Red dust rain within the Spanish Mediterranean area

Dust rain belongs to the climatological conditions of the Iberian Peninsula's Mediterranean seaboard. Traditionally known as muddy' or bloody rains, red dust rain has become a topical issue as a result of more frequent rainfall of this kind in recent years. In spite of the difficulties that studying this phenomenon involves, owing to the lack of systematically kept records at meteorological observatories, details are provided of the high frequency of such phenomena within the Spanish Mediterranean area, using records from other phenological sources. The study analyzes the chemical composition of red dust rain and the atmospheric factors giving rise to such phenomena. Whether there is a relationship betwen the higher frequency of dust rain and possible changes in global atmospheric circulation is as yet unclear.     

About the specification of erosion flux for soft stratified cohesive sediments

The present paper deals with the specification of bed erosion flux that accounts for the effects of sediment-induced stratification in the water column. Owing to difficulties in measuring the bed shear stress _b and the erosive shear strength _s, we suggest a series of methods that combine laboratory and numerical experiments. A simplified turbulent transport model that includes these effects helps to quantify _b and _s. Focusing on soft stratified beds, the present study considers erosion rate formulas of the form =_f exp {[T_b-T_s]} where is a model constant (=1 for Gularte's (1978) formula and =1/2 for Parchure's (1984) formula). First, the bed erosive strength profile _s(Z) is adjusted by forcing the turbulent transport model with measured erosion rates. Second, three procedures are suggested to determine the erosion rate formula coefficients _f and : a global procedure and two different layer-by-layer procedures. Each procedure is applied to an erosion experiment conducted in a rotating annular flume by Villaret and Paulic (1986). The use of the layer-by-layer procedure based on a least squares fitting technique provides a closer fit than the global procedure. The present study points out the complementarity of experimental and numerical approaches and also suggests possible improvements in laboratory test procedures.     

The P-T-fO 2 stability of deerite,Fe 12 2+ Fe 6 3+ [Si12O40](OH)10

New equilibrium experiments have been performed in the 20–27 kbar range to determine the upper thermal stability limit of endmember deerite, Fe ₁₂ ²⁺ Fe ₆ ³⁺ [Si₁₂O₄₀](OH)₁₀. In this pressure range, the maximum thermal stability limit is represented by the oxygen-conserving reaction: deerite(De)=9 ferrosilite(Fs)+3 magnetite(Mag)+3 quartz(Qtz)+5 H₂O(W) (1). Under the oxygen fugacities of the Ni-NiO buffer the breakdown-reduction reaction: De=12 Fs+2 Mag+5 W+1/2 O₂ (10) takes place at lower temperatures (e.g. T=63° at 27 kbar). The experimental brackets can be fitted using thermodynamic data for ferrosilite, magnetite and quartz from Berman (1988) and the following 1 bar, 298 K data for deerite (per gfw): V^o=55.74 J.bar^-1, S^o=1670 J.K^-1, H _f ^o =-18334 kJ, =2.5x10^-5K^-1, =-0.18x10^-5 bar^-1. Using these data in conjunction with literature data on coesite, grunerite, minnesotaite, and greenalite, the P-T stability field of endmember deerite has been calculated for P _s=P _{H 2}O. This field is limited by 6 univariant oxygenconserving dehydration curves, from which three have positive dP/dT slopes, the other three negative slopes. The lower pressure end of the stability field of endmember deerite is thus located at an invariant point at 250±70°C and 10+-1.5 kbar. Deerite rich in the endmember can thus appear only in environments with geothermal gradients lower than 10°C/km and at pressures higher than about 10 kbar, which is in agreement with 4 out of 5 independent P-T estimates for known occurrences. The presence of such deerite places good constraints on minimum pressure and maximum temperature conditions. From log f _{O 2}-T diagrams constructed with the same data base at different pressures, it appears that endmember deerite is, at temperatures near those of its upper stability limit, stable only over a narrow range of oxygen fugacities within the magnetite field. With decreasing temperatures, deerite becomes stable towards slightly higher oxygen fugacities but reaches the hematite field only at temperatures more than 200°C lower than the upper stability limit. This practically precludes the coexistence deerite-hematite with near-endmember deerite in natural environments.     

On the tidal variation of the geopotential

In this paper analytical expressions are derived for the temporal variations ofJ ₂ andJ ₂₂ due to the tides of the solid Earth, taking into account only the deformation of the mantle, and employing a procedure already used by the authors in their Hamiltonian theory of the Earth's rotation, which obtain the necessary parameters in a direct way by integration of those provided by a selected model of Earth interior.Numerical tables giving the periodic variation of coefficients are given, as well as a new prediction for UT1. For J ₂ and J ₂₂ the amplitudes reach such a magnitude that both two variations should not be ignored in studies involving the analysis of highly precise satellite tracking data. Moreover, the possibility of improving our knowledge of the value of those harmonic coefficients in only a more exact digit appears as to be strongly dependent on the limitations in the theoretical modeling of the variations of the inertia tensor due to solid tides.     

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.     

Dynamical evolution of NEAs: Close encounters, secular perturbations and resonances

We discuss the main mechanisms affecting the dynamical evolution of Near-Earth Asteroids (NEAs) by analyzing the results of three numerical integrations over 1 Myr of the NEA (4179) Toutatis. In the first integration the only perturbing planet is the Earth. So the evolution is dominated by close encounters and looks like a random walk in semimajor axis and a correlated random walk in eccentricity, keeping almost constant the perihelion distance and the Tisserand invariant. In the second integration Jupiter and Saturn are present instead of the Earth, and the 3/1 (mean motion) and v ₆ (secular) resonances substantially change the eccentricity but not the semimajor axis. The third, most realistic, integration including all the three planets together shows a complex interplay of effects, with close encounters switching the orbit between different resonant states and no approximate conservation of the Tisserand invariant. This shows that simplified 3-body or 4-body models cannot be used to predict the typical evolution patterns and time scales of NEAs, and in particular that resonances provide some fast-track dynamical routes from low-eccentricity to very eccentric, planet-crossing orbits.On leave from the Department of Mathematics, University of Pisa, Via Buonarroti 2, 56127 Pisa, Italy, thanks to the G. Colombo fellowships of the European Space Agency.     

Jupiter: New retrieved thermal profiles and ammonia distributions

New thermal profiles of Jupiter are retrieved from recent far infrared spectral measurements and for H₂ mixing ratios varying from 0.8 to 0.94. The effective temperature corresponding to the inferred thermal profile is 123.15 ± 0.35°K. Far-infrared brightness temperature spectra computed from these profiles are compared to experimental data including measurements made at high spectral resolution in the NH₃ν₂ band at 10 μm and in NH₃ pure rotational bands between 40 and 110 μm. It is found that a strong depletion of NH₃ does occur in the Jovian stratosphere and that ammonia seems to be undersaturated in the upper troposphere.     

Surface texture of Vesta from optical polarimetry

Polarimetric, photometric, and reflectance spectroscopic properties of asteroid 44 Vesta are simulated in the laboratory by a preparation of eucrite Bereba consisting oof a broad mixture of particle sizes (mainly greater than 50-μm) mixed and partially coated with particles of size 10 μm and less. Coarse grains are necessary for producing the same albedo and a very fine dust coating is necessary for producing the same polarization inversion angle as observed for Vesta. There are less small grains and fine dust in this sample than in lunar soils. Photometrically, if coating a sphere, this sample shows a constant brightness on the sunward half of the observed hemisphere, the brightness being given on the other half by the Minnaert reciprocity principle. With such a photometric behavior, the global geometric albedo and the sub-Earth point geometric albedo differ by no more than 5%. The microscopic phase coefficient β is 0.021 magnitude per degree for the sample; the larger value, β = 0.025, observed telescopically for Vesta indicates that large-scale roughness is present on this asteroid.     

X-ray imaging of three flares during the impulsive phase

The impulsive phases of three flares that occurred on April 10, May 21, and November 5, 1980 are discussed. Observations were obtained with the Hard X-ray Imaging Spectrometer (HXIS) and other instruments aboard SMM, and have been supplemented with Hα data and magnetograms. The flares show hard X-ray brightenings (16–30 keV) at widely separated locations that spatially coincide with bright Hα patches. The bulk of the soft X-ray emission (3.5–5.5 keV) originates from in between the hard X-ray brightenings. The latter are located at different sides of the neutral line and start to brighten simultaneously to within the time resolution of HXIS. Concluded is that:

1. The bright hard X-ray patches coincide with the footpoints of loops.
2. The hard X-ray emission from the footpoints is most likely thick target emission from fast electrons moving downward into the dense chromosphere.
3. The density of the loops along which the beam electrons propagate to the footpoints is restricted to a narrow range (10⁹ < n < 2 × 10¹⁰ cm^-3), determined by the instability threshold of the return current and the condition that the mean free path of the fast electrons should be larger than the length of the loop.
4. For the November 5 flare it seems likely that the acceleration source is located at the merging point of two loops near one of the footpoints.

It is found that the total flare energy is always larger than the total energy residing in the beam electrons. However, it is also estimated that at the time of the peak of the impulsive hard X-ray emission a large fraction (at least 20%) of the dissipated flare power has to go into electron acceleration. The explanation of such a high acceleration efficiency remains a major theoretical problem.     

Spatial and temporal evolution of soft and hard X-ray emission in a solar flare

We study the spatial and temporal characteristics of the 3.5 to 30.0 keV emission in a solar flare on April 10, 1980. The data were obtained by the Hard X-ray Imaging Spectrometer aboard the Solar Maximum Mission Satellite. It is complemented in our analysis with data from other instruments on the same spacecraft, in particular that of the Hard X-ray Burst Spectrometer.Key results of our investigation are: (a) Continuous energy release is needed to substain the increase of the emission through the rising phase of the flare, before and after the impulsive phase in hard X-rays. The energy release is characterized by the production of hot (5 × 10⁷ T 1.5 × 10⁸ K) thermal regions within the flare loop structures. (b) The observational parameters characterizing the impulsive burst show that it is most likely associated with non-thermal processes (particle acceleration). (c) The continuous energy release is associated with strong chromospheric evaporation, as evidenced in the spectral line behavior determined from the Bent Crystal Spectrometer data. Both processes seem to stop just before flare maximum, and the subsequent evolution is most likely governed by the radiative cooling of the flare plasma.