Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

鄂尔多斯盆地南部的黄土塬区地震资料处理与解释,第一部分:地震资料处理

Branching river channels and the coexistence of valleys, ridges, hiils, and slopes＇as the result of long-term weathering and erosion form the unique loess topography. The Changqing Geophysical Company, working in these complex conditions, has established a suite of technologies for high-fidelity processing and fine interpretation of seismic data. This article introduces the processes involved in the data processing and interpretation and illustrates the results.     

Converted-wave seismology in anisotropic media revisited,Part I: Basic theory

We have developed new basic theories for calculating the conversion point and the travel time of the P-SV converted wave (C-wave) in anisotropic, inhomogeneous media. This enables the use of conventional procedures such as semblance analysis, Dix-type model building and Kirchhoff summation, to implement anisotropic processing, and makes anisotropic processing affordable. Here we present these new developments in two parts: basic theory and application to velocity analysis and parameter estimation. This part deals with the basic theory, including both conversion-point calculation and moveout analysis. Existing equations for calculating the PS-wave (C-wave) conversion point in layered media with vertical transverse isotropy (VTI) are strictly limited to offsets about half the reflector depth (an offset-depth ratio, xlz, of 0.5), and those for calculating the C-wave traveltimes are limited to offsets equal to the reflector depth (x/z=l.0). In contrast, the new equations for calculating the conversion-point extend into offsets about three-times the reflector depth (x/z=3.0), those for calculating the C-wave traveltimes extend into offsets twice the reflector depth (x/z=2.0). With the improved accuracy, the equations can help in C-wave data processing and parameter estimation in anisotropic, inhomogeneous media. This work is funded by the Edinburgh Anisotropy Project (EAP) of the British Geological Survey. First author: Xiangyang Li, Mr. Li is currently a professorial research seismologist (Grade 6) and technical director of the Edinburgh Anisotropy Project in the British Geological Survey. He also holds a honorary professorship in multicomponent seismology at the School of Geosciences, University of Edinburgh. He received his BSc(1982) in Geophysics from Changchun Geological Institute, China, an MSc (1984) in applied geophysics from East China Petroleum Institute (now known as the China University of Petroleum), and a PhD (1992) in seismology from the University of Edinburgh. During 1984–1987, he worked as a lecturer with the East China Petroleum Institute. Since 1991, he has been employed by the British Geological Survey. His research interests include seismic anisotropy and multicomponent seismology.     

Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.     

Observed Evolution of Linear and Nonlinear Effects at the Dahan Downhole Array,Taiwan: Analysis of the September 21, 1999 M 7.3 Chi-Chi Earthquake Sequence

— In this paper, the site characteristics of the Dahan downhole array are studied by analyzing the September 21, 1999 M 7.3 Chi-Chi earthquake sequence including the main shock and some aftershocks. The four-level array (0 m, 50 m, 100 m and 200 m) is located to the north of Hualien City in eastern Taiwan. Polarization analysis is used to check the orientation errors of the seismometers at different levels of depth. If the surface instrument is chosen as reference, the angle between the major polarization axes of the surface and any downhole records is the orientation error that must be corrected for the downhole accelerographs. The orientation errors at depths of 50 m, 100 m and 200 m are 32°, 120° and –84°. After the corrections, the coherency between the surface and downhole records is substantially improved. Spectral ratio analysis shows that the predominant frequency of the Chi-Chi main shock shifts to a lower frequency. We also simulate ground motions at different depths by using the Haskell method with a linear velocity structure model. The record at surface is chosen as the input motion. Compared with the observed data, ground acceleration can be well reproduced for the aftershocks (weak-motion events) of the September 21, 1999 M 7.3 Chi-Chi earthquake. However, for the Chi-Chi main shock, the synthetic waveform cannot match well with the observation neither in amplitude nor in phase. This indicates that large ground shaking probably induced the nonlinear site effect at that time, and the model used cannot support it.Acknowledgement. The authors would like to express their thanks to Dr. L.F. Bonilla and one anonymous reviewer for their valuable suggestions. This research was supported by the National Science Council under grant number NSC 89-2921-M-194-007. The Institute of Earth Sciences, Academia Sinica supplied the strong-motion data. The support of these organizations is gratefully acknowledged.     

Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China

An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.     

Scattering of plane SV waves by cylindrical canyons in saturated porous medium

On the basis of Biot dynamic theory, an analytic solution of two-dimensional scattering and diffraction of plane SV waves by circular cylindrical canyons in a half space of saturated porous media is presented in this paper for the first time. The solution is obtained by employing the Fourier–Bessel series expansion technique. Parametric studies had been carried out, which includes: the angle of incidence, the frequency of the incident SV wave, the porosity of saturated porous medium and the stiffness and Poisson's ratio of the solid-skeleton. All the outcomes are useful for the seismic analysis of the surface topography conditions.     

Study on the Source Parameters of Earthquakes in the Middle Eastern Area of North Tianshan in Xinjiang

INTRODUCTIONThe study of source parameters is usually based oninversionfromobservational seismic waveformdata.Seismic wave affected bygeometric spreading,inelastic attenuation,scatteringandsite effects ofthe mediumontheir way fromsource to station.Therefo…     

福建沿海土壤地球化学分类及基准值研究

利用多目标区域地球化学调查成果,探讨了福建沿海土壤地球化学分类的方法,提出了分类命名方案和诊断标准,将研究区土壤按SiO₂含量划分为铁铝土、硅铝土、铝硅土、硅土4个大类,其中硅铝土又分为一般硅铝土、铁质硅铝土、钾质硅铝土、硫铁质硅铝土4个亚类,铝硅土分为一般铝硅土和钾质铝硅土2个亚类;提出了在各种统计量中,中值比较客观地反映元素含量背景,适合作为基准值;给出了研究区各类土壤的分布图和52种元素及pH的基准值,分析了其成因和农业利用情况。     

当前国际水文学科技术领域的研究方向

根据联合国有关机构发布的公报和世界各国近年来的学术研究情况，整理出了近期水文学科在地表水、地下水、水质、水资源系统、大气～土壤～植被、大陆侵蚀、冰雪、遥感技术和示踪技术等领域的热门研究课题，在一定程度上反映了当前国际上水文学科的研究和发展方向，对国内同行有一定的参考价值。