Methylmercury in tailings ponds of Amazonian gold mines (French Guiana): Field observations and an experimental flocculation method for in situ remediation

Sites of monomethylmercury (MMHg) production in Amazonian regions have been identified in hydraulic reservoirs, lake sediments and wetlands, but tailings ponds have not yet received sufficient attention for this purpose. This work evidenced high MMHg production within the water column and the interstitial water of two tailings ponds of French Guiana Au mines located; (i) in a small scale exploitation (Combat) where Hg was used for Au amalgamation, and (ii) in an industrial on-going Au mine (Yaoni) processing without Hg. The (MMHg)_D maximum (2.5 ng L⁻¹) occurred in the oxic water column above the sediment-water interface (SWI) of the most recent tailings pond (Combat), where the substrate was fresh, the redox transition was sharp and the pool of total Hg was large. In the Yaoni pond, the (MMHg)_D maximum concentration (1.4 ng L⁻¹) was located at the SWI where suboxic conditions prevailed. Using the (MMHg)_D concentration as a proxy for Hg methylation rates, the present results show that Hg methylation may occur in various redox conditions in tailings ponds, and are favored in areas where the organic matter regeneration is more active.A 3-month long laboratory experiment was performed in oxic and anoxic boxes filled with high turbidity waters from the Combat Au mine to simulate tailings ponds. Slaked lime was added in an experimental set (2 mg L⁻¹) and appeared to be very efficient for the reduction of suspended particulate matter (SPM) to environmentally acceptable concentrations. However, at the end of the experiment, large (MMHg)_D concentrations were monitored under treated anoxic conditions with the (MMHg)_D maximum located at the SWI above the Fe-reducing zones. No (MMHg)_D was detected in oxic experiments. The use of slaked lime for SPM decantation appears to be an efficient and non-onerous process for Au miners to avoid Hg methylation in tailings ponds when it is combined with rapid drainage of the mine waters. A subsequent human intervention is however necessary for the recovery of soil structure through the cover of dried ponds with organic rich materials and reforestation to avoid the stagnation of rain waters and the occurrence of anoxia.     

Coastal Phytoplankton Do Not Rest in Winter

The climatology and interannual variability of winter phytoplankton was analyzed at the Long Term Ecological Research Station MareChiara (LTER-MC, Gulf of Naples, Mediterranean Sea) using data collected from 1985 to 2006. Background winter chlorophyll values (0.2–0.5 μg chl a dm⁻³) were associated with the dominance of flagellates, dinoflagellates, and coccolithophores. Winter biomass increases (<5.47 μg chl a dm⁻³) were often recorded until 2000, generally in association with low-salinity surface waters (37.3–37.9). These blooms were most often caused by colonial diatoms such as Chaetoceros spp., Thalassiosira spp., and Leptocylindrus danicus. In recent years, we observed more modest and sporadic winter biomass increases, mainly caused by small flagellates and small non-colonial diatoms. The resulting negative chl a trend over the time series was associated with positive surface salinity and negative nutrient trends. Physical and meteorological conditions apparently exert a strict control on winter blooms, hence significant changes in winter productivity can be foreseen under different climatic scenarios.     

Effect of the water/cement ratio on concrete behavior under extreme loading

This study focuses on identifying concrete behavior under severe triaxial loadings (near field detonation or ballistic impacts). In order to reproduce high stress levels with well‐controlled loading paths, static tests have been carried out on concrete samples by mean of a very high‐capacity triaxial press (stress levels on the order of 1 GPa). It is a longstanding fact that the water/cement ratio (W/C), upon entering the concrete composition, is a major parameter affecting the porosity and strength of the cement matrix of hardened concrete. The objective of this article is to quantify the effect of this ratio on concrete behavior under conditions of high confinement. From the composition of a reference ‘ordinary’ concrete (i.e. W/C=0.6), two other concretes have been produced with W/C ratios equal to 0.4 and 0.8, respectively. This article presents experimental results and their analysis regarding the effect of water/cement ratio (W/C) on concrete behavior under high confinement. It shows that when placed under high confinement, concrete behaves like a granular stacking composed of concrete without any influence from the level of cement matrix strength. Copyright © 2009 John Wiley & Sons, Ltd.     

Disaster prevention,disaster preparedness and local community resilience within the context of disaster risk management in Cameroon

This paper presents a simulation of three components of near-field ground shaking recorded during the main shock at three stations of the September 16, 1978, Tabas (M _w = 7.4), Iran, earthquake, close to the causative fault. A hybrid method composed of a discrete wavenumber method developed by Bouchon (Bouchon in Bull Seismol Soc Am 71:959–971, 1981; Cotton and Coutant in Geophys J Int 128:676–688, 1997) and a stochastic finite-fault modeling based on a dynamic corner frequency proposed by Motazedian and Atkinson (Bull Seismol Soc Am 95:995–1010, 2005), modified by Assatourians and Atkinson (Bull Seismol Soc Am 97:935–1949, 2007), is used for generating the seismograms at low (0.1–1.0 Hz) and high frequencies (1.0–20.0 Hz), respectively. The results are validated by comparing the simulated peak acceleration, peak velocity, peak displacement, Arias intensity, the integral of velocity squared, Fourier spectrum and acceleration response spectrum on a frequency-by-frequency basis, the shape of the normalized integrals of acceleration and velocity squared, and the cross-correlation with the observed time-series data. Each characteristic is compared on a scale from 0 to 10, with 10 being perfect agreement. Also, the results are validated by comparing the simulated ground motions with the modified Mercalli intensity observations reported by reconnaissance teams and showed reasonable agreement. The results of the present study imply that the damage distribution pattern of the 1978 Tabas earthquake can be explained by the source directivity effect.     

Unravelling the morphogenesis of coastal terraces at Cape Laundi (Sumba Island,Indonesia): Insights from numerical models

The morphology of coastal sequences provides fundamental observations to unravel past sea level (SL) variations. For that purpose, converting morphometric observations into a SL datum requires understanding their morphogenesis. The long-lasting sequence of coral reef terraces (CRTs) at Cape Laundi (Sumba Island, Indonesia) could serve as a benchmark. Yet, it epitomizes a pitfall that challenges the ultimate goal: the overall chronology of its development remains poorly constrained. The polycyclic nature of the terraces, involving marine erosion and reoccupation of old coral colonies by more recent ones hinders any clear assignment of Marine Isotope Stages (MIS) to specific terraces, in particular the reference datum corresponding to the last Interglacial maximum (i.e., MIS 5e). Thus, to overcome these obstacles, we numerically model the genesis of the sequence, testing a range of eustatic SL (ESL) reconstructions and uplift rates, as well as exploring the parameter space to address reef growth, erosion and sedimentation. A total of 625 model runs allowed us to improve the morpho-chronological constraints of the coastal sequence and, more particularly, to explain the morphogenesis of the several CRTs associated with MIS 5e. Our results suggest that the lowermost main terrace was first constructed during the marine transgression of MIS 5e and was later reshaped during the marine regression of MIS 5e, as well as during the MIS 5c and MIS 5a highstands. Finally, we discuss the general morphology of the sequence and the implications it may have on SL reconstructions. At Cape Laundi, as elsewhere, we emphasize the necessity of addressing the development of CRT sequences with a dynamic approach, that is, considering that a CRT is a landform built continuously throughout the history of SL oscillations, and not simply during a singular SL maximum.     

Words as tracers in the history of science and technology:the case of photogrammetry and remote sensing

The evolution of terminology in a given field of science and technology is a good indicator of the context in which inventions originated and how concepts have evolved.This is the case of photogrammetry,remote sensing and related methods,whose terminology evolved,first under the influence of the early inventors Laussedat and Meydenbauer,in French and German,respectively,and then in English and other languages as an international professional community developed.The development of space remote sensing and analytical photogram-metry led to the modification of old concepts and the renewal of terminology,and more recently,the advent of digital photography has blurred the boundaries between different fields and the meaning of the terms.This article proposes an analysis of the evolution of technical terms through the Google Ngram Viewer tool,which allows the visualization of the occurrence of terms in documents accessible on the web.Despite its biases,this tool allows an interpreta-tion of the evolution of the terminology over a long period of time,as well as a comparison of the evolution observed in the different languages.In particular,it makes it possible to highlight the periods when these methods were very popular,as well as a recent decline in the use of classical terms such as photogrammetry and remote sensing in favor of a new vocabulary,due to the blurring of boundaries between disciplines and to the emergence of new solutions related to UAVs,computer vision,etc.,which have renewed the potential of classical methods.     

Projected 21st century snowfall changes over the French Alps and related uncertainties

Snowfall changes in mountain areas in response to anthropogenic forcing could have widespread hydrological, ecological and economic impacts. In this paper, the robustness of snowfall changes over the French Alps projected during the 21st century and the associated uncertainties are studied. In particular, the role of temperature changes on snowfall changes is investigated. Those issues are tackled through the analysis of the results of a very large ensemble of high-resolution regional climate projections, obtained either through dynamical or statistical downscaling. We find that, at the beginning and at the end of the cold season extending from November to March (included), temperature change is an important source of spread in snowfall changes. However, no link is found between temperature and snowfall changes in January and February. At the beginning and at the end of the cold season, the rate of change in snowfall per Kelvin does not depend much on the bias correction step, the period or the greenhouse gas scenario but mostly on the downscaling method and the climate models, the latter uncertainty source being dominant.     

Evaluation of regional climate simulations for air quality modelling purposes

In order to evaluate the future potential benefits of emission regulation on regional air quality, while taking into account the effects of climate change, off-line air quality projection simulations are driven using weather forcing taken from regional climate models. These regional models are themselves driven by simulations carried out using global climate models (GCM) and economical scenarios. Uncertainties and biases in climate models introduce an additional “climate modeling” source of uncertainty that is to be added to all other types of uncertainties in air quality modeling for policy evaluation. In this article we evaluate the changes in air quality-related weather variables induced by replacing reanalyses-forced by GCM-forced regional climate simulations. As an example we use GCM simulations carried out in the framework of the ERA-interim programme and of the CMIP5 project using the Institut Pierre-Simon Laplace climate model (IPSLcm), driving regional simulations performed in the framework of the EURO-CORDEX programme. In summer, we found compensating deficiencies acting on photochemistry: an overestimation by GCM-driven weather due to a positive bias in short-wave radiation, a negative bias in wind speed, too many stagnant episodes, and a negative temperature bias. In winter, air quality is mostly driven by dispersion, and we could not identify significant differences in either wind or planetary boundary layer height statistics between GCM-driven and reanalyses-driven regional simulations. However, precipitation appears largely overestimated in GCM-driven simulations, which could significantly affect the simulation of aerosol concentrations. The identification of these biases will help interpreting results of future air quality simulations using these data. Despite these, we conclude that the identified differences should not lead to major difficulties in using GCM-driven regional climate simulations for air quality projections.