Electrical resistivity investigation of the arsenic affected alluvial aquifers in West Bengal,India: usefulness in identifying the areas of low and high groundwater arsenic

This study aims at finding out possible relation between lithology and spatial pattern of dissolved arsenic (As) in groundwater around Chakdaha municipality, West Bengal, India. Satellite image, coupled with electrical resistivity survey and borehole drilling helps to delineate surface and sub-surface lithological framework of the As affected alluvial aquifers. The satellite imagery demonstrate that the high As area are presumably under active flood plain environment (low-lying areas), that constantly receive organics due to periodic flooding. Thick low resistive (fine-grained) layer was observed at the top around the high As areas, which, however, not found in low As areas. The result suggests that hydraulic properties of the surface/sub-surface soil/sediment have an important control on the fate and transport of As in the aquifer. This study demonstrates that electrical resistivity tools can be effectively used for the reconnaissance survey in characterizing the plausible lithological framework of an alluvial aquifer containing As.     

Analytical and numerical analyses of the load‐bearing capacity of retaining walls laterally supported at both ends

This paper investigates the load‐bearing capacity of a perfectly smooth retaining wall laterally supported at both ends assuming that the wall fails by the development of three plastic hinges. The study considers the case of a cohesionless elastic–perfectly plastic backfill with a Mohr–Coulomb yield criterion and an associative flow rule in drained conditions. A kinematically admissible soil–structure failure mechanism is proposed and compared with the conventional solutions and with results from a numerical finite element modelling. The study shows that the proposed solution and the numerical solution are in good agreement. These solutions are found to be much more favourable for the wall than the conventional solutions. Copyright © 2010 John Wiley & Sons, Ltd.     

Ice Sheet And Satellite Altimetry

Since 1991, the altimeters of the ERS European Satellites allow the observation of 80% of the Antarctica ice sheet and the whole Greenland ice sheet: They thus offer for the first time a unique vision of polar ice caps. Indeed, surface topography is an essential data thanks to its capacity to highlight the physical processes which control the surface shape, or to test models. Moreover, the altimeter is also a radar which makes it possible to estimate the snow surface or subsurface characteristics, such as surface roughness induced by the strong katabatic wind or ice grain size. The polar ice caps may not be in a stationary state, they continue to respond to the climatic warming of the beginning of the Holocene, that is 18000 years ago, and possibly start to react to present climatic warming: the altimeter offers the unique means of estimating the variations of volume and thus the contribution of polar ice caps to present sea level change.     

The AGNS and their host galaxies as seen in the mid-infrared

We present a new diagnostic diagram based on ISOCAMspectra (5-16 m) to distinguish the emission inducedby the active galactic nucleus (AGN) from that associated with thestar formation activity. This diagnostic based on the mid-IRcontinuum and the Unidentified Infrared Band (UIB) intensity allowsus to estimate the relative importance of the three components (HIIregions, diffuse/photo-dissociation regions (PDRs), and AGN) contained ingalaxy mid-infrared emission. In AGN spectra, we confirm the absenceof UIBs presumably photodissociated by the X-UV radiation field. Inaddition, a non-negligible continuum below 9 m commonlyassociated with emission from hot dust is present in AGNs. Adiagnostic diagram derived from these two results can be used fordetecting obscured AGNs embedded in a large concentration of dust.     

Spatial Variability of Trends in the Rainfall-Runoff Relationship: A Mesoscale Study in the Mosel Basin

The spatial variability of observed trends in rainfall structure over the last 5 decades and its effects on the spatial variability of maximum daily water levels in the Grand-Duchy of Luxembourg (Europe) were investigated in 9 sub-basins of the Mosel river. Over the past 25 years, an increase in westerly atmospheric circulation types during winter months has caused an increase in winter rainfall totals, duration and intensity. More specifically, the spatial variability of trends having affected winter rainfall totals, duration and intensity have led to spatially varying positive trends in maximum daily water levels. Observed trends in rainfall characteristics and maximum daily water levels during winter show closely linked spatial patterns that are strongly related to the topography of the study area.     

Mid-latitude Southern Indian Ocean response to Northern Hemisphere Heinrich events

The lack of temporal resolution and accurate chronology of Southern Ocean marine cores has hampered comparison of glacial millennial-scale oscillations between the Southern Ocean, Antarctic ice and other records from both hemispheres. In this study, glacial climate variability is investigated over the last 50 ka using a multi-proxy approach. A precise chrono-stratigraphy was developed on the high-sedimentation rate core MD94-103 (Indian Southern Ocean, 45°35′S 86°31′E, 3560 m water depth) by geomagnetic synchronization between the later core and NAPIS75, and ¹⁴C dates. High-resolution time-series of δ¹⁸O in planktonic foraminifera Globigerina bulloides and Neogloboquadrina pachyderma, and sea surface temperatures (SSTs) estimated from the alkenone U^K′₃₇ index and foraminifera assemblages have been generated. Temporal evolution of the two temperature proxy records is notably different during the last glacial period. While foraminifera data indicate a consistent cooling towards the last glacial maximum, anomalous warm glacial alkenone temperatures suggest a strong advection of warm “detrital” alkenones by surface waters of the Agulhas current. Superimposed to this general trend, during Heinrich events, foraminiferal SSTs point to warmer surface waters, while concurrent alkenone SSTs exhibit apparent coolings probably caused by enhanced local alkenone production. By analogy to modern observations, possible influence of ENSO-like conditions on the subantarctic Southern Ocean SSTs is discussed.     

Spécificités hydrogéologiques des hautes vallées alpines: Exemple de la Haute-Sarine (Suisse)

The alpine valley of the Haute-Sarine is on several accounts representative of the alluvial aquifers of mountain by its very environment and its hydrogeologic characteristics. The investigations and the analysis carried out within the framework of this study enabled us to improve knowledge on the Quaternary filling of the valley and to highlight the preferential supplies of the aquifer by infiltration of the river and precipitations and also by the underground contributions of evaporitic karsts. We also could note the opulence of groundwater resources of the Haute-Sarine both from the qualitative and the quantitative points of view. The knowledge of these typical characteristics of alluvial aquifers of high altitude allowed finally the development of a concept of management and protection of groundwater resources that falls under a sustainable development policy of the groundwater storage in the alpine areas. Manuscrit re?u le 4 février 2003 Révision acceptée le 30 mars 2005     

Surface chemistry of disordered mackinawite (FeS)

Disordered mackinawite, FeS, is the first formed iron sulfide in ambient sulfidic environments and has a highly reactive surface. In this study, the solubility and surface chemistry of FeS is described. Its solubility in the neutral pH range can be described by K_s^app = {Fe²⁺} · {H₂S(aq)} · {H⁺}⁻² = 10^+4.87±0.27. Acid-base titrations show that the point of zero charge (PZC) of disordered mackinawite lies at pH ∼7.5. The hydrated disordered mackinawite surface can be best described by strongly acidic mono-coordinated and weakly acidic tricoordinated sulfurs. The mono-coordinated sulfur site determines the acid-base properties at pH < PZC and has a concentration of 1.2 × 10⁻³ mol/g FeS. At higher pH, the tricoordinated sulfur, which has a concentration of 1.2 × 10⁻³ mol/g FeS, determines surface charge changes. Total site density is 4 sites nm⁻². The acid-base titration data are used to develop a surface complexation model for the surface chemistry of FeS.     

New insight on aliphatic linkages in the macromolecular organic fraction of Orgueil and Murchison meteorites through ruthenium tetroxide oxidation

Ruthenium tetroxide oxidation was used to examine the macromolecular insoluble organic matter (IOM) from the Orgueil and Murchison meteorites and especially to characterize the aliphatic linkages. Already applied to various terrestrial samples, ruthenium tetroxide is a selective oxidant which destroys aromatic units, converting them into CO₂, and yields aliphatic and aromatic acids. In our experiment on chondritic IOM, it produces mainly short aliphatic diacids and polycarboxylic aromatic acids. Some short hydroxyacids are also detected.Aliphatic diacids are interpreted as aliphatic bridges between aromatic units in the chemical structure, and polycarboxylic aromatic acids are the result of the fusion of polyaromatic units. The product distribution shows that aliphatic links are short with numerous substitutions. No indigenous monocarboxylic acid was detected, showing that free aliphatic chains must be very short (less than three carbon atoms). The hydroxyacids are related to the occurrence of ester and ether functional groups within the aliphatic bridges between the aromatic units. This technique thus allows us to characterize in detail the aliphatic linkages of the IOMs, and the derived conclusions are in agreement with spectroscopic, pyrolytic, and degradative results previously reported.Compared to terrestrial samples, the aliphatic part of chondritic IOM is shorter and highly substituted. Aromatic units are smaller and more cross-linked than in coals, as already proposed from NMR data. Orgueil and Murchison IOM exhibit some tiny differences, especially in the length of aliphatic chains.