Evolution of the Taupo-Hikurangi subduction system

The present day Taupo-Hikurangi subduction system is a southward extension of the Tonga-Kermadec Arc system into a sediment-rich continental margin environment. It consists of a shallow structural trench (the Hikurangi Trough), a 150 km wide, imbricate thrust controlled accretionary borderland (the continental slope, shelf, and coastal hills of eastern North Island), a frontal ridge (the main “greywacke” ranges of North Island), and a volcanic arc and marginal basin (the Taupo Volcanic Zone).Structural elements become progressively more elevated and subduction more oblique towards the south. The whole NNE-trending system is truncated at a largely strike-slip, transform boundary that extends along the southwestern part of the Hikurangi Trough and the Hope fault of South Island to the main Alpine Fault.The volcanic arc is 200–270 km from the structural trench and comprises a NNE trending chain of andesite-dacite volcanoes extending along the eastern side of the Taupo Volcanic Zone. Most of the andesites are olivine-bearing and have been erupted within the last 50,000 years.It is suggested the Taupo-Hikurangi margin has evolved by rotation of accretionary elements, from an original NW-trending subduction system north of New Zealand. The older elements of the prism were associated with subduction of a re-entrant of the Pacific Plate (and perhaps the South Fiji Basin) in Mid Tertiary times. They subsequently became separated from their NW-trending volcanic arc by dextral strike-slip movement along curved faults east of the main “greywacke” ranges. During the Plio-Pleistocene, oblique subduction and accretion intensified as the Taupo-Hikurangi margin rotated into line with the NNE-trending Kermadec system and a marginal basin was developed along a similar trend to form the Taupo Volcanic Zone. Within the last 50,000 years olivine-bearing andesite volcanism has commenced along the eastern side of the Taupo Volcanic Zone.     

Rare gases in separated whitlockite from the St. Severin chondrite: xenon and krypton from fission of extinct 244Pu

Helium, neon, argon, krypton and xenon data are presented from stepwise heating of samples of the mineral whitlockite from the chondritic meteorite St. Severin. The xenon is shown to be a uniform mixture derived from ²⁴⁴Pu fission and rare-earth element spallation. The krypton similarly contains spallation products and ⁸⁶Kr from ²⁴⁴Pu fission. Plutonium-244 fission yields of ⁸⁶Kr/¹²⁹Xe/¹³¹Xe/¹³²Xe/¹³⁴Xe/¹³⁶Xe = 1.9 ± 0.5/4.8 ± 5.5/24.6 ± 2.0/88.5 ±3.0/93.9 ± 0.8/  100 are obtained. The helium, neon and argon are dominated by spallation and radiogenic ⁴He and ⁴⁰Ar. A pile neutron irradiation experiment does not yield a unique Pu/U ratio for this mineral but yields ratios varying from 0.045 down to 0.017. Both the high concentration of ²⁴⁴Pu fission xenon and the high ratio of Pu/U previously reported by Wasserburget al. (J. Oeophys. Res. 74, 4221–4232, 1969) are thus confirmed.     

Mineralogy of the ejected plutonic blocks of the soufriere volcano St. Vincent: Olivine,pyroxene, amphibole and magnetite paragenesis

Ejected plutonic blocks from the Soufrière volcano, St. Vincent, consist of the mineral phases plagioclase (An₉₆?An₈₉, average An₉₃), olivine (Fo₇₉?Fo₆₇, most frequent interval Fo₇₄?₇₂), salite containing 5–6 percent Al₂O₃, hastingsitic amphibole and magnetite containing 6% Al₂O₃, 4% MgO and 7% TiO₂. Aluminous salitic pyroxenes are not confined to alkaline suites but also occur as high temperature phases in certain calc-alkaline suites. Similarly low silica amphiboles with comparatively high Fe⁺³+Ti contents are unusual in common sub-alkaline rocks. Magnetite in the St. Vincent blocks is an example of a single homogeneous iron oxide phase precipitated in equilibrium with the other four phases in the blocks. Conditions of crystallisation are just as important as silica activity in determining the compositions of phases separating from basaltic magmas at relatively shallow depths (P _tot< 8 kb). It is argued mainly on crystal chemical grounds that the mineral assemblage in the St. Vincent blocks can crystalline from a sub-alkaline magma under conditions of relatively high temperature, high water vapor pressure, and oxygen fugacity.     

Background concentrations of photochemically active trace constituents in the stratosphere and upper troposphere

Summary High resolution absorption spectroscopy can be used for obtaining very small background concentrations or very low upper limits of trace constituents, particularly from measurements inQ-branches of fundamental vibration-rotation bands. As examples, the results of a search for NH₃ and SO₂ in the Vermande and Dionne Mont-Louis solar spectra will be reported. The relative concentration of NH₃ is very much lower above the Pyrenees than the generally accepted minimum background concentrations near sea-level.     

Metal/silicate fractionation in the solar system

Fractionation between the metal and silicate components of objects in the inner solar system has long been recognized as a necessity in order to explain the observed density variations of the terrestrial planets and the H-group, L-group dichotomy of the ordinary chondrites. This paper discusses the densities of the terrestrial planets in light of current physical and chemical models of processes in the solar nebula. It is shown that the observed density trends in the inner solar system need not be the result of special fractionation processes, and that the densities of the planets may be direct results of simultaneous application of both physical and chemical restraints on the structure of the nebula, most notably the variation of temperature with heliocentric distance. The density of Mercury is easily attributed to accretion at temperatures so high that MgSiO₃ is only partially retained but Fe metal is condensed. The densities of the other terrestrial planets are shown to be due to different degrees of retention of S, O and H as FeS, FeO and hydrous silicates produced in chemical equilibrium between condensates and solar-composition gases. It is proposed that Mercury and Venus Have cores of Fe⁰, Earth has a core of Fe⁰ containing substantial amounts of FeS, and Mars has a quite small core of FeS with more FeO in its mantle than in Earth's. Geophysical and geochemical consequences of these conclusions are discussed.     

Volatile element chemistry in the solar nebula: Na,K, F,Cl, Br,and P

The results of the most extensive set to date of thermodynamic calculations of the equilibrium chemistry of several hundred compounds of the elements Na, K, F, Cl, Br, and P in a solar composition system are reported. The calculations are carried out over a wide range of temperatures and pressures and along an adiabat in the primitive solar nebula. Two extreme models of accretion are investigated. In one extreme complete chemical equilibrium between condensates and gases is maintained because the time scale for accretion is long compared to the time scale for cooling or dissipation of the nebula. Condensates formed in this homogeneous accretion model include several phases such as whitlockite, alkali feldspars, and apatite minerals which are found in chondrites. In the other extreme complete isolation of newly formed condensates from prior condensates and gases occurs due to a time scale for accretion that is short relative to the time required for nebular cooling or dissipation. The condensates produced in this heterogeneous accretion model include alkali sulfides, ammonium halides, and ammonium phosphates. None of these phases are found in chondrites. Available observations of the Na, K, F, Cl, Br, and P elemental abundances in the terrestrial planets are found to be compatible with the predictions of the homogeneous accretion model.     

Comparison of Measured Ozone Production Efficiencies in the Marine Boundary Layer at Two European Coastal Sites under Different Pollution Regimes

Ozone production efficiencies (E_N), which can be defined as the netnumber of ozone molecules produced per molecule of NO_xoxidised, have been calculated from measurements taken during three intensive field campaigns (one in the spring, EASE 96, and two in the summer, EASE 97 and TIGER 95), at two European coastal sites (Mace Head, Ireland (EASE) and Weybourne, Norfolk (TIGER)) impacted by polluted air masses originating from both the U.K. and continental Europe, as well as relatively clean oceanic air masses from the Arctic and Atlantic. From a detailed wind sector analysis of the EASE 96 and 97 data it is clear that two general types of pollution regime were encountered at Mace Head. The calculated ozone production efficiency in clean oceanic air masses was approximately 65, which contrasted to more polluted air, from the U.K. and the continental European plume, where the efficiency decreased to between 4 and 6. The latter values of E_Nagree well with literature measurements conducted downwind of various urban centres in the U.S. and Europe, which are summarised in a wide-ranging review table. The E_N value calculated for clean oceanic air is effectivelyan upper limit, owing to the relatively rapid deposition of HNO₃ tothe ocean. Consideration of the variation of E_N with NO_x forthe three campaigns suggests that ozone production efficiency is relatively insensitive to both geographical location and season. The measuredE_N values are also compared with values derived from steady-state expressions. An observed anti-correlation between E_N and measured ozone tendencyis briefly discussed.     

Embedding the reforms in New Zealand schooling: After neo-liberalism?

Two decades of reforms to the state in New Zealand have altered policy, its making and the ways in which it is realised in micro settings. This paper uses the example of schooling to examine the rationality of these reforms, their spatial logic and what they mean for our understanding of the national state. It examines the development and practices of the Education Review Office (ERO), the body established under the reforms to evaluate and audit the performance of schools in the new national education `system'. The paper interprets neo-liberalism as a governmentality, and argues that the development of new managerial technologies of remote control such as contract and audit constitute a spatial model of control. The paper suggests that this model encourages, and relies for its efficacy upon, the cultivation of neo-liberal subjectivities. It argues that although the political projects working through the reforms have shifted, the altered rationality of the state and the models of control erected to secure it define an enduring and neo-liberalising social transformation. The shift to the `Third Way' in New Zealand's political and social economy is underpinned by neo-liberalising processes, which continue to reorganise social and economic spaces. This revised version was published online in July 2006 with corrections to the Cover Date.