Warming the early earth—CO2 reconsidered

Despite a fainter Sun, the surface of the early Earth was mostly ice-free. Proposed solutions to this so-called “faint young Sun problem” have usually involved higher amounts of greenhouse gases than present in the modern-day atmosphere. However, geological evidence seemed to indicate that the atmospheric CO₂ concentrations during the Archaean and Proterozoic were far too low to keep the surface from freezing. With a radiative-convective model including new, updated thermal absorption coefficients, we found that the amount of CO₂ necessary to obtain 273 K at the surface is reduced up to an order of magnitude compared to previous studies. For the late Archaean and early Proterozoic period of the Earth, we calculate that CO₂ partial pressures of only about 2.9 mb are required to keep its surface from freezing which is compatible with the amount inferred from sediment studies. This conclusion was not significantly changed when we varied model parameters such as relative humidity or surface albedo, obtaining CO₂ partial pressures for the late Archaean between 1.5 and 5.5 mb. Thus, the contradiction between sediment data and model results disappears for the late Archaean and early proterozoic.     

Polybrominated diphenyl ethers and polychlorinated biphenyls in sediments of southwest Taiwan: regional characteristics and potential sources

Very little information is available on the contamination of coastal sediments of Taiwan by PBDEs and PCBs. In this study, we determined the concentrations of 19 PBDE and 209 PCB congeners in 57 surface sediment samples to identify the possible sources of PBDEs and PCBs. The total PBDE and PCB concentrations ranged from below detection limit to 7.73 ng/g and 0.88-7.13 ng/g, respectively; these values are within the ranges observed for most coastal sediments worldwide. The PBDE congeners were dominated by BDE-209 (50.7-99.7%), with minor contributions from penta- and octa-BDEs. The signatures of PCB congeners suggested that PCB residues in Kaohsiung coast may be the legacy of past use or the result of ongoing inputs from the maintenance, repair and salvage of old ships. Principal component analysis of the congener-specific composition of PBDEs and PCBs revealed distinct regional patterns that are related to the use of commercial products.     

A semi-continuous measurement of gaseous ammonia and particulate ammonium concentrations in PM<Subscript>2.5</Subscript> in the ambient atmosphere

Ammonia has a short residence time in the atmosphere and rapidly neutralizes acid gases that occur near its source, requiring a rapid measurement system for ammonia and particulate ammonium concentrations to better understand their sources, temporal variation of ammonia emissions, and the formation of secondary ammonium aerosols. A semi-continuous measurement system, consisting of a diffusion scrubber, a particle growth chamber, an air-liquid separator, and a fluorescent detector, was developed to determine both gaseous ammonia (NH₃) and particulate ammonium (NH ₄ ⁺ ) in PM_2.5 in the ambient atmosphere of Gwangju, South Korea, during the months of March, April, July, and September of 2007. During the sampling periods, the average concentrations of ammonia and ammonium were found to be 2.33?±?1.29 μg/m³ and 1.89?±?0.99 μg/m³, respectively. Although the average gaseous ammonia concentration was highest in March, the particulate ammonium concentration was higher during the warmer season, reaching 2.08?±?1.07 μg/m³ and 2.32?±?0.94 μg/m³ in April and July, respectively, while only 1.68?±?0.61 μg/m³ in March and 1.24?±?0.99 μg/m³ in September. It is proposed that the higher availability of acid species during the warmer months produced a significant amount of particulate ammonium sulfate. Diurnal fluctuation of ammonia and ammonium during the warmer months showed that their peak time occurred at approximately 10:00 am. Both ammonia and ammonium concentrations were better correlated during the warmer months than during the cooler months. Further, the data suggest that the ammonia and ammonium were measured under well dispersed conditions, and multiple sources contributed to the ammonia at the sampling site.     

The impact of doubled CO2 on the energetics and hydrologic processes of mid-latitude transient eddies

The Northern Hemisphere winter (DJF) stationary eddy response of a general circulation model (GCM) to a doubling of atmospheric CO₂ is simulated with a linear steady state model as a response to anomalies in diabatic heating (latent, sensible and radiative), mountain and transient eddy effects. For this analysis the doubled CO₂ experiment performed by Wilson and Mitchell (1987) is used. The linear simulations of the control and perturbation climate capture most of the important features of the GCMs stationary eddies. The simulation of the anomalous stationary eddy pattern in the Northern Hemisphere captures only some of the important features of the GCMs anomalies. The climate anomalies in the Southern Hemisphere are poorly simulated. In the Northern Hemisphere the climate anomalies are dominated by the effect of transient eddies and mountains. In low latitudes also the contribution of latent heating is important. The contributions of sensible and radiative heating are small.     

Strength and stiffness variation of frozen soilsaccording to confinement during freezing

When water between soil particles is frozen, the strength and stiffness behavior of soils significantly change. Thus, numerous experimental studies in the laboratory have been carried out to characterize the strength and stiffness of frozen soils. The goals of this study are to evaluate the strength characteristics of frozen soils, which underwent confinement in freezing and shearing stages, and to estimate the stiffness variation by shear wave velocity during shear phase. The specimens are prepared in a brass cell by mixing sand and silt with 10% degree of saturation at a relative density of 60%. The applied normal stresses as confining stresses are 5, 10, 25 and 50 k Pa. When the temperature of the specimens is lowered up to-5 °C, direct shear tests are carried out. Furthermore, shear waves are continuously measured through bender elements during shearing stage for the investigation of stiffness change. Test results show that shear strength and stiffness are significantly affected by the confining stress in freezing and shearing phases. This study suggests that the strength and stiffness of frozen soils may be dependent on the confining stresses applied during freezing and shearing.     

Future change of Asian-Australian monsoon under RCP 4.5 anthropogenic warming scenario

We investigate the future changes of Asian-Australian monsoon (AAM) system projected by 20 climate models that participated in the phase five of the Coupled Model Intercomparison Project (CMIP5). A metrics for evaluation of the model’s performance on AAM precipitation climatology and variability is used to select a subset of seven best models. The CMIP5 models are more skillful than the CMIP3 models in terms of the AAM metrics. The future projections made by the selected multi-model mean suggest the following changes by the end of the 21st century. (1) The total AAM precipitation (as well as the land and oceanic components) will increase significantly (by 4.5 %/°C) mainly due to the increases in Indian summer monsoon (5.0 %/°C) and East Asian summer monsoon (6.4 %/°C) rainfall; the Australian summer monsoon rainfall will increase moderately by 2.6 %/°C. The “warm land-cool ocean” favors the entire AAM precipitation increase by generation of an east-west asymmetry in the sea level pressure field. On the other hand, the warm Northern Hemisphere-cool Southern Hemisphere induced hemispheric SLP difference favors the ASM but reduces the Australian summer monsoon rainfall. The combined effects explain the differences between the Asian and Australian monsoon changes. (2) The low-level tropical AAM circulation will weaken significantly (by 2.3 %/°C) due to atmospheric stabilization that overrides the effect of increasing moisture convergence. Different from the CMIP3 analysis, the EA subtropical summer monsoon circulation will increase by 4.4 %/°C. (3) The Asian monsoon domain over the land area will expand by about 10 %. (4) The spatial structures of the leading mode of interannual variation of AAM precipitation will not change appreciably but the ENSO-AAM relationship will be significantly enhanced.     

Modelling road surface sediment production using a vector geographic information system

Field investigations indicate that unpaved roads are the largest sediment source on St John, US Virgin Islands. Cross-sectional measurements of eroded road surfaces were used to establish an empirical relationship to predict annual road surface erosion as a function of road gradient and contributing drainage area. A model (ROADMOD) for estimating and mapping average annual sediment production from a road network was developed by combining this empirical relationship with a series of network algorithms to analyse road data stored in a vector geographic information system. ROADMOD was used to estimate road surface erosion in two St John catchments with very different road densities but similar land cover, topography and soils. Unpaved roads were found to increase sediment production in the more densely roaded catchment by a factor of three to eight, and in the less-roaded catchment by a factor of 1·3–2·0. Turbidity measurements in the receiving bays of these two catchments are consistent with model predictions and observed sediment delivery processes. Although this model was developed specifically for St John, it can easily be adapted to other locations by substituting a locally derived predictive equation for road erosion. Model assumptions, limitations and potential improvements are discussed. © 1998 John Wiley & Sons, Ltd.     

Eutrophication and management initiatives for the control of nutrient inputs to Rhode Island coastal lagoons

An assessment of developing eutrophic conditions in small temperate lagoons along the coast of Rhode Island suggests that in such shallow, macrophyte based systems the response to nutrient enrichment differs from that described for plankton based systems. The nitrogen loadings per unit area of the salt ponds are 240–770 mmol N per m² per year. Instead of the high nutrient concentrations, increased phytoplankton biomass and turbidity, leading to eventual loss of benthic macrophytes described for such systems as the Chesapeake, Patuxent and Appalachicola Bay, nutrient enrichment of the Rhode Island lagoons has led to increased growth of marine macroalgae. The increased macroalgal growth appears to alter the benthic habitat and a shift from a grazing to detrital food chain appears to be impacting important shellfisheries. As more extensive areas of organic sediments develop, geochemical cycling changes, resulting in higher rates of nitrogen remineralization and accelerated eutrophication. The major sources of nitrogen inputs to the salt ponds have been identified and a series of management initiatives have been designed to limit inputs from present and potential development within the watersheds of the lagoons.     

Source identification of PM2.5 particles measured in Gwangju, Korea

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.