Dating megafaunal extinction on the Pleistocene Darling Downs,eastern Australia: the promise and pitfalls of dating as a test of extinction hypotheses

A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) ¹⁴C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS ¹⁴C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS ¹⁴C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (～40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ～120–83 ka, thus occurring beyond the AMS ¹⁴C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ～75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival.     

Remote estimation of terrestrial evapotranspiration by Landsat 5 TM and the SEBAL model in cold and high‐altitude regions: a case study of the upper reach of the Shule River Basin,China

Evapotranspiration (ET) is an important expenditure in water and energy balances, especially on cold and high‐altitude land surfaces. Daily ET of the upper reach of the Shule River Basin was estimated using Landsat 5 TM data and the Surface Energy Balance Algorithm for Land (SEBAL) model. Based on observations made at the Suli station, the algorithms of land surface temperature and soil heat flux in SEBAL were modified. Land surface temperature was retrieved and compared with ground truth via three methods: the radiative transfer equation method, the mono‐window algorithm, and the single‐channel method. We selected the best of these methods, mono‐window algorithm, for estimating ET. The average error of daily ET estimated by the modified SEBAL model and measured by the eddy covariance system was 16.4%, with a root‐mean‐square error of 0.52 mm d^?1. The estimated ET means were 3.09, 2.48, and 1.48 mm d^?1 on June 9 (DOY 160), June 25 (DOY 176), and July 27 (DOY 208) of the year 2010, respectively. The average estimated ET on the glacier surface of all days was more than 3 mm d^?1, a measurement that is difficult to capture in‐situ and has rarely been reported. This study will improve the understanding of water balance in cold, high‐altitude regions. Copyright © 2016 John Wiley & Sons, Ltd.     

Vertical variations and transport mechanism of soil moisture in response to vegetation restoration on the Loess Plateau of China

Soil moisture is essential for vegetation restoration in arid and semi-arid regions. Ascertaining the vertical distribution and transportation of soil moisture under different vegetation types has a profound effect on the ecological construction. In this study, the soil moisture at a depth of 500 cm for four typical vegetation types, including Robinia pseudoacacia, Caragana korshinskii, Stipa bungeana, and corn, were investigated and compared in the Zhifanggou watershed of the Loess plateau. Additionally, hydrogen and oxygen stable isotopes were detected to identify the transport mechanism of soil moisture. The results showed vertical distribution and transportation of soil moisture were different under different vegetation types. Depth-averaged soil moisture under S. bungeana and corn generally increased along the profile, while C. korshinskii and R. pseudoacacia showed weakly increasing and relatively stable after an obvious decreasing trend (0–40 cm). The soil moisture under R. pseudoacacia was lower than that under other vegetation types, especially in deep layer. However, the effect of R. pseudoacacia on soil moisture in the topsoil (< 30 cm) could be positive. For R. pseudoacacia (160–500 cm), C. korshinskii (0–500 cm), and S. bungeana (0–100 cm), the soil moisture declined with increased in vegetation age. Planting arbor species such as R. pseudoacacia intensified the decline of soil moisture on the Loess Plateau. The capacity of evaporation fractionation of soil moisture followed the sequence: corn > S. bungeana > R. pseudoacacia > C. korshinskii. The δ¹⁸O values in soil water fluctuated across the profile. The δ¹⁸O values changed sharply in upper layer and generally remained stable in deep layer. However, in middle layer, the vertical distribution characteristics of the δ¹⁸O values were different under different vegetation types. We estimated that piston flow was the main mode of precipitation infiltration, and the occurrence of preferential flow was related to vegetation types. These results were helpful to improve the understanding of the response of deep soil moisture to vegetation restoration and inform practices for sustainable water management.     

Diatom‐based reconstruction of summer sea‐surface salinity in the South China Sea over the last 15 000 years

We present a new reconstruction of summer sea‐surface salinity (SSS) over the past 15 000 years based on a diatom record from piston core 17940, located on the northern slope of the South China Sea (SCS). The reconstructed diatom‐based summer SSS values for the modern period are in accord with instrumental observations of summer SSS in the area. Here, the modern summer SSS is primarily controlled by river runoff, in particular from the Pearl River. The reconstruction presented in this study shows that the summer SSS varied between 33.3 and 34.2 psu over the past 15 000 years. The long‐term summer SSS trend closely followed the trend of the orbitally controlled solar insolation at 20°N, suggesting that orbital forcing was the dominant driver of changes in summer SSS in this area. Comparisons to speleothem δ¹⁸O data and studies of surface hydrography in the region suggest that changes in solar insolation affected the summer SSS through changes in the East Asian Monsoon and sea‐level changes associated with the last deglaciation. Univariate spectral analyses indicate that centennial‐scale oscillatory variations in summer SSS were superimposed on the long‐term trend. During the deglacial period (c. 12 000–9000 cal. a BP), the dominant periodicity was centred around 230–250 years, whereas a ～350‐year oscillation dominated in the period 2200–4500 cal. a BP. The balance of evidence suggests that these centennial‐scale changes in summer SSS may have been driven by solar‐induced changes in the East Asian Monsoon, but further evidence is needed to firmly establish this relationship.     

Exploring the interaction of surface roughness and slope gradient in controlling rates of soil loss from sloping farmland on the Loess Plateau of China

Surface roughness and slope gradient are two important factors influencing soil erosion. The objective of this study was to investigate the interaction of surface roughness and slope gradient in controlling soil loss from sloping farmland due to water erosion on the Loess Plateau, China. Following the surface features of sloping farmland in the plateau region, we manually prepared rough surfaces using four tillage practices (contour drilling, artificial digging, manual hoeing, and contour plowing), with a smooth surface as the control measure. Five slope gradients (3°, 5°, 10°, 15°, and 20°) and two rainfall intensities (60 and 90 mm/hr) were considered in the artificial rainfall simulation experiment. The results showed that the runoff volume and sediment yield increased with increasing slope gradient under the same tillage treatment. At gentle slope gradients (e.g., 3° and 5°), the increase in surface roughness prevented the runoff and sediment production, that is, the surface roughness reduced the positive effect of slope gradient on the runoff volume and sediment yield to a certain extent. At steep slope gradients, however, the enhancing effect of slope gradient on soil erosion gradually increased and surpassed the reduction effect of surface roughness. This study reveals the existence of a critical slope gradient that influences the interaction of surface roughness and slope gradient in controlling soil erosion on sloping farmland. If the slope gradient is equal to or less than the critical value, an increase in surface roughness would decrease soil erosion. Otherwise, the increase in surface roughness would be ineffective for preventing soil erosion. The critical slope gradient would be smaller under higher rainfall intensity. These findings are helpful for us to understand the process of soil erosion and relevant for supporting soil and water conservation in the Loess Plateau region of China.     

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.     

Lateral extrusion along the Altyn Tagh Fault,Qilian Shan (NE Tibet): insight from a 3D crustal budget

The lithospheric strike‐slip Altyn Tagh Fault has accommodated hundreds of kilometres of displacement between the Qaidam and Tarim blocks since its Eocene reactivation. However, the way the deformation is accommodated in the Qilian Shan and further east remains uncertain. Based on 360 km of north‐eastward migration of the relatively rigid Qaidam block along the Altyn Tagh Fault and 3D isovolumetric balancing of the crustal deformation within the Altyn Tagh Fault–Qilian Shan system, we demonstrate that 250 ± 28 km (43.8–49.4%) of N20E directed crustal shortening and an additional ~250–370 km of eastward motion of the Qilian Shan crust must be accounted for by strike‐slip faulting in the Qilian Shan and crustal thickening in the Qinling area, as well as by extension in the adjoining North China block graben systems.