Assessment of transmission losses and groundwater recharge from runoff events in a wadi under shortage of data on lateral inflow,Negev, Israel

A hydrological–lithostratigraphical model was developed for assessment of transmission losses and groundwater recharge from runoff events in arid water courses where hydrological and meteorological records are incomplete. Water balance equations were established for reaches between hydrometric stations. Because rainfall and tributary flow data are scarce, lateral inflow, which is an essential component of the water balance equation, could not be estimated directly. The solution was obtained by developing a method which includes a hydrological–lithostratigraphical analogy. This is based on the following assumptions: (a) runoff resulting from a given rainfall event is related to the watershed surface lithology; (b) for a given event, the spatial distribution of runoff reflects the distribution of rainfall: and (c) transmission losses are uniquely related to the total inflow to the reach. The latter relationship, called the loss function, and the water balance equation comprise a model which simultaneously assesses lateral inflow and transmission losses for runoff events recorded at the terminal stations. The model was applied to three reaches of the arid Nahal Tsin in Israel. In this case study, the transmission losses were of the same order of magnitude as the flow at the major hydrometric stations. The losses were subdivided into channel moistening, which subsequently evaporates, and deep percolation, which recharges groundwater. For large runoff events, evaporation was substantially smaller than the losses. The mean annual recharge of groundwater from runoff events in the Tsin watershed was 4·1×10⁶ m³, while the mean annual flow volume at the major stations ranged from 0·6 to 1·5×10⁶ m³. Once in 100 years, the annual recharge may be seven times higher than the mean annual value, but the recharge during most years is very small. Copyright © 1999 John Wiley & Sons, Ltd.     

Pyritization processes and greigite formation in the advancing sulfidization front in the upper Pleistocene sediments of the Black Sea

Pyritization in late Pleistocene sediments of the Black Sea is driven by sulfide formed during anaerobic methane oxidation. A sulfidization front is formed by the opposing gradients of sulfide and dissolved iron. The sulfidization processes are controlled by the diffusion flux of sulfide from above and by the solid reactive iron content. Two processes of diffusion-limited pyrite formation were identified. The first process includes pyrite precipitation with the accumulation of iron sulfide precursors with the average chemical composition of FeS_n (n = 1.10-1.29), including greigite. Elemental sulfur and polysulfides, formed from H₂S by a reductive dissolution of Fe(III)-containing minerals, serve as intermediates to convert iron sulfides into pyrite. In the second process, a “direct” pyrite precipitation occurs through prolonged exposure of iron-containing minerals to dissolved sulfide. Methane-driven sulfate reduction at depth causes a progressive formation of pyrite with a δ³⁴S of up to +15.0‰. The S-isotopic composition of FeS₂ evolves due to contributions of different sulfur pools formed at different times. Steady-state model calculations for the advancement of the sulfidization front showed that the process started at the Pleistocene/Holocene transition between 6360 and 11 600 yr BP. Our study highlights the importance of anaerobic methane oxidation in generating and maintaining S-enriched layers in marine sediments and has paleoenvironmental implications.     

The role of sea ice in the temperature-precipitation feedback of glacial cycles

The response of the hydrological cycle to climate variability and change is a critical open question, where model reliability is still unsatisfactory, yet upon which past climate history can shed some light. Sea ice is a key player in the climate system and in the hydrological cycle, due to its strong albedo effect and its insulating effect on local evaporation and air-sea heat flux. Using an atmospheric general circulation model with specified sea surface temperature and sea-ice distribution, the role of sea ice in the hydrological cycle is investigated under last glacial maximum (LGM) and present day conditions, and by studying its contribution to the “temperature-precipitation feedback”. By conducting a set of sensitivity experiments in which the albedo and thickness of the sea ice are varied, the various effects of sea ice in the hydrological cycle are isolated. It is demonstrated that for a cold LGM like state, a warmer climate (as a result of reduced sea-ice cover) leads to an increase in snow precipitation over the ice sheets. The insulating effect of the sea ice on the hydrological cycle is found to be larger than the albedo effect. These two effects interact in a nonlinear way and their total effect is not equal to summing their separate contribution.     

Influence of solar activity on the state of the wheat market in medieval England

The database of professor Rogers (1887), which includes wheat prices in England in the Middle Ages, was used to search for a possible influence of solar activity on the wheat market. Our approach was based on the following: (1) Existence of the correlation between cosmic ray flux entering the terrestrial atmosphere and cloudiness of the atmosphere. (2) Cosmic ray intensity in the solar system changes with solar activity, (3) Wheat production depends on weather conditions as a nonlinear function with threshold transitions. (4) A wheat market with a limited supply (as it was in medieval England) has a highly nonlinear sensitivity to variations in wheat production with boundary states, where small changes in wheat supply could lead to bursts of prices or to prices falling. We present a conceptual model of possible modes for sensitivity of wheat prices to weather conditions, caused by solar cycle variations, and compare expected price fluctuations with price variations recorded in medieval England. We compared statistical properties of the intervals between wheat price bursts during the years 1249-1703 with statistical properties of the intervals between the minima of solar cycles during the years 1700-2000. We show that statistical properties of these two samples are similar, both for characteristics of the distributions and for histograms of the distributions. We analyze a direct link between wheat prices and solar activity in the 17^th century, for which wheat prices and solar activity data (derived from ¹⁰Be isotope) are available. We show that for all 10 time moments of the solar activity minima the observed prices were higher than prices for the corresponding time moments of maximal solar activity (100% sign correlation, on a significance level < 0.2%). We consider these results a direct evidence of the causal connection between wheat prices bursts and solar activity.     

Crust and mantle of the Tien Shan from data of the receiver function tomography

A 3-D velocity model of the Tien Shan crust and upper mantle is constructed through the inversion of the receiver functions of P and S waves together with teleseismic traveltime anomalies at nearly 40 local seismic stations. It is found that in the vast central region, where no strong earthquakes have been known over the past century, the S wave velocity at depths of 10–35 km is lower than in adjacent regions by up to 10%. These data are evidence for mechanical weakness of the crust preventing the accumulation of elastic energy. Apparently, the lower velocity and the weakness of the crust are due to the presence of water. The weakness of the crust is one of the possible reasons for the strain localization responsible for the formation of the present Tien Shan but can also be due in part to the young orogenesis. The crustal thickness is largest (about 60 km) in the Tarim-Tien Shan junction zone. The crust-mantle boundary in this region descends by a jump as a result of an increase in the lower crust thickness. This is probably due to the underthrusting of the Tien Shan by the Tarim lithosphere. This causes the mechanically weak lower crust of the Tarim to delaminate and accumulate in nearly the same way as an accretionary prism during the subduction of oceanic lithosphere. In the upper mantle, the analysis has revealed a low velocity anomaly, apparently related to basaltic outflows of the Upper Cretaceous-Early Paleogene. The Cenozoic Bachu uplift in the northern Tarim depression is also associated with the low velocity anomaly. The Naryn depression is characterized by a high velocity in the upper mantle and can be interpreted as a fragment of an ancient platform.     

Manganese(II) oxidation driven by lateral oxygen intrusions in the western Black Sea

Mn(II) oxidation in the suboxic zone of the water column was studied at four stations in the western Black Sea. We measured Mn(II) oxidation rates using ⁵⁴Mn tracer and tested the hypothesis of alternative oxidants for Mn(II) other than dissolved oxygen. In anoxic incubation experiments with water from different depths of the chemocline, Mn(II) was not oxidized by nitrite, nitrate, or iodate. In the presence of light, Mn(II) also was not oxidized under anoxic conditions as well. Anaerobic Mn(II) oxidizing microorganisms could not be enriched. In oxic incubation experiments, the addition of alternative oxidants did not significantly increase the Mn(II) oxidation rate. The lack of an anaerobic Mn(II) oxidation in our experiments does not unambiguously prove the absence of anaerobic Mn(II) oxidation in the Black Sea but suggests that dissolved oxygen is the only oxidant for biologically catalyzed Mn(II) oxidation. Lateral intrusions of modified Bosphorus water were shown to be the main mechanism providing dissolved oxygen in the suboxic and the upper anoxic zones and explaining observed Mn(II) oxidation rates. Maximum in situ Mn(II) oxidation rates in the suboxic zone were 1.1 nM Mn(II) per h in the central Black Sea, 25 nM Mn(II) per h on the Romanian continental slope and 60 nM Mn(II) per h on the Anatolian continental slope. These rates correlate with the amount of particulate Mn and the number of Mn-oxide particles and are in agreement with rates measured 13 yr before. Our study highlights the importance of lateral intrusions of oxygen for the ventilation of the suboxic zone and the anoxic interior and for the regulation of different oxidation-reduction processes in the chemocline, including Mn(II) oxidation, which may be significant for other anoxic basins as well.     

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