On an instability mechanism in a stably stratified atmospheric layer over a moistened surface

In air stratified by a specific humidity gradient, the vertical motions result in variations in specific humidity (mixing ratio) near the underlying surface. This, in turn, causes a variation of evaporation from the surface, resulting in horizontal thermal inhomogeneities on the surface, which under certain conditions can strengthen the initial vertical motions. The linear problem of the stability of the system under consideration is solved in this paper, boundaries of the unstable region are defined, and specific values of growth rates of disturbances are investigated. The estimates show that even in a density-stratified atmospheric layer over a moist surface, rapid development of disturbances with horizontal scales of several hundred metres is possible. The horizontal sizes of the most rapidly growing modes, as a rule, are an order of magnitude larger than the vertical sizes. The possibility of observing this instability under natural conditions is discussed.     

Multi-Element Reference Samples of Black Shale

This paper describes the creation of two new reference samples of black shale, SCHS-1 and SLg-1, collected in the Bodaibo Region of Irkutsk District (Siberia, Russia). These samples have been developed as State Standard Samples to meet the requirements of Russia's Normative Documents, so that they can be recognised by the Russian State Certification Agency and included on the State Register of certified reference materials. SCHS-1 was produced from shale of the Khomolkho suite; SLg-1 represents the average composition of the Sukhoy Log gold deposit (within Au mineralisation). The homogeneity was assessed by applying the concept of potential inhomogeneity, and the inhomogeneity uncertainties (σ_inhom) for the indicator elements that were estimated experimentally by silicate XRF analysis. It was found that a majority of the indicator elements was characterised by σ_inhom/Δ_p < 1/8 (Δ_p is the permissible certification uncertainty), and so σ_inhom was neglected for the indicator elements and all other elements that were included in their respective group. The value of σ_inhom calculated for Fe (σ_inhom,Fe/Δ_p > 1 /8) was taken into consideration for the noble metals and their associated elements (e.g., Ag, As, Au, etc.). More than fifty laboratories (thirty-seven from Russia) were involved in the interlaboratory experiment (ILE) to analyse these reference samples. The data obtained from the ILE allowed SCHS-1 and SLg-1 to be certified for, fifty-one and forty-three elements, respectively, as State Standard Samples.     

Joint inversion of P- and S-receiver functions and dispersion curves of Rayleigh waves: The results for the Central Anatolian Plateau

The P- and S-wave receiver functions and dispersion curves of the fundamental Rayleigh wave are used to study the lithosphere within the Central Anatolian Plateau. The results for eight broadband seismic stations are presented. It is established that within the plateau, the crust with a thickness of about 35 km is underlain by the mantle lid with its bottom at a depth of about 60 km. The velocities of longitudinal (Vp) and shear (Vs) waves in this layer are at most 7.6 and 4.5 km/s, respectively, and the Vp/Vs ratio is close to 1.7 (i.e., by 6% lower than in the standard IASP91 and PREM models). Such a low velocity ratio is characteristic of rocks having high orthopyroxene content. Beneath the high-velocity mantle lid, the S-wave velocity decreases to 4.0–4.2 km/s and the Vp/Vs ratio is close to its standard value (1.8). At most stations, the P-wave receiver functions do not contain seismic phase P410s, which is formed at the global seismic boundary at a depth of 410 km. The seismic boundary at a depth of 410 km is related to the olivine-spinel phase transformation, and its absence can indicate the anomalously low olivine content and high basalt content. This anomaly is probably associated with the subduction of a large amount of oceanic crust during the closure of the Tethys. The results of the study overall indicate the high informativity of the used method.     

Anisotropy of the mantle inferred from observations of P to S converted waves

Summary. Seismic anisotropy has been previously studied at depths usually not exceeding 100 or 150 km. In this paper we present a method of analysis of seismic records which is very sensitive to azimuthal anisotropy and is applicable at almost any depth range. The idea of the method is to detect and analyse the SH -component of the waves, converted from P to S in the mantle. The procedure of record processing includes frequency filtering, axis rotation, transformation of the record to a standard form, stacking the standardized SH -component records of many seismic events, and the harmonic analysis of amplitude as a function of the direction of wave propagation. When applied to the long-period records of NORSAR the procedure detected a converted wave with the properties implying the possibility of its propagation in a transversely isotropic medium with a horizontal axis of symmetry . Our preferred model postulates anisotropy of ∼ 1 per cent in a layer 50 km thick at the base of the upper mantle.     

Determination of three-dimensional velocity structure from observations of refracted body waves

Summary. The computational effectiveness of travel-time inversion methods depends on the parameterization of a 3-D velocity structure. We divide a region of interest into a few layers and represent the perturbation of wave slowness in each layer by a series of Chebyshev polynomials. Then a relatively complex velocity structure can be dcscribed by a small set of parameters that can be accurately evaluated by a linearized inversion of travel-time residuals. This method has been applied to artificial and real data at small epicentral distances and in the teleseismic distance range. The corresponding matrix equations were solved using singular value decomposition. The results suggest that the method combines resolution with computational convenience.     

Evaluation of Simulated CO_2 Concentrations from the CarbonTracker-Asia Model Using In-situ Observations over East Asia for 2009–2013

The CarbonTracker(CT) model has been used in previous studies for understanding and predicting the sources, sinks, and dynamics that govern the distribution of atmospheric CO_2 at varying ranges of spatial and temporal scales. However, there are still challenges for reproducing accurate model-simulated CO_2 concentrations close to the surface, typically associated with high spatial heterogeneity and land cover. In the present study, we evaluated the performance of nested-grid CT model simulations of CO_2 based on the CT2016 version through comparison with in-situ observations over East Asia covering the period 2009–13. We selected sites located in coastal, remote, inland, and mountain areas. The results are presented at diurnal and seasonal time periods. At target stations, model agreement with in-situ observations was varied in capturing the diurnal cycle. Overall, biases were less than 6.3 ppm on an all-hourly mean basis, and this was further reduced to a maximum of 4.6 ppm when considering only the daytime. For instance, at Anmyeondo, a small bias was obtained in winter, on the order of 0.2 ppm. The model revealed a diurnal amplitude of CO_2 that was nearly flat in winter at Gosan and Anmyeondo stations, while slightly overestimated in the summertime. The model's performance in reproducing the diurnal cycle remains a challenge and requires improvement. The model showed better agreement with the observations in capturing the seasonal variations of CO_2 during daytime at most sites, with a correlation coefficient ranging from 0.70 to 0.99. Also, model biases were within-0.3 and 1.3 ppm, except for inland stations(7.7 ppm).     

Determination of REE, Y, Nb, Zr, Hf, Ta, Th and U in Geological Reference Materials LSHC-1 and Amf-1 by Solution and Laser Ablation ICP-MS

This paper presents data on REE and Y, Nb, Zr, Hf, Ta, Th and U abundances for two candidate reference materials (RMs), spinel lherzolite LSHC-1 and amphibole Amf-1, being currently developed at the Institute of Geochemistry SB RAS, Irkutsk. To determine the contents of these elements inductively coupled plasma-mass spectrometry was applied with: (i) solution nebulisation (solution ICP-MS) and (ii) laser ablation (LA-ICP-MS) of fused glass disks. The precision of results obtained by both techniques was better than 6% RSD for most elements. Accuracy was assessed by using the geochemical RMs JB-2, JGb-1 (GSJ) and MAG-1 (USGS). The trace element results by solution ICP-MS for JGb-1 and JB-2 agree with reference values presented by Imai et al. (1995, this Journal) within 1–10%. Significant differences were found for Nb and Ta determinations. The accuracy of LA-ICP-MS results evaluated by RM MAG-1 was within 4%, except for Eu (about 10%). The analytical results obtained for LSHC-1 and Amf-1 by solution ICP-MS and LA-ICP-MS were in good agreement with each other and with INAA and XRF data presented for the certification of these RMs. They can be considered as the indicative values for assigning certified values to the above-mentioned RMs.