Magnetic fabrics and their relationship with the emplacement of the Piracaia pluton,SE Brazil

Magnetic fabric and rock-magnetism studies were performed on the four units of the 578 ± 3-Ma-old Piracaia pluton (NW of São Paulo State, southern Brazil). This intrusion is roughly elliptical (~32 km²), composed of (i) coarse-grained monzodiorite (MZD-c), (ii) fine-grained monzodiorite (MZD-f), which is predominant in the pluton, (iii) monzonite heterogeneous (MZN-het), and (iv) quartz syenite (Qz-Sy). Magnetic fabrics were determined by applying both anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of anhysteretic remanent magnetization (AARM). The two fabrics are coaxial. The parallelism between AMS and AARM tensors excludes the presence of a single domain (SD) effect on the AMS fabric of the units. Several rock-magnetism experiments performed in one specimen from each sampled units show that for all of them, the magnetic susceptibility and magnetic fabrics are carried by magnetite grains, which was also observed in the thin sections. Foliations and lineations in the units were successfully determined by applying magnetic methods. Most of the magnetic foliations are steeply dipping or vertical in all units and are roughly parallel to the foliation measured in the field and in the country rocks. In contrast, the magnetic lineations present mostly low plunges for the whole pluton. However, for eight sites, they are steep up to vertical. Thin-section analyses show that rocks from the Piracaia pluton were affected by the regional strain during and after emplacement since magmatic foliation evolves to solid-state fabric in the north of the pluton, indicating that magnetic fabrics in this area of the pluton are related to this strain. Otherwise, the lack of solid-state deformation at outcrop scale and in thin sections precludes deformation in the SW of the pluton. This evidence allows us to interpret the observed magnetic fabrics as primary in origin (magmatic) acquired when the rocks were solidified as a result of magma flow, in which steeply plunging magnetic lineation suggests that a feeder zone could underlie this area.     

Differential responses of hillslope and channel elements to rainfall events in a semi-arid area

The degree of hydrological connectivity of hillslope elements in a semi-arid climate was studied at the season and event timescales. Field data were obtained in Rambla Honda, a Medalus project field site situated in SE Spain, on micaschist bedrock and with 300 mm annual rainfall. The season timescale was assessed using correlation analysis between soil moisture and topographic indices. The event timescale was studied by a quasi-continuous monitoring of rainfall, soil moisture, runoff and piezometric levels. Results show that widespread transfers of water along the hillslope are unusual because potential conditions for producing overland flow or throughflow are spatially discontinuous and extremely short-lived. During extreme events, runoff coefficients may be locally high (ca. 40% on slope lengths of 10 m), but decrease dramatically at the hillslope scale (<10% on slope lengths of 50 m). Two mechanisms of overland flow generation have been identified: infiltration excess, and local subsurface saturation from upper layers. The former occurs during the initial stages of the event while the latter, which is quantitatively more important, takes place later and requires a certain time structure of rainfall intensities that allow saturation of the topsoil and the subsequent production of runoff. Hillslopes and alluvial fans function as runoff sources and sinks respectively. Permanent aquifers are lacking in Rambla Honda. Variable proportions of hillslope areas may contribute to flash floods in the main channel, but their contribution to the formation of saturated layers within the sediment fill is very limited.     

Active and break phases of the South American summer monsoon: MJO influence and subseasonal prediction

The role of the Madden–Julian Oscillation (MJO) in producing active and break periods of the South American (SA) monsoon and the performance of the ECMWF and NCEP models in predicting these periods at multiweek lead times are assessed. Two monsoon indices, based on precipitation and wind, are proposed to characterize these periods. The models represent well the observed association of active and break monsoon days with large scale convection and circulation anomalies. Although reproducing approximately the distribution of active and break days proportions in each phase of the MJO cycle, models produce a phase shift between observed and simulated distributions because they establish the teleconnection between Central Pacific and South America, as well as its impacts, sooner than in observations. The predictive skill of both rainfall and wind anomalies is limited to about 2 weeks, with the monsoon wind index displaying higher correlation score till week 3. The forecast performance is apparently not affected by initialization on active or break monsoon days. However, it is higher for prediction of lower precipitation in break days than heavier rainfall in active days. Wind is much better predicted than rainfall for active days, which could be used for extreme rainfall events forecast. Although relatively small at shorter lead times, the MJO contribution is the major source of rainfall predictability after week 3. To improve the multiweek prediction of SA monsoon, models need not only to predict correctly the MJO phase, but also to reproduce in the right phase the MJO-related SA rainfall anomalies.

     

Impact of human activities on the central Mediterranean offshore: Evidence from Hg distribution in box-core sediments from the Ionian Sea

Total Hg concentrations have been measured for five box-core sediments collected seawards of the Augusta industrial area (SE Sicily). In more coastal sediments, upcore increasing Hg concentrations, exceeding the Hg background concentration estimated for the Strait of Sicily, indicate Hg contamination over time due to the industrial area development. Strong correlation between total organic C (TOC) and Hg concentrations was found only for core BX2, that displays organic C to total N (C/N) ratios indicative of autochthonous organic matter. For other sediments, high Hg enrichment factors with respect to TOC indicate, in addition to Hg trapping by TOC, other factors as responsible for Hg accumulation. In the presence of some contribution of detrital organic matter, Hg is mainly adsorbed onto the mineral component of the bottom sediments probably because TOC is saturated by Hg excess. Contaminant impact affected also the open sea environment. Main drivers of Hg flux towards the offshore were dredged materials, which repeatedly discharged sediment, resulting in substantial increases in TOC contents and high C/N ratios. Consistent with the geochemistry of recent turbidites, these anomalous sedimentary inputs induced sediment redox environment modifications, constrained by Mn peaks, which affected Hg distribution.     

Late orogenic collapse and thermal doming in the northern Gondwana margin incorporated in the Variscan Chain: A case study from the Ozieri Metamorphic Complex, northern Sardinia, Italy

A branch of the South European Variscan chain is noticeably exposed in Sardinia. The early stage of collision between the Northern Gondwana margin and the Armorica Terrane Assemblage (ATA) generated syn-metamorphic folding and thrusting. The evidences of such deformation are well preserved in the nappe zone, a structural domain characterized by stacking of different tectonic units under metamorphism of Barrovian greenschist facies. A late, post-nappe, shortening, under retrograde metamorphic conditions, gave rise to wide, upright, N120–N160 trending antiforms that control the trend of the chain. The structural analysis of the Ozieri Metamorphic Complex (OMC) shows evidence of an important phase of late-Variscan extensional tectonics. Deformation results in, the formation of oppositely dipping, normal shear zones, which developed at upper and middle structural level along the limbs of major regional antiforms causing fabric reactivation, crustal thinning, and exhumation of the OMC core. Within the OMC, the activity of the shear zones was coeval with HT-LP metamorphism as suggests the occurrence of syn-kinematic cordierite + andalusite ± sillimanite + biotite. Whereas syntectonic dykes and a tonalite body in the deeper part of the OMC indicate that early emplacement of melt along shear zones and/or in the antiform hinges possibly supplied the heat for the anomalous thermal gradient and triggered the exhumation of a core complex-like structure.     

Evolution of an early Eocene pull‐apart basin in the Central Pontides (Northern Turkey): New insights into the origin of the North Anatolian Shear Zone

Although the North Anatolian Shear Zone is one of the main lithospheric‐scale strike‐slip deformation zone in the world, playing a prominent role in the complex geodynamic interaction among the Eurasian, Anatolian and Arabian plates, the onset time of its activity remains highly controversial. Here, we tackle this issue by utilizing nannofossil biostratigraphy on deposits from the Ta?cilar basin, a pull‐apart basin that we have identified inside the North Anatolian Shear Zone overprinting the Intra‐Pontide suture zone. The syn‐tectonic sedimentary succession of the Ta?cilar basin developed completely during the early Eocene (Ypresian; CNE4–CNE5 Zones). The strike‐slip faulting related to the initial onset of the North Anatolian Shear Zone can likely be constrained within the Ypresian, suggesting that the westward escape of the Anatolian plate along the North Anatolian Shear Zone started in the early Eocene.     

Wetlandscape hydrologic dynamics driven by shallow groundwater and landscape topography

Wetlands play an important role in watershed eco-hydrology. The occurrence and distribution of wetlands in a landscape are affected by the surface topography and the hydro-climatic conditions. Here, we propose a minimalist probabilistic approach to describe the dynamic behaviour of wetlandscape attributes, including number of inundated wetlands and the statistical properties of wetland stage, surface area, perimeter, and storage volume. The method relies on two major assumptions: (a) wetland bottom hydrologic resistance is negligible; and (b) groundwater level is parallel to the mean terrain elevation. The approach links the number of inundated wetlands (depressions with water) to the distribution of wetland bottoms and divides, and the position of the shallow water table. We compared the wetlandscape attribute dynamics estimated from the probabilistic approach to those determined from a parsimonious hydrologic model for groundwater-dominated wetlands. We test the reliability of the assumptions of both models using data from six cypress dome wetlands in the Green Swamp Wildlife Management Area, Florida. The results of the hydrologic model for groundwater-dominated wetlands showed that the number of inundated wetlands has a unimodal dependence on the groundwater level, as predicted by the probabilistic approach. The proposed models provide a quantitative basis to understand the physical processes that drive the spatiotemporal hydrologic dynamics in wetlandscapes impacted by shallow groundwater fluctuations. Emergent patterns in wetlandscape hydrologic dynamics are of key importance not only for the conservation of water resources, but also for a wide range of eco-hydrological services provided by connectivity between wetlands and their surrounding uplands.     

Fecal Sterols in Estuarine Sediments as Markers of Sewage Contamination in the Cubat?o Area, S?o Paulo, Brazil

Sterol biomarkers serve as an alternative method for detecting sewage pollution. Sterols were extracted from samples of surface sediment collected in Cubat?o (the Vila dos Pescadores and Vila Esperan?a communities) and quantified using GC–MS after Soxhlet extraction, cleanup, and derivatization. Fecal contamination was evaluated based on the concentration of coprostanol and the ratio of the selected sterols. The most abundant sterol was cholestanol, followed by coprostanol. The concentrations of coprostanol in surface sediments ranged from a minimum of 4.21?μg?g^?1 dry sediment (Vila dos Pescadores station) to a maximum of 8.32?μg?g^?1 dry sediment (Vila Esperan?a station). A coprostanol concentration of about 10?μg?g^?1 was found, indicating areas of high sewage contamination. Coprostanol levels at sewage stations were higher than in other Brazilian coastal areas, which may be attributed to the fraction of the population without sanitation services.     

Chemistry, Raman and infrared spectroscopic characterization of the phosphate mineral reddingite: (MnFe)3(PO4)2(H2O,OH)3, a mineral found in lithium-bearing pegmatite

Detailed investigation of an intermediate member of the reddingite–phosphoferrite series, using infrared and Raman spectroscopy, scanning electron microcopy and electron microprobe analysis, has been carried out on a homogeneous sample from a lithium-bearing pegmatite named Cigana mine, near Conselheiro Pena, Minas Gerais, Brazil. The determined formula is $ ({\text{Mn}}_{1.60} {\text{Fe}}_{1.21} {\text{Ca}}_{0.01} {\text{Mg}}_{0.01} )_{\sum 2.83} ({\text{PO}}_{4} )_{2.12} \cdot ({\text{H}}_{2} {\text{O}}_{2.85} {\text{F}}_{0.01} )_{\sum 2.86} $ , indicating predominance in the reddingite member. Raman spectroscopy coupled with infrared spectroscopy supports the concept of phosphate, hydrogen phosphate and dihydrogen phosphate units in the structure of reddingite-phosphoferrite. Infrared and Raman bands attributed to water and hydroxyl stretching modes are identified. Vibrational spectroscopy adds useful information to the molecular structure of reddingite–phosphoferrite.     

Groundwater Modeling of Fractured Aquifers in Mines: The Case Study of Gavorrano (Tuscany,Italy)

In this paper, we describe the hydrogeological problems related to the closure of the mine at Gavorrano (Tuscany, Italy). The geological and geo-structural settings of the Gavorrano area affect the groundwater flow systems and their chemical composition; hence, the settings also affect the chance and modalities to rehabilitate and re-utilize these water resources. This paper reports the results of studies, analyses of existing data and the consequent implementation of preliminary numerical models with particular reference to the effects of controlled water recovery and the complex measures required for stopping dewatering. The study incorporates recent data and the available historical records in an analysis of the hydrodynamic impact of water recovery and an assessment of the consequences of water recovery for water resources restoration. The applied numerical simulations have been demonstrated to be a promising and effective tool for planning and managing the future applications of groundwater recovery in the Gavorrano mining area. Using these applications, it will be possible to implement mitigation measures and types of re-use that consider thermal, chemical and discharge features.