Functioning of intertidal flats inferred from temporal and spatial dynamics of O<Subscript>2</Subscript>, H<Subscript>2</Subscript>S and pH in their surface sediment

In this article, we describe the dynamics of pH, O₂ and H₂S in the top 5–10 cm of an intertidal flat consisting of permeable sand. These dynamics were measured at the low water line and higher up the flat and during several seasons. Together with pore water nutrient data, the dynamics confirm that two types of transport act as driving forces for the cycling of elements (Billerbeck et al. 2006b): Fast surface dynamics of pore water chemistry occur only during inundation. Thus, they must be driven by hydraulics (tidal and wave action) and are highly dependent on weather conditions. This was demonstrated clearly by quick variation in oxygen penetration depth: Seeps are active at low tide only, indicating that the pore water flow in them is driven by a pressure head developing at low tide. The seeps are fed by slow transport of pore water over long distances in the deeper sediment. In the seeps, high concentrations of degradation products such as nutrients and sulphide were found, showing them to be the outlets of deep-seated degradation processes. The degradation products appear toxic for bioturbating/bioirrigating organisms, as a consequence of which, these were absent in the wider seep areas. These two mechanisms driving advection determine oxygen dynamics in these flats, whereas bioirrigation plays a minor role. The deep circulation causes a characteristic distribution of strongly reduced pore water near the low water line and rather more oxidised sediments in the centre of the flats. The two combined transport phenomena determine the fluxes of solutes and gases from the sediment to the surface water and in this way create specific niches for various types of microorganisms.     

A hyperspectral experiment over tropical forests based on the EO-1 orbit change and PROSAIL simulation

ABSTRACT

We designed a unique hyperspectral experiment from the Earth Observing One (EO-1) orbit change to evaluate solar illumination effects over tropical forests in Brazil. Ten nadir-viewing Hyperion images collected over a fixed site and period of the year (July to August) were selected for analysis. We evaluated variations in reflectance and in 16 narrowband vegetation indices (VIs) with increasing solar zenith angle (SZA) from the pre-drift (2004–2008) to the EO-1 drift period (2011–2016). To detect changes in reflectance and shadows, we applied spectral mixture analysis (SMA) and principal component analysis (PCA) and calculated the similarity spectral angle (θ) between the vegetation spectra measured with variable SZA. The magnitude of the illumination effects was also evaluated from change-point analysis and nonparametric Mann-Whitney U tests applied over the time series. Finally, we complemented our experiment using the PROSAIL model to simulate the VIs variation with increasing SZA resultant from satellite drift. The results showed significant changes in Hyperion reflectance and VIs, especially when the EO-1 crossed the study area at earlier times and larger SZA in 2015 (9:05 a.m.; SZA = 59°) and 2016 (8:30 a.m.; SZA = 67°). Compared to the pre-drift period (10:30 a.m.; SZA = 45°), the SZA differences of 14° (2015) and 22° (2016) increased the shade fractions and decreased the vegetation brightness. PCA separated the pre-drift and drift reflectance datasets, showing shifts in scores due to changes in brightness. θ increased with SZA, indicating changes in the shape of the vegetation spectra with drift. For most VIs, the change-point analysis indicated 2015 (SZA = 59°) as the predominant year of detected changes. Compared to the EO-1 original orbit, the Plant Senescence Reflectance Index (PSRI), Anthocyanin Reflectance Index (ARI) and Structure Insensitive Pigment Index (SIPI) presented the largest positive changes during drift, while the Photochemical Reflectance Index (PRI), Visible Atmospherically Resistant Index (VARI) and Enhanced Vegetation Index (EVI) had the largest negative changes. The effect size of the illumination geometry on these VIs was large, as indicated by increasing values of the Cohen’s r metric toward 2016. The anisotropy of the Hyperion VIs was generally consistent with that from PROSAIL in the simulated pre-drift and drift periods. Focusing on structural indices, it affected the relationships between VIs and simulated leaf area index (LAI) at large SZA.     

Modelling Positional Uncertainty of Line Features by Accounting for Stochastic Deviations from Straight Line Segments

The assessment of positional uncertainty in line and area features is often based on uncertainty in the coordinates of their elementary vertices which are assumed to be connected by straight lines. Such an approach disregards uncertainty caused by sampling and approximation of a curvilinear feature by a sequence of straight line segments. In this article, a method is proposed that also allows for the latter type of uncertainty by modelling random rectangular deviations from the conventional straight line segments. Using the model on a dense network of sub‐vertices, the contribution of uncertainty due to approximation is emphasised; the sampling effect can be assessed by applying it on a small set of randomly inserted sub‐vertices. A case study demonstrates a feasible way of parameterisation based on assumptions of joint normal distributions for positional errors of the vertices and the rectangular deviations and a uniform distribution of missed sub‐vertices along line segments. Depending on the magnitudes of the different sources of uncertainty, not accounting for potential deviations from straight line segments may drastically underestimate the positional uncertainty of line features.     

Deep-sea coral aragonite as a recorder for the neodymium isotopic composition of seawater

Deep-sea corals have been shown to be useful archives of rapid changes in ocean chemistry during the last glacial cycle. Their aragonitic skeleton can be absolutely dated by U-Th data, freeing radiocarbon to be used as a water-mass proxy. For certain species of deep-sea corals, the growth rate allows time resolution that is comparable to ice cores. An additional proxy is needed to exploit this opportunity and turn radiocarbon data into rates of ocean overturning in the past.Neodymium isotopes in seawater can serve as a quasi-conservative water-mass tracer and initial results indicate that deep-sea corals may be reliable archives of seawater Nd isotopes. Here we present a systematic study exploring Nd isotopes as a water-mass proxy in deep-sea coral aragonite. We investigated five different genera of modern deep-sea corals (Caryophyllia, Desmophyllum, Enallopsamia, Flabellum, Lophelia), from global locations covering a large potential range of Nd isotopic compositions. Comparison with ambient seawater measurements yields excellent agreement and suggests that deep-sea corals are reliable archives for seawater Nd isotopes.A parallel study of Nd concentrations in these corals yields distribution coefficients for Nd between seawater and coral aragonite of 1-10, omitting one particular genus (Enallopsamia). The corals and seawater did however not come from exactly the same location, and further investigations are needed to reach robust conclusions on the incorporation of Nd into deep-sea coral aragonite.Lastly, we studied the viability of extracting the Nd isotope signal from fossil deep-sea corals by carrying out stepwise cleaning experiments. Our results show that physical removal of the ferromanganese coating and chemical pre-cleaning have the highest impact on Nd concentrations, but that oxidative/reductive cleaning is also needed to acquire a seawater Nd isotope signal.     

TAOS – The Taiwanese‐American Occultation Survey

The Taiwanese‐American Occultation Survey (TAOS) seeks to determine the number and size spectrum for small (∼3 km) bodies in the Kuiper Belt. This will be accomplished by searching for the brief occultations of bright stars (R ∼ 14) by these objects. We have designed and built a special purpose photometric monitoring system for this purpose. TAOS comprises four 50 cm telescopes, each equipped with a 2048 × 2048 pixel CCD camera, in a compact array located in the central highlands of Taiwan. TAOS will monitor up to 2 000 stars at 5 Hz. The system went into scientific operation in the autumn of 2005. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)