Stratigraphy and sedimentology of Devensian (Dimlington Stadial) glacial deposits,east Yorkshire,England

The stratigraphy and sedimentology of the glacial deposits exposed along the coast of east Yorkshire are reviewed. Critical sections at Filey Brigg, Barmston and Skipsea are examined to reassess the stratigraphy of Devensian Dimlington Stadial glacial deposits in the light of recent developments in glacial sedimentology. Sedimentary and glaciotectonic structures studied in the field and by using scanning electron microscopy are emphasised. Two hypotheses are considered for the genesis of the interbedded diamictons and stratified sediments. The first involves the deposition of lodgement till and/or deformation till followed by meltout till, which was overridden to produce more deformation till, reflecting periods of ice stagnation punctuated by glacier thickening. The second hypothesis, which is favoured on the basis of field evidence and micromorphology, involves the vertical accretion of a deforming till layer associated with cavity/channel or tunnel valley fills, beneath active ice. At Barmston the upper part of the diamicton contains elongate pendant structures containing gravels, indicating that the diamicton was saturated and able to flow. The diamictons, therefore, represent a complex sequence of tills deposited and deformed by active ice during the Dimlington Stadial. Previously published stratigraphical schemes involving classifications of multiple tills in east Yorkshire should be simplified and it is more appropriate to assign these to a single formation, the Skipsea Till Formation. Rhythmic glaciolacustrine and proglacial glaciofluvial sediments overlie the tills at Barmston and Skipsea. These were deposited in sag basins during deglaciation as the tills settled and deformed under thickening sediment and as buried ice melted out. Extensive sands and gravels cap the succession and were deposited on a sandur during the later stages of deglaciation.     

Maralinga,a metamorphosed carbonaceous chondrite found in Australia

Abstract— The Maralinga meteorite was found near the village of Maralinga, South Australia (30°18′S, 131°16′E) in 1974, but was not recognized as a meteorite until 1989. One weathered individual was recovered with a total mass of 3.38 kg. The bulk composition and petrography of Maralinga indicate that it is a metamorphosed (petrographic type 4) carbonaceous chondrite with major similarities to the Vigarano-subtype. However, recent trace element data from the literature suggest that Maralinga should be included with the CK (Karoonda-type) carbonaceous chondrites. We classify Maralinga as an anomalous CK4 chondrite because of its abundant chondrules and refractory inclusions relative to other known members of the CK group. Maralinga contains homogeneous silicates, including Ni-bearing olivines (Fa₃₄), high-Ca clinopyroxene, and rare orthopyroxene. Plagioclase is chemically heterogeneous and falls into two distinct compositional groups one of ～ An₂₀ and an ～ An₈₀ group. Highly oxidizing conditions during metamorphism of Maralinga are indicated by the abundance of magnetite and the paucity of Fe-Ni metal.     

A regional coupled approach to water cycle prediction during winter 2013/14 in the United Kingdom

A regional coupled approach to water cycle prediction is demonstrated for the 4-month period from November 2013 to February 2014. This provides the first multi-component analysis of precipitation, soil moisture, river flow and coastal ocean simulations produced by an atmosphere-land-ocean coupled system focussed on the United Kingdom (UK), running with horizontal grid spacing of around 1.5 km across all components. The Unified Model atmosphere component, in which convection is explicitly simulated, reproduces the observed UK rainfall accumulation (r² of 0.95 for water day accumulation), but there is a notable bias in its spatial distribution—too dry over western upland areas and too wet further east. The JULES land surface model soil moisture state is shown to be in broad agreement with a limited number of cosmic-ray neutron probe observations. A comparison of observed and simulated river flow shows the coupled system is useful for predicting broad scale features, such as distinguishing high and low flow regions and times during the period of interest but are less accurate than optimized hydrological models. The impact of simulated river discharge on NEMO model simulations of coastal ocean state is explored in the coupled modelling framework, with comparisons provided relative to experiments using climatological river input and no river input around the UK coasts. Results show that the freshwater flux around the UK contributes of order 0.2 psu to the mean surface salinity, and comparisons to profile observations give evidence of an improved vertical structure when applying simulated flows. This study represents the first assessment of the coupled system performance from a hydrological perspective, with priorities for future model developments and challenges for evaluation of such systems discussed.     

Antifouling strategies: history and regulation, ecological impacts and mitigation

Biofouling increases drag on marine vessels resulting in higher fuel consumption and can also facilitate the transport of harmful non-indigenous species (NIS). Antifouling technologies incorporating biocides (e.g., copper and tributyltin) have been developed to prevent settlement of organisms on vessels, but their widespread use has introduced high levels of contamination into the environment and raised concerns about their toxic effects on marine communities. The recent global ban on tributyltin (1 January 2008) and increasing regulation of copper have prompted research and development of non-toxic paints. This review synthesises existing information regarding the ecological impact of biocides in a wide range of organisms and highlights directions for the management of antifouling paints. We focus particularly on representatives of the recent past (copper and tributyltin) and present (copper and ‘booster’) biocides. We identify knowledge gaps in antifouling research and provide recommendations relating to the regulation and phasing-out of copper.     

NN detectability in Pluto’s atmosphere

Based on the vapor pressure behavior of Pluto’s surface ices, Pluto’s atmosphere is expected to be predominantly composed of N₂ gas. Measurement of the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere would provide important clues to the evolution of Pluto’s atmosphere from the time of formation to its present state. The most straightforward way of determining the N₂ isotopologue ¹⁵N/¹⁴N ratio in Pluto’s atmosphere is via spectroscopic observation of the ¹⁴N¹⁵N gas species. Recent calculations of the 80–100 nm absorption behavior of the ¹⁴N₂ and ¹⁴N¹⁵N isotopologues by Heays et al. (Heays, A.N. et al. [2011]. J. Chem. Phys. 135, 244301), Lewis et al. (Lewis, B.R., Heays, A.N., Gibson, S.T., Lefebvre-Brion, H., Lefebvre, R. [2008]. J. Chem. Phys. 129, 164306); Lewis et al. (Lewis, B.R., Gibson, S.T., Zhang, W., Lefebvre-Brion, H., Robbe, J.-M. [2005]. J. Chem. Phys. 122, 144302), and Haverd et al. (Haverd, V.E., Lewis, B.R., Gibson, S.T., Stark, G. [2005]. J. Chem. Phys. 123, 214304) show that the peak magnitudes of the ¹⁴N₂ and ¹⁴N¹⁵N absorption bandhead cross-sections are similar, but the locations of the bandhead peaks are offset in wavelength by ∼0.05–0.1 nm. These offsets make the segregation of the ¹⁴N₂ and ¹⁴N¹⁵N absorption signatures possible. We use the most recent N₂ isotopologue absorption cross-section calculations and the atmospheric density profiles resulting from photochemical models developed by Krasnopolsky and Cruickshank (Krasnopolsky, V.A., Cruickshank, D.P. [1999]. J. Geophys. Res. 104, 21979–21996) to predict the level of solar light that will be transmitted through Pluto’s atmosphere as a function of altitude during a Pluto solar occultation. We characterize the detectability of the isotopic absorption signature per altitude assuming ¹⁴N¹⁵N concentrations ranging from 0.1% to 2% of the ¹⁴N₂ density and instrumental spectral resolutions ranging from 0.01 to 0.3 nm. Our simulations indicate that optical depth of unity is attained in the key ¹⁴N¹⁵N absorption bands located between 85 and 90 nm at altitudes ∼1100–1600 km above Pluto’s surface. Additionally, an ¹⁴N¹⁵N isotope absorption depth ∼4–15% is predicted for observations obtained at these altitudes at a spectral resolution of ∼0.2–0.3 nm, if the N₂ isotopologue ¹⁵N/¹⁴N percent ratio is comparable to the 0.37–0.6% ratio observed at Earth, Titan and Mars. If we presume that the predicted absorption depth must be at least 25% greater than the expected observational uncertainty, then it follows that a statistically significant detection of these signatures and constraint of the N₂ isotopologue ¹⁴N/¹⁵N ratio within Pluto’s atmosphere will be possible if the attainable observational signal-to noise (S/N) ratio is ?9. The New Horizons (NH) Mission will be able to obtain high S/N, 0.27–0.35 nm full-width half-max 80–100 nm spectral observations of Pluto using the Alice spectrograph. Based on the NH/Alice specifications we have simulated 0.3 nm spectral resolution solar occultation spectra for the 1100–1600 km altitude range, assuming 30 s integration times. These simulations indicate that NH/Alice will obtain spectral observations within this altitude range with a S/N ratio ∼25–50, and should be able to reliably detect the ¹⁴N¹⁵N gas absorption signature between 85 and 90 nm if the ¹⁴N¹⁵N concentration is ∼0.3% or greater. This, additionally, implies that the non-detection of the ¹⁴N¹⁵N species in the 1100–1600 km range by NH/Alice may be used to reliably establish an upper limit to the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere. Similar results may be derived from 0.2 to 0.3 nm spectral resolution observations of any other N₂-rich Solar System or exoplanet atmosphere, provided the observations are attained with similar S/N levels.     

Climate science in climate security scenarios

The climate is changing and this will have consequences across the globe, affecting all areas of the natural and human environment in complex ways. One tool for exploring the complex relationship between climate change and security is to use a scenariobased approach as means to develop plausible rather than probable narratives. This approach can explore the range of uncertainty, and help policymakers to visualise the potential consequences of climate change. Scenario methodology has been most comprehensively developed for use in business planning and there are some differences in the way scenarios work for climate security. The most notable is the fact that there is a physical modelling basis for climate projections. This means that the uncertainty range associated with at least this one aspect of the scenario can be systematically sampled. This paper reviews how scenarios have been used in the climate security literature to date, in particular in the grey literature. The integration of climate projections is explored in detail, as the main distinguishing feature of climate security scenarios over other scenario types. Few climate security scenarios have been developed to date, but all those included in this review, regardless of the differences in national conditions, regional climate change and potential responses, came to very similar conclusions. This was despite differences in the changes in climate and non-climate drivers, or differences in the scenario approach and audience. A more systematic and scientific approach to developing the scenario drivers and narratives is recommended, and successfully embedding changes in climate within the socio-economic context, through better integration of inter-disciplinary expertise, is critical.