Evaluation of bioremediation strategies of a controlled oil release in a wetland

A controlled petroleum release was conducted to evaluate bioremediation in a wetland near Houston, Texas. The 140-day study was conducted using a randomized, complete block design to test three treatments with six replicates per treatment. The three treatment strategies were inorganic nutrients, inorganic nutrients with an alternative electron acceptor, and a no-action oiled control. Samples were analyzed for petroleum chemistry and inorganic nutrients. These results are discussed in the context of our related research involving toxicology and microbiology at the site during the experiment. To evaluate biodegradation, the targeted compounds were normalized to the conservative compound C3017alpha, 21beta-[H]hopane, thus reducing the effects of spatial heterogeneity and physical transport. The two biostimulation treatments demonstrated statistically-higher rates of biodegradation than the oiled no-action control. For the majority of the experiment, target nutrient levels were maintained. Further research may be warranted to optimize these bioremediation strategies as well as evaluating additional treatment strategies for wetlands and other shoreline systems.     

The loss of the chemical tanker Ievoli Sun in the English Channel,October 2000

A chemical product tanker, The Ievoli Sun, was abandoned and later sank approximately 11 miles NW of Alderney in the English Channel in October 2000. The vessel carried a mixed cargo comprising 4000 tonnes of styrene, and 1000 tonnes each of methyl ethyl ketone and isopropyl alcohol. These chemicals are of low to moderate toxicity to aquatic life, are not persistent and have a low potential for bio-accumulation. Both of the solvents are miscible in water, whilst styrene is practically insoluble and, following release, it will rise to the sea surface and rapidly evaporate. More than 1000 tonnes of styrene are believed to have been lost to sea during the incident, resulting in an aerial plume of vapour which crossed Alderney and episodic contamination of air and water in the immediate vicinity of the wreck site. Analysis of edible tissues using coupled gas chromatography/mass spectrometry demonstrated low-level styrene contamination of crabs recovered from pots laid very close to the wreck site prior to the incident. These concentrations posed no risks to human consumers, and no fishery controls were implemented. The remainder of the styrene and the ship's main bunker fuel were recovered from the wreck on the seabed, whilst the two chemical solvents were released to the water column in a slow, controlled manner.     

The role of population change in widening the mortality gap in Scotland

The social gradient in health and mortality has been acknowledged for some time and, more recently, there is some evidence that the gap between the richer and poorer is widening in Britain. Other studies have also shown that health and mortality outcomes are worse in places that are experiencing population decline and better in places that are growing. This analysis examines, first, whether there is a mortality gap between the least and most deprived people in Scotland, second, whether this gap has widened since the 1980s and, third, whether the gap can be explained by patterns of population change. Our results demonstrate that the widening mortality gap in Scotland cannot be explained simply as an artefact of population change, even though it is widening most in those places that are experiencing population decline. This type of research is made possible by the reliable denominator population information provided in the 1981 and 2001 censuses.     

'On the rocks': New Zealand's coastal bach landscape and the case of Rangitoto Island

Abstract:  A distinctive feature of many of New Zealand's coastal landscapes has been the rudimentarily constructed holiday home known as a 'bach'. In recent years, however, rapidly escalating beachfront property prices, and the associated development of elite residential landscapes, have threatened the status of the bach. This commentary examines the diminishing number of 'classic' kiwi baches, and specifically considers the case of Rangitoto, a volcanic island close to central Auckland. Here, the location of baches on publicly owned land has been controversial and the small number that remains symbolize curiosities from another time and place.     

Late Holocene eruptive activity at Nevado Cayambe Volcano, Ecuador

 Four Late Holocene pyroclastic units composed of block and ash flows, surges, ashfalls of silicic andesite and dacite composition, and associated lahar deposits represent the recent products emitted by domes on the upper part of Nevado Cayambe, a large ice-capped volcano 60 km northeast of Quito. These units are correlated stratigraphically with fallout deposits (ash and lapilli) exposed in a peat bog. Based on ¹⁴C dating of the peat and charcoal, the following ages were obtained: ∼910 years BP for the oldest unit, 680–650 years BP for the second, and 400–360 years BP for the two youngest units. Moreover, the detailed tephrochronology observed in the peat bog and in other sections implies at least 21 volcanic events during the last 4000 years, comprising three principal eruptive phases of activity that are ∼300, 800, and 900 years in duration and separated by repose intervals of 600–1000 years. The last phase, to which the four pyroclastic units belong, has probably not ended, as suggested by an eruption in 1785–1786. Thus, Cayambe, previously thought to have been dormant for a long time, should be considered active and potentially dangerous to the nearby population of the Interandean Valley. Received: 5 July 1997 / Accepted: 21 October 1997     

Potential radionuclide transport pathways from seafloor dumpsites: Kamchatka region of the North Pacific Ocean

Encapsulated nuclear waste materials, dumped by Russia, are present at two deepwater seafloor locations in the offshore north-west Pacific Ocean, south-east of the Kamchatka Peninsula. This paper assesses potential pathways by which these wastes might, if released from their containers, disperse away from the dumpsites and through the surrounding ocean. A review of large-scale ocean circulation theory and of field and model results suggests that mean abyssal currents are north-eastward to eastward from the dumpsite locations and would advect leaking materials toward the north-eastern Pacific. Results of advective and diffusive horizontal plume transport models are consistent with this sense of flow. Trajectory speeds are, however, subject to considerable uncertainty. Our results suggest that as little as 5 years or as long as 100 years might be required for material to be transported from the dump sites to the north-east Pacific. Dilution by 4 or 5 orders of magnitude is predicted during this transit. Vertical mixing or upwelling are necessary in order to transport contaminants upward from north-east Pacific abyssal waters to the near-surface layers before they can potentially impact productive coastal regions, such as those off Alaska. Information concerning such upwelling mechanisms is inadequate for estimation of rates or to identify geographical areas that might be at risk.     

Central Arctic Ocean response to Pleistocene Earth-orbital variations

Three central Arctic Ocean sediment cores were sampled for percentage carbonate, number of foraminifera, and texture. These three parameters were used in spectral analyses to test the idea that the ice-covered Arctic Ocean may respond to orbital forcing in a different manner than has been indicated for lower latitude ice-free oceans. The record for two of the cores represents approximately 1 my, and the record for the third, approximately 400,000 yr. The 100,000-yr frequency is well represented in all of the cores. A 40,000-yr frequency may be present, as well. An unexpected 70,000-yr frequency occurs in most of the spectra and may reflect nonlinear sedimentation rates or the combined effect of obliquity and eccentricity. The strong 100,000-yr signal confirms that, in spite of ice feedback, the Arctic Ocean has responded to orbital forcing in much the same manner as have ice-free oceans.     

Characterization of kerogens and study of their evolution by infrared spectroscopy: carbonyl and carboxyl groups

Measurements of the absorption coefficient of the band around 1710cm^?1, combined with adequate chemical treatments, allow an evaluation of the importance of carbonyl, carboxylic acid and ester groups in various series of kerogens. The concentration of carbonyl and acid groups, the concentration of oxygenated functions other than carbonyl or carboxyl, and the total oxygen content are higher in shallow kerogens originating from higher plants than in those containing an important algal contribution; however the concentration of ester groups varies in the opposite direction.The carboxylic acid groups are the most sensitive to catagenetic evolution or pyrolysis. The carbonyl groups are removed progressively as evolution proceeds but a fraction of them is retained up to advanced degrees of evolution.Study of the band at 1630cm^?1 has shown that, besides the bending vibration of molecular water, there is some contribution of bridged quinones and unsaturated hydrocarbons. However at least 50% of the absorption coefficient is due to polyaromatic structures. This band is generally much more intense for kerogens originating from higher plants.