A radio magnetotelluric study to evaluate the extents of a limestone quarry in Estonia

Electromagnetic signals from distant radio transmitters in the frequency range 15–250 kHz were measured to model an electrical resistivity structure beneath 7 profiles in the vicinity of the Karinu limestone quarry in Estonia with the aim to map the extent of the economically exploitable limestone. The resistivity models from a 2D inversion of determinant resistivity and phase values using an Occam type of regularization contained reasonably accurate information about the geometry, namely depth to the top and the bottom of the target high‐resistivity limestone. The resistivity models correlated well with existing geological evidences as well as information from closely located boreholes. However, the sharp lithological boundaries seen in the boreholes were not resolved exactly in the resistivity models. This is probably because of the smoothing regularization used in the inversion process. Combined use of borehole data together with resistivity models resulted in two major geological interpretations; a) towards the western part of the existing limestone quarry there is a NNW to NS striking fault, covered by post‐glacial sediments, b) a potential cost‐effective exploitable area containing high quality highly resistive limestone is located south of the existing quarry. This case study shows the applicability of the reasonably fast radio magnetotelluric (RMT) method for the exploration of near‐surface resources.     

Enthalpy of formation of sulfate green rusts

As a contribution to the systematic study of iron oxide thermodynamics, this work reports enthalpies of formation of green rust, a double layered (Fe^II, Fe^III) hydroxide with the ideal stoichiometry , with sulfate as the anion in the interlayer. Samples were characterized by X-ray powder diffraction, thermogravimetric analysis, infrared spectroscopy, and Mössbauer spectroscopy. Full chemical analysis was performed. Contents of Fe^II, Fe^III, water, and sulfate were obtained. We report standard enthalpies of formation for green rust with different Fe^II/Fe^III ratios. Enthalpies of formation from single cation compounds, namely, Fe(OH)₂, Fe(OH)₃, FeSO₄ and H₂O show reasonable agreement with Gibbs free energies of formation from single cation compounds recalculated from the reported literature values. These values show that green rust has little stabilization over a mechanical mixture of these single cation compounds and there is no thermodynamic preference for any particular Fe^II/Fe^III ratio.     

Dr. Evamaria Koch (1961–2014)

During their spring migration, Atlantic herring (Clupea harengus) populations in the Baltic Sea rely on shallow transitional waters, such as estuaries, bays, and lagoons for spawning. Such inshore spawning grounds are ecologically important by providing suitable substrates for demersal egg deposition. These habitats are often highly impacted by multiple anthropogenic threats. Decades of eutrophication have caused a decline in depth distribution of submerged aquatic vegetation, the main herring spawning substrate in the Baltic Sea. Nowadays, spawning beds are limited to the shallow littoral zone (≤3 m depth). Accordingly, macrophytes are increasingly exposed to mechanic forcing due to storm-induced wave action. Generally, reproductive success and year class strength of the Western Baltic herring population is strongly determined by the survival of early life stages such as eggs and larvae in local nursery areas. However, explicit mechanisms by which local stressors might affect overall recruitment are currently not well understood. Hypothesizing that aquatic vegetation limited by water depth causes high herring egg mortality due to increased exposure to storm-induced hydrodynamics, we performed a combination of field studies investigating the impact of storm events on herring egg loss. Results of an egg loss experiment revealed a total egg loss of 29% in one single spawning bed during a storm event within the spawning season and the quantification of eggs attached to macrophyte litter on the shoreline emphasize the potential for regional weather extremes such as storm events to act as influential stressors for herring reproduction.     

Ant mounds as a source of sediment in a tropical rainforest?

In Lutzito catchment on Barro Colorado Island, Panama, extraordinarily high suspended‐sediment yields of 1–2 Mg ha^?1 year^?1 were generated despite the dense forest cover coinciding with erosion‐resistant soils. We hypothesized that ant mounding activity is an important zoogeomorphological mechanism in this area, providing relevant quantities of easily transportable material at the soil surface. To test this hypothesis, all ant mound material was collected collected for dry mass determination from thirty 4 m² plots installed in the study area every 1–3 days during the 39‐day sampling period. Additionally, three ground‐nesting ant species responsible for mounds in the study area, Ectatomma ruidum, Trachymyrmex cornetzi and Strumigenys marginiventris, were identified. On the basis of the total of 1.38 kg of material collected in the wet season of 2011, the estimate for the whole 8 months wet season amounts to 725 kg ha^?1. As this value is in the same order of magnitude as sediment output, it shows that ants may act as important ecosystem engineers and contribute to sediment production here by providing large quantities of fine‐grained, readily erodible material at the soil surface for subsequent transport to the streambed. Copyright © 2014 John Wiley & Sons, Ltd.     

A new Middle Pleistocene interglacial record from Denmark: Chronostratigraphic correlation,palaeovegetation and fire dynamics

Previously only three terrestrial interglacial periods were known from southern Scandinavia, all of which could be relatively easily correlated within the central European stratigraphical framework. Here, we present a new interglacial–interstadial pollen, plant macrofossil and charcoal record from Trelde Klint, Denmark, and analyse its biostratigraphy, correlation with other European records, vegetation development, fire dynamics and absolute dating. Except for a slight truncation of the early part of the record, the pollen stratigraphy exhibits a full interglacial succession, including temperate trees (Quercus, Ulmus and Tilia) during its mesocratic stage. Macrofossil analysis allowed identification to species level for Quercus robur, Picea abies and two mosses. Conifers (Pinus and Picea) dominate the pollen record of the interglacial sequence, and the occurrence of Larix pollen in the top part of the interglacial record as well as in the interstadial sediments is especially indicative of this interglacial. The overall diversity of tree genera is rather low. These biostratigraphical features suggest that Trelde Klint is unique among Danish records, but it is similar to records from northern Germany. Numerical analyses (REVEALS and DCA) indicate that forests during the temperate stage were dense and that vegetation openness increased only towards the end of the interglacial, accompanied by increased fire occurrence. A short interstadial sequence with a dominance of Pinus and Betula and the presence of Larix is present above the interglacial deposit. We argue that lack of attention to differences in fire regimes may hamper understanding of between‐site correlations of interglacial pollen records. OSL dating, using a novel feldspar technique, yields an average age of 350±20 ka for the sandy sediments above the interglacial layers at Trelde Klint, suggesting that the whole interglacial–interstadial succession belongs to Marine Isotope Stage 11.     

Effect of saline intrusion on the properties of cohesive soils in the Red River Delta,Vietnam

Abstract

This study conducted a series of laboratory experiments and established numerical models on selected undisturbed soil samples in the Red River Delta (RRD) to determine the effect of change in soils intruded by saline water. The variation in the technical parameters of soils was verified in soils fully saturated by solution of four salt concentrations, that is, 0.0, 9.9, 19.8, and 33.0?g/L. Results show that the content and composition of clay minerals in cohesive soils before and after saline intrusion are unchanged. The same finding is obtained for clay after removing absorbed water layer by using a centrifuge apparatus. The zeta potential and settlement velocity of soils in the RRD increase when salt is added to the saturated solution. Similarly, the deformation of soils increases proportionally with the salt concentrations of that solution. This result is attributed to the linear decrease in deformation modulus. The decrease in modulus versus salinities is nearly consistent for pressure stages from 100 to 400?kPa. The safety factor of bearing capacity also decreases linearly with salinities. The decrease reaches 12.5–16.3% when soils are in the maximum saline solution. All these changes are considered as the degradation of soils in saline media.     

Assessing groundwater vulnerability using travel time and specific surface area as indicators

 A method for general assessment of groundwater vulnerability was developed using the concept of hydrogeological settings by which a small-scale landscape can be represented by larger units on the map. For accidental spills, the time available for remedial actions is crucial. Travel times to the saturated zone or to a depth of 5 m are classified in four intervals, ranging from <1 day to > 1 yr. Total particle surface available for retention of pollutants in the unsaturated zone is used as a semi-quantitative indicator of vulnerability in a long-term perspective. This indicator is classified into four intervals, ranging from <1×10⁶ m²/m² to >25×10⁶ m²/m². The quality of the surfaces is not assessed. However, the absence of an intact soil profile is estimated to result in an increase in vulnerability by one class. Application of the methodology was demonstrated in an area south of Stockholm, Sweden. The digital geological map was processed using GIS to delineate four defined hydrogeological settings and vulnerability classes. Compared with an existing vulnerability map based on stratigraphic zoning, the hydrogeological settings allow a site to be interpreted in its hydrogeological context, and the use of quantitative vulnerability indicators increase the usefulness in practical planning and management. Received, June 1997 · Revised, February 1998 · Accepted, April 1998     

Impregnation of organic lake sediments for palaeomagnetic measurements

A procedure for impregnating high water-content sediments for palaeomagnetic measurements is described and applied to an organic lake sediment core. Comparison of results obtained by a standard sub-sampling procedure, and by the impregnation method, demonstrates a significant improvement in the scatter of the palaeomagnetic directions using the latter method.     

Airborne VLF measurements and mapping of ground conductivity in Sweden

Airborne VLF data are routinely collected by The Geological Survey of Sweden (SGU) as part of its bedrock mapping programme. In this paper we demonstrate that the novel Tensor VLF technique developed at Uppsala University and SGU can provide useful qualitative and quantitative information about the electrical conductivity distribution in the upper few hundred meters. Single transmitter scalar VLF maps emphasize those conductive structures that have dominant strikes in the direction of the transmitter. The tensor tipper (essentially the vertical magnetic field from currents along the strike direction) calculated from multiple transmitters is dependent only upon the underlying conductivity structure. Transformation of the tipper into the peaker (the horizontal divergence) has proven to enhance the lateral resolution while the transformation to the apparent resistivity can be used to discriminate different rock types. Two case histories from the application of VLF data are presented in this study. Two dimensional structures can be quantitatively modelled by modern inversion methods developed originally for deep electromagnetic MT soundings. Direct inversion of the real and imaginary parts of the tipper provides more quantitative information about the subsurface resistivity distribution.